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Data release for mean random reflectance for products of hydrous pyrolysis experiments on artificial rock mixtures of humic Wyodak-Anderson coal (2018)

Metadata Updated: October 29, 2023

Mean random vitrinite reflectance (Ro) is the most widely accepted method to determine thermal maturity of coal and other sedimentary rocks. However, oil-immersion Ro of polished rock or kerogen samples is commonly lower than Ro values measured in samples from adjacent vitrinite-rich coals that have undergone the same level of thermal stress. So-called suppressed Ro values have also been observed in hydrous pyrolysis experiments designed to simulate petroleum formation. Various hypotheses to explain Ro suppression, such as sorption of products generated from liptinite during maturation, diagenetic formation of perhydrous vitrinite or overpressure, remain controversial. To experimentally test for suppression of vitrinite reflectance, artificial rock was prepared using silica and a calcined blend of limestone and clay with various proportions of thermally immature vitrinite-rich Wyodak-Anderson coal and liptinite-rich kerogen isolated from the oil-prone Parachute Creek Member of the Green River Formation. The samples were subjected to hydrous pyrolysis for 72 hr. at isothermal temperatures of 300 C, 330 C, and 350 C to simulate burial maturation. Compared to artificial rock that contains only coal, samples with different proportions of oil-prone kerogen show distinct suppression of calibrated Ro at 300 C and 330 C. The reflectance of solid bitumen generated during heating of the samples is lower than that of the associated vitrinite and does not interfere with the Ro measurements. These results provide the first experimental evidence that Ro suppression occurs in vitrinite mixed with liptinite-rich kerogen in a rock matrix. Although the precise chemical mechanism for Ro suppression by liptinite remains unclear, free radicals generated from solid bitumen and associated volatile products during maturation of liptinite may contribute to termination reactions that slow the aromatization and rearrangement of polyaromatic sheets in vitrinite, thus suppressing Ro. This mechanism does not preclude Ro suppression that might result from overpressure or differences in redox conditions during diagenesis.

Access & Use Information

Public: This dataset is intended for public access and use. License: No license information was provided. If this work was prepared by an officer or employee of the United States government as part of that person's official duties it is considered a U.S. Government Work.

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Dates

Metadata Created Date June 1, 2023
Metadata Updated Date October 29, 2023

Metadata Source

Harvested from DOI EDI

Additional Metadata

Resource Type Dataset
Metadata Created Date June 1, 2023
Metadata Updated Date October 29, 2023
Publisher U.S. Geological Survey
Maintainer
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Identifier USGS:5bcde62de4b0f0758fc18167
Data Last Modified 20200819
Category geospatial
Public Access Level public
Bureau Code 010:12
Metadata Context https://project-open-data.cio.gov/v1.1/schema/catalog.jsonld
Metadata Catalog ID https://datainventory.doi.gov/data.json
Schema Version https://project-open-data.cio.gov/v1.1/schema
Catalog Describedby https://project-open-data.cio.gov/v1.1/schema/catalog.json
Harvest Object Id 3d0181bb-7ac3-49e9-94fe-c51c580de167
Harvest Source Id 52bfcc16-6e15-478f-809a-b1bc76f1aeda
Harvest Source Title DOI EDI
Metadata Type geospatial
Old Spatial -108.125,39.75,-106.9697,44.84648
Publisher Hierarchy White House > U.S. Department of the Interior > U.S. Geological Survey
Source Datajson Identifier True
Source Hash 5f6aa56c0c0d459c4eb2234bad6f2ec131e9124ea2992456f9c149050b489023
Source Schema Version 1.1
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