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            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/08fd82a1-4370-46a2-82ea-94c0f91498a7" xlink:actuate="onRequest">EARTH SCIENCE &gt; ATMOSPHERE &gt; ATMOSPHERIC PRESSURE</gmx:Anchor>
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                        <gmd:CI_OnlineResource>
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                            <gco:CharacterString>Global Change Master Directory (GCMD). 2025. GCMD Keywords, Version 21. Greenbelt, MD: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA). URL (GCMD Keyword Forum Page): https://forum.earthdata.nasa.gov/app.php/tag/GCMD+Keywords</gco:CharacterString>
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                <gco:CharacterString>OCADS Study Type</gco:CharacterString>
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                <gco:CharacterString>Global Change Master Directory (GCMD) Instrument Keywords</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: pCO2 (fCO2) autonomous;
Abbreviation: fCO2_SW@SST;
Unit: uatm;
Observation type: Surface underway;
Measured or calculated: Measured;
Sampling instrument: Seawater pump;
Location of seawater intake: Bow;
Analyzing instrument: Infrared Analyzer: LI-COR model 6262;
Detailed sampling and analyzing information: Pierrot, D., Neill, C., Sullivan, K., Castle, R., Wanninkhof, R., Lüger, H., Johannessen, T., Olsen, A., Feely, R. A., &amp; Cosca, C. E. (2009). Recommendations for autonomous underway pCO2 measuring systems and data-reduction routines. Deep Sea Research Part II: Topical Studies in Oceanography, 56(8-10), 512-522. https://doi.org/10.1016/j.dsr2.2008.12.005;
Equilibrator type: Spray head above dynamic pool, with thermal jacket;
Equilibrator volume: 0.95 L (0.4 L water, 0.55 L headspace);
Is the equilibrator vented or not: Vented;
Water flow rate: 1.5 - 2.0 L/min;
Gas flow rate: 70 - 150 ml/min;
How was temperature inside the equilibrator measured: Hart Scientific model 1523 digital thermometer;
How was pressure inside the equilibrator measured: External Setra 270 connected to the exit of the analyzer;
Drying method for gas: Gas stream passes through a thermoelectric condenser (~5 C) and then through a Perma Pure (Nafion) dryer before reaching the analyzer (90% dry).;
SEA CO2 gas detector manufacturer: Licor, Inc;
SEA CO2 gas detector model: Licor 6262;
SEA CO2 gas detector resolution: 0.01 uatm;
SEA CO2 gas detector uncertainty: 2 uatm;
Standardization technique: The analyzer is calibrated every 4.3 hours with field standards that in turn were calibrated with primary standards that are directly traceable to the WMO scale. The zero gas is ultra-high purity air.;
Standardization frequency: Every 4.3 hours;
Standard gas manufacturer: Scott-Marrin, Inc.;
Standard gas concentration: Std 1: JA02645, 204.74 ppm, owned by AOML, used every ~3.5 hours. Std 2: JA02273, 317.49 ppm, owned by AOML, used every ~3.5 hours. Std 3: JB03591, 409.69 ppm, owned by AOML, used every ~3.5 hours. Std 4: JA02647, 518.24 ppm, owned by AOML, used every ~3.5 hours. Std 5: 0.00 ppm, owned by AOML, used every ~17.0 hours.;
Standard gas uncertainty: 0.01 ppm;
Water vapor correction method: Details of the data reduction are described in Pierrot, et.al. (2009).;
Temperature correction method: Details of the data reduction are described in Pierrot, et.al. (2009).;
At what temperature was pCO2 reported: In situ sea surface temperature;
Uncertainty: 0.01C;
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value;
Method reference: Pierrot, D., Neill, C., Sullivan, K., Castle, R., Wanninkhof, R., Lüger, H., Johannessen, T., Olsen, A., Feely, R. A., &amp; Cosca, C. E. (2009). Recommendations for autonomous underway pCO2 measuring systems and data-reduction routines. Deep Sea Research Part II: Topical Studies in Oceanography, 56(8-10), 512-522. https://doi.org/10.1016/j.dsr2.2008.12.005;
Researcher name: Kevin Sullivan;
Researcher institution: NOAA/AOML</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Sea Surface Temperature;
Abbreviation: SST_C;
Unit: degrees celcius;
Observation type: Surface Underway;
Analyzing instrument: SBE 38, Seabird, Inc.;
Detailed sampling and analyzing information: After sea water pump, ~3 m below sea surface;
Uncertainty: Accuracy: 0.001C, Precision: 0.0003C;
Researcher name: Kevin Sullivan;
Researcher institution: NOAA/AOML</gco:CharacterString>
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Abbreviation: SAL_permil;
Observation type: Surface Underway;
Analyzing instrument: SBE 45, Seabird, Inc.;
Uncertainty: Accuracy: +/- 0.005; Precision: 0.0002;
Researcher name: Kevin Sullivan;
Researcher institution: NOAA/AOML</gco:CharacterString>
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Abbreviation: PRES_ATM@SSP_hPa;
Unit: hPa;
Analyzing instrument: Vaisala, Model: PTB220;
Uncertainty: Accuracy: +/- 0.15 hPa; Precision: 0.01 hPa;
Researcher name: Kevin Sullivan;
Researcher institution: NOAA/AOML</gco:CharacterString>
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            <gco:CharacterString>measures gaseous carbon dioxide

Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption.

Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
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A carbon dioxide equilibrator is usually in the shape of a vertical tube, with a showerhead on the top, some headspace, a lot of beads to increase the surface exchange area between water and air, a water seal device at the bottom to allow water to overflow, but prevents air exchange between inside and outside.

Carbon dioxide (CO2) equilibrator works together with carbon dioxide (CO2) gas analyzer (insttypes_id 183) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
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Flag: United States of America
Vessel Type: Fishery Research Vessel (Oceanographic)
DOB: Jun 2006
IMO: 9349057

NOAA Ship HENRY B. BIGELOW was launched on July 8, 2005 and commissioned by NOAA on July 16, 2007.  For more information, see http://www.moc.noaa.gov/hb.

Submitted by NODC to ICES on 2010-09-08.
Confirmed in ICES by NOAA on 2012-10-02.</gco:CharacterString>
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