This data set contains archival results from radio science investigations conducted during the Mars Global Surveyor (MGS) mission. Radio measurements were made using the MGS spacecraft and Earth-based stations of the NASA Deep Space Network (DSN). The data set includes high-resolution spherical harmonic models of Mars' gravity field generated by groups at the Jet Propulsion Laboratory and Goddard Space Flight Center, covariance matrices for some models, and maps for some models; these results were derived from raw radio tracking data. Also included are profiles of atmospheric temperature and pressure and ionospheric electron density, derived from phase measurements collected during radio occultations. The data set also includes analyses of transient surface echoes observed close to occultations during the first few years of MGS operations. The atmospheric and surface investigations were conducted by Radio Science Team members at Stanford University. The data set also includes 93 line-of-sight acceleration profiles derived at JPL from radio tracking data collected near periapsis while Mars Global Surveyor was in its Science Phasing Orbit and below its nominal Mapping altitude of 400 km. The data were delivered to PDS in approximately chronological order at the rate of one CD-WO volume (typically 100 MB) every three months.