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            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/114" xlink:actuate="onRequest">DISSOLVED ORGANIC CARBON</gmx:Anchor>
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          <gmd:keyword>
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                    <gco:CharacterString>These data are available through the File Transfer Protocol (FTP). FTP is no longer supported by most internet browsers. You may copy and paste the FTP link to the data into an FTP client (e.g., FileZilla or WinSCP).</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: RADIUM ISOTOPES (measured);
Units: dpm/L;
Observation Category: laboratory analysis;
Sampling Instrument: manganese fiber;
Sampling and Analyzing Method: Prior to sample collection, stagnant groundwater was pumped out of each well using a peristaltic pump. Radium samples were then collected as described previously (Moore et al., 2006). Briefly, freshly recharged groundwater was pumped into a 4 L cubitainer, which was sample-rinsed three times before being filled. For surface water, a 26 L sample was collected into a large plastic drum. Each sample was then gravity-filtered through 15-20 g of Mn-coated acrylic fibers to trap dissolved radium. The activities of 226Ra and 228Ra were determined later using a gamma ray spectrometer following HCl-extraction of radium from the Mn fiber (Moore, 1984).</gco:CharacterString>
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Units: psu;
Observation Category: in situ;
Sampling Instrument: YSI - handheld multi-parameter instrument;
Sampling and Analyzing Method: A 1-liter polycarbonate bottle was rinsed 3 times with sample and then filled to the brim with sample. The YSI probe was completely submerged in the sample and a stable value was recorded.;
Data Quality Method: Data were checked to make sure that all values fell within the acceptable value range of 0-60 psu.</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: WATER TEMPERATURE (measured);
Units: degrees Celsius;
Observation Category: in situ;
Sampling Instrument: YSI - handheld multi-parameter instrument;
Sampling and Analyzing Method: A 1-liter polycarbonate bottle was rinsed 3 times with sample and then filled to the brim with sample. The YSI probe was completely submerged in the sample and a stable value was recorded.;
Data Quality Method: Data were checked to make sure that all values fell within the acceptable value range of 0-45 degrees Celsius.</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: pH (measured);
Units: pH;
Observation Category: in situ;
Sampling Instrument: handheld pH sensor;
Sampling and Analyzing Method: A 1-liter polycarbonate bottle was rinsed 3 times with sample and then filled to the brim with sample. pH was measured using an electrode (Orion ROSS Sure Flow pH Electrode) connected with a handheld meter (Thermo Fisher Orion 5-Star portable meter). The electrode was calibrated against pH 4, pH 7, and pH 10 standards prior to each deployment.</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: DISSOLVED ORGANIC CARBON (measured);
Units: µmol/L;
Observation Category: laboratory analysis;
Sampling Instrument: Shimadzu TOC5000;
Sampling and Analyzing Method: Prior to sampling, stagnant groundwater was removed from wells with a peristaltic pump. Freshly recharged groundwater was then collected into a disposable syringe using tygon tubing. The syringe and tubing were rinsed with ~30 mL of groundwater prior to collecting samples. DOC samples were 0.2 µm  ﬁltered into an acid-washed Nalgene bottle and stored frozen until analysis using a Shimadzu TOC-5000 analyzer.</gco:CharacterString>
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Units: µmol/L;
Observation Category: laboratory analysis;
Sampling Instrument: Shimadzu TOC5000;
Sampling and Analyzing Method: Prior to sampling, stagnant groundwater was removed from wells with a peristaltic pump. Freshly recharged groundwater was then collected into a disposable syringe using tygon tubing. The syringe and tubing were rinsed with ~30 mL of groundwater prior to collecting samples. TDN samples were 0.2 µm  ﬁltered into an acid-washed Nalgene bottle and stored frozen until analysis using a Shimadzu TOC-5000 analyzer with a TN unit.</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: AMMONIUM (NH4) (measured);
Units: µmol/L;
Observation Category: laboratory analysis;
Sampling Instrument: spectrophotometer;
Sampling and Analyzing Method: Prior to sampling, stagnant groundwater was removed from wells with a peristaltic pump. Freshly recharged groundwater was then collected into a disposable syringe using tygon tubing. The syringe and tubing were rinsed with ~30 mL of groundwater prior to collecting samples. A 5-mL subsample was 0.2-µm ﬁltered into a 15-mL centrifuge tube containing 200 μL of phenol reagent and stored refrigerated until colorimetric analysis of ammonium (Solorzano 1969).</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: nitrate + nitrite content (concentration) (measured);
Units: µmol/L;
Observation Category: laboratory analysis;
Sampling Instrument: Antek 7050 chemiluminescent detector;
Sampling and Analyzing Method: Prior to sampling, stagnant groundwater was removed from wells with a peristaltic pump. Freshly recharged groundwater was then collected into a disposable syringe using tygon tubing. The syringe and tubing were rinsed with ~30 mL of groundwater prior to collecting samples. NOx (nitrate + nitrite) samples were 0.2 µm ﬁltered into an acid-washed Nalgene bottle and stored frozen until analysis using an Antek 7050 chemiluminescent nitric oxide detector.</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: NITRITE (measured);
