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Portable Raman spectroscopic analysis of bulk crushed rock

Metadata Updated: July 6, 2024

This study presents a simplified method and empirical relationships for determining organic matter thermal maturity using a portable Raman system equipped with a 785 nm laser, for analysis of crushed, whole-rock samples. Several sets of rocks comprised of shale and coal samples with various mineralogical composition, thermal maturity, total organic carbon (TOC), and age were used to test the method and build correlations between Raman band separation (RBS) values and traditional thermal maturity indicators; organic matter reflectance (Ro) and programmed temperature pyrolysis (Tmax) values. Several sample preparation methods were tested on cuttings material and standard deviation values for RBS were minimized by washing, drying, and hand crushing the material to pass through a 40-mesh sieve, although less preparation can still yield reliable results. For the coal data set, Ro values range from 1.21-4.08% and correlated RBS values plateau at ~250 cm-1 above Ro=3.0% suggesting its correlative application below this maturity level. The second data set, comprised of disparate shale samples where both vitrinite and solid bitumen reflectance values were reported, have Ro values that range from 0.40-4.62%. Above 3.35% Ro, the corresponding RBS values plateau at ~290 cm-1, thus correlations were evaluated with a linear equation (R2= 0.96) between 0.40-3.35% Ro. Shale samples with Ro <2% and Tmax <551 were also used to correlate Tmax and RBS, yielding a linear correlation with an R2 of 0.94. The high degrees of correlation between whole rock RBS data and two thermal maturity indicators demonstrate the utility of this approach for generating source rock thermal maturity data from minimally processed whole rock samples which could easily be applied in field or laboratory settings. These datasets also highlight the utility of whole-rock thermal maturity techniques like programmed temperature pyrolysis and portable Raman spectroscopy versus microscopic maceral specific methods where analyst error (e.g., incorrect maceral identification) can yield potentially erroneous maturity correlations.

Access & Use Information

Public: This dataset is intended for public access and use. License: No license information was provided. If this work was prepared by an officer or employee of the United States government as part of that person's official duties it is considered a U.S. Government Work.

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Dates

Metadata Created Date August 24, 2023
Metadata Updated Date July 6, 2024

Metadata Source

Harvested from DOI EDI

Additional Metadata

Resource Type Dataset
Metadata Created Date August 24, 2023
Metadata Updated Date July 6, 2024
Publisher U.S. Geological Survey
Maintainer
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Identifier USGS:6480cdc4d34eac007b57de91
Data Last Modified 20230803
Category geospatial
Public Access Level public
Bureau Code 010:12
Metadata Context https://project-open-data.cio.gov/v1.1/schema/catalog.jsonld
Metadata Catalog ID https://datainventory.doi.gov/data.json
Schema Version https://project-open-data.cio.gov/v1.1/schema
Catalog Describedby https://project-open-data.cio.gov/v1.1/schema/catalog.json
Harvest Object Id f7ae634f-33ff-4a76-841f-99e8276315b2
Harvest Source Id 52bfcc16-6e15-478f-809a-b1bc76f1aeda
Harvest Source Title DOI EDI
Metadata Type geospatial
Old Spatial -115.1807,23.564,120.7617,50.2893
Publisher Hierarchy White House > U.S. Department of the Interior > U.S. Geological Survey
Source Datajson Identifier True
Source Hash a2becad2f860a4b15f354c32634ac41aef7af8d73b6b2aa98b357edd74f39db6
Source Schema Version 1.1
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