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              <gmd:title>
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                    <gmd:URL>https://www.ncei.noaa.gov/archive/accession/oas/123317</gmd:URL>
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                  <gmd:protocol>
                    <gco:CharacterString>HTTPS</gco:CharacterString>
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                  <gmd:applicationProfile>
                    <gco:CharacterString>Web browser</gco:CharacterString>
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                    <gco:CharacterString>Descriptive Information</gco:CharacterString>
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                    <gco:CharacterString>Navigate directly to the URL for a descriptive web page with download links.</gco:CharacterString>
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                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
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                  <gmd:protocol>
                    <gco:CharacterString>HTTPS</gco:CharacterString>
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                  <gmd:applicationProfile>
                    <gco:CharacterString>Web browser</gco:CharacterString>
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                  <gmd:name>
                    <gco:CharacterString>HTTPS</gco:CharacterString>
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                  <gmd:description>
                    <gco:CharacterString>Navigate directly to the URL for data access and direct download.</gco:CharacterString>
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                    <gmd:URL>ftp://ftp-oceans.ncei.noaa.gov/nodc/archive/arc0072/0123317/</gmd:URL>
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                  <gmd:protocol>
                    <gco:CharacterString>FTP</gco:CharacterString>
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                    <gco:CharacterString>FTP</gco:CharacterString>
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                    <gco:CharacterString>These data are available through the File Transfer Protocol (FTP). FTP is no longer supported by most internet browsers. You may copy and paste the FTP link to the data into an FTP client (e.g., FileZilla or WinSCP).</gco:CharacterString>
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                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="download">download</gmd:CI_OnLineFunctionCode>
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                                <gmd:CI_OnlineResource>
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                                    <gmd:URL>https://www.ncei.noaa.gov/archive/accession/0123317/1.1</gmd:URL>
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                                    <gco:CharacterString>NCEI Accession 0123317 v1.1</gco:CharacterString>
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                                    <gco:CharacterString>published 2014-12-29T13:23:06Z</gco:CharacterString>
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            <gmd:MD_ScopeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_ScopeCode" codeListValue="nonGeographicDataset">nonGeographicDataset</gmd:MD_ScopeCode>
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            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Dissolved Inorganic Carbon;
Abbreviation: DIC;
Unit: umol/kg;
Observation type: Dissolved inorganic carbon;
In-situ / Manipulation / Response variable: manipulation condition;
Measured or calculated: Measured;
Sampling instrument: manual;
Analyzing instrument: Carbon Coulometer (UIC, Inc.);
Detailed sampling and analyzing information: Column samples were collected by hand using a tube attached to the bypass at the base of each CO2 addition column. Experimental container samples were extracted and transfered to sample bottles using a 60 mL syringe. All samples were collected in a 300mL glass BOD bottle by filling from the bottom of the bottle. A 25mL sample was extracted with a syringe, weighed, and the added to 8.5% phosphoric acid in an acid stripping chamber. The empty syringe was reweighed to get sample weight. Sample CO2 was transferred to the coulometer using a CO2 free gas. Coulometer had been modified with an emulator chip to give output in counts.;
Replicate information: no field replicates collected;
Standardization description: Three calcium carbonate standards were created and analyzed to produce a standard curve. A CRM was also analyzed at the beginning and end of a daily sample analysis. The standard curve was used to determine the measured value for the first CRM. The % difference between the measured CRM value and its true value was used to adjust the sample values calculated from the coulometer output and the standard curve. The difference in the measured value for the second CRM compared to its true value was used to determine measurement uncertainty.;
Standardization frequency: Daily;
CRM manufacturer: Dickson Lab at UCSD;
Preservation method: Saturated solution of mercuric chloride;
Preservative volume: 0.06mL;
Method reference: SOP 2 in Dickson, A.G., Sabine, C.L. and Christian, J.R. (Eds.) 2007. Guide to best practices for ocean CO2 measurements. PICES Special Publication 3, 191 pp.;
Researcher name: Matthew Poach;
Researcher institution: NOAA-James J. Howard Lab</gco:CharacterString>
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          <gmd:processStep>
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              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Total alkalinity;
Abbreviation: ALK;
Unit: umol/kg;
Observation type: Laboratory experiment;
In-situ / Manipulation / Response variable: manipulation condition;
Measured or calculated: calculated;
Researcher name: Daniel Wieczorek;
Researcher institution: Northeast Fisheries Science Center, National Marine Fisheries Service, National Oceanic and Atmospheric Administration</gco:CharacterString>
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            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: pH;
Abbreviation: Spectrophotometer pH;
pH scale: total;
Observation type: pH;
In-situ / Manipulation / Response variable: manipulation condition;
Measured or calculated: measured;
Sampling instrument: manual;
Analyzing instrument: dual beam spectrophotometer (Varian/Agilent -Cary 300);
Temperature of pH measurement: provided in data file (~25 C);
Detailed sampling and analyzing information: Samples were collected according to location. Samples from the columns were collected in a 250mL plastic bottle and transfer by pouring into a 100mm spec cell. Samples from experimental containers or from DIC sample bottles were collected and transferred to a spec cell using a 60mL syringe. The spectrophotometer was then used to determine absorbances at wavelengths of 434, 578, and 730 for a sample without and then with 2mM m-cresol purple dye added. The absorbance