Units: µmol/L;
Observation Category: laboratory analysis;
Sampling Instrument: spectrophotometer;
Sampling and Analyzing Method: Prior to sampling, stagnant groundwater was removed from wells with a peristaltic pump. Freshly recharged groundwater was then collected into a disposable syringe using tygon tubing. The syringe and tubing were rinsed with ~30 mL of groundwater prior to collecting samples. Nitrite samples were 0.2 µm ﬁltered into an acid-washed Nalgene bottle and stored frozen until analysis using standard colorimetric methods (Bendschneider and Robinson 1952) on a spectrophotometer.</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: NITRATE (calculated);
Units: µmol/L;
Observation Category: laboratory analysis;
Sampling Instrument: None;
Sampling and Analyzing Method: The concentration of nitrate was calculated as the difference between the NOx (nitrate + nitrite) concentration and the nitrite concentration alone.</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Dissolved Organic Nitrogen (calculated);
Units: µmol/L;
Observation Category: laboratory analysis;
Sampling Instrument: None;
Sampling and Analyzing Method: The dissolved organic nitrogen concentration was calculated as the difference between the total dissolved nitrogen concentration and the dissolved inorganic nitrogen concentration.</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Dissolved inorganic nitrogen (calculated);
Units: µmol/L;
Observation Category: laboratory analysis;
Sampling Instrument: None;
Sampling and Analyzing Method: The dissolved inorganic nitrogen concentration was calculated as the sum of its constituent concentration pools (ammonium + nitrate + nitrite)</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Phosphate (measured);
Units: µmol/L;
Observation Category: laboratory analysis;
Sampling Instrument: spectrophotometer;
Sampling and Analyzing Method: Prior to sampling, stagnant groundwater was removed from wells with a peristaltic pump. Freshly recharged groundwater was then collected into a disposable syringe using tygon tubing. The syringe and tubing were rinsed with ~30 mL of groundwater prior to collecting samples. Chloride samples were 0.2 µm ﬁltered, ﬁxed with concentrated nitric acid, and stored in an acid-washed glass scintillation vial before colorimetric analysis (Strickland and Parsons 1972) using a spectrophotometer.</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Chloride (Cl-) (measured);
Units: mmol/L;
Observation Category: laboratory analysis;
Sampling Instrument: Dionex ICS-2000;
Sampling and Analyzing Method: Prior to sampling, stagnant groundwater was removed from wells with a peristaltic pump. Freshly recharged groundwater was then collected into a disposable syringe using tygon tubing. The syringe and tubing were rinsed with ~30 mL of groundwater prior to collecting samples. A 20-mL sample was 0.2 µm ﬁltered, ﬁxed with 0.05 mL of concentrated nitric acid, and stored in an acid-washed glass scintillation vial. Chloride was measured by ion chromatography (Dionex ICS-2000).</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Sulfate (SO4 2-) (measured);
Units: mmol/L;
Observation Category: laboratory analysis;
Sampling Instrument: Dionex ICS-2000;
Sampling and Analyzing Method: Prior to sampling, stagnant groundwater was removed from wells with a peristaltic pump. Freshly recharged groundwater was then collected into a disposable syringe using tygon tubing. The syringe and tubing were rinsed with ~30 mL of groundwater prior to collecting samples. A 20-mL sample was 0.2 µm ﬁltered, ﬁxed with 0.05 mL of concentrated nitric acid, and stored in an acid-washed glass scintillation vial. Sulfate was measured by ion chromatography (Dionex ICS-2000).</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Total dissolved iron (measured);
Units: µmol/L;
Observation Category: laboratory analysis;
Sampling Instrument: PerkinElmer ELAN DRC ICP-MS;
Sampling and Analyzing Method: Prior to sampling, stagnant groundwater was removed from wells with a peristaltic pump. Freshly recharged groundwater was then collected into a disposable syringe using tygon tubing. The syringe and tubing were rinsed with ~30 mL of groundwater prior to collecting samples. A 20-mL sample was 0.2 µm ﬁltered, ﬁxed with 0.05 mL of concentrated nitric acid, and stored in an acid-washed glass scintillation vial. Total dissolved iron was measured by inductively coupled plasma mass spectrometry (PerkinElmer ELAN DRC ICP-MS). Samples were measured against a multielement standard dissolved in 2% nitric acid (Environmental Express ACQ500-7). A yttrium internal standard (in 2% nitric acid; Environmental Express HP100067-1) was added to all samples and standards.</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Hydrogen Sulfide (H2S) (measured);
Units: µmol/L;
Observation Category: laboratory analysis;
Sampling Instrument: spectrophotometer;
Sampling and Analyzing Method: Prior to sampling, stagnant groundwater was removed from wells with a peristaltic pump. Freshly recharged groundwater was then collected into a disposable syringe using tygon tubing. The syringe and tubing were rinsed with ~30 mL of groundwater prior to collecting samples. A 5-mL subsample for sulfide analysis was 0.2-μm filtered into a 15-mL centrifuge tube, fixed with 200 μL of 20% (w/v) zinc acetate, and refrigerated until analysis using the Cline (1969) colorimetric method.</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Methane (CH4) (measured);
Units: µmol/L;
Observation Category: laboratory analysis;
Sampling Instrument: Shimadzu GC2100;
Sampling and Analyzing Method: Prior to sampling, stagnant groundwater was removed from wells with a peristaltic pump. Freshly recharged groundwater was then collected into a disposable syringe using tygon tubing. The syringe and tubing were rinsed with ~30 mL of groundwater prior to collecting samples. A 10-mL subsample was collected into a disposable syringe and injected into a 20-mL serum vial for trace gas analysis. The serum vial had been pre-purged with helium and contained a sodium hydroxide pellet to halt metabolic activity; each vial was sealed with a butyl rubber septum and stored inverted. Methane concentrations were measured using a gas chromatograph (Shimadzu GC2100) equipped with a ﬂame ionization detector.;
Data Quality Method: The detection limit for this method, defined as 3 times the standard deviation of the concentrations measured in field blanks (n = 41), was 0.45 µM CH4. Samples with measured concentrations below this detection limit are marked "NaN".</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: DISSOLVED INORGANIC CARBON (DIC) (measured);
Units: mmol/L;
Observation Category: laboratory analysis;
Sampling Instrument: Shimadzu GC2100;
Sampling and Analyzing Method: Prior to sampling, stagnant groundwater was removed from wells with a peristaltic pump. Freshly recharged groundwater was then collected into a disposable syringe using tygon tubing. The syringe and tubing were rinsed with ~30 mL of groundwater prior to collecting samples. A 10-mL subsample was collected into a disposable syringe and injected into a 20-mL serum vial for trace gas analysis. The serum vial had been pre-purged with helium and contained a sodium hydroxide pellet to halt metabolic activity; each vial was sealed with a butyl rubber septum and stored inverted. Prior to analysis, concentration hydrochloric acid was injected into each vial to convert the dissolved organic carbon pool into gaseous carbon dioxide. Carbon dioxide concentrations were measured using a gas chromatograph (Shimadzu GC2100) equipped with a methanizer and ﬂame ionization detector.;
Data Quality Method: The detection limit for this method, defined as 3 times the standard deviation of the concentrations measured in field blanks (n = 41), was 0.87 mmol/L. Samples with measured concentrations below this detection limit are marked "NaN".</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: nitrous oxide (N2O) (measured);
Units: nmol/L;
Observation Category: laboratory analysis;
Sampling Instrument: Shimadzu GC8A;
Sampling and Analyzing Method: Prior to sampling, stagnant groundwater was removed from wells with a peristaltic pump. Freshly recharged groundwater was then collected into a disposable syringe using tygon tubing. The syringe and tubing were rinsed with ~30 mL of groundwater prior to collecting samples. A 10-mL subsample was collected into a disposable syringe and injected into a 20-mL serum vial for trace gas analysis. The serum vial had been pre-purged with helium and contained a sodium hydroxide pellet to halt metabolic activity; each vial was sealed with a butyl rubber septum and stored inverted. Nitrous oxide concentrations were measured using a gas chromatograph (Shimadzu GC8A) equipped with an electron capture detector.;
Data Quality Method: The detection limit for this method, defined as 3 times the standard deviation of the concentrations measured in field blanks (n = 41), was 31 nmol/L. Samples with measured concentrations below this detection limit are marked "NaN"</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
        </gmd:LI_Lineage>
      </gmd:lineage>
    </gmd:DQ_DataQuality>
  </gmd:dataQualityInfo>
  <gmd:metadataMaintenance>
    <gmd:MD_MaintenanceInformation>
      <gmd:maintenanceAndUpdateFrequency>
        <gmd:MD_MaintenanceFrequencyCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_MaintenanceFrequencyCode" codeListValue="asNeeded">asNeeded</gmd:MD_MaintenanceFrequencyCode>
      </gmd:maintenanceAndUpdateFrequency>
      <gmd:maintenanceNote>
        <gco:CharacterString>Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.</gco:CharacterString>
      </gmd:maintenanceNote>
      <gmd:contact>
        <gmd:CI_ResponsibleParty>
          <gmd:organisationName>
            <gco:CharacterString>NOAA National Centers for Environmental Information</gco:CharacterString>
          </gmd:organisationName>
          <gmd:role>
            <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="custodian">custodian</gmd:CI_RoleCode>
          </gmd:role>
        </gmd:CI_ResponsibleParty>
      </gmd:contact>
    </gmd:MD_MaintenanceInformation>
  </gmd:metadataMaintenance>
  <gmi:acquisitionInformation>
    <gmi:MI_AcquisitionInformation id="AMS">
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_bef3">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>multi-parameter water quality sensor</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>multi-parameter water quality sensor</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>used to measure temperature, salinity, dissolved oxygen, and other parameters

Instrument used to measure temperature, salinity, dissolved oxygen, and other parameters, often used to measure water quality parameters. Can be a hand-held instrument or a sonde for unattended monitoring. Often used in coastal water monitoring stations. YSI is the preeminent brand (as of 2024).</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
    </gmi:MI_AcquisitionInformation>
  </gmi:acquisitionInformation>
</gmi:MI_Metadata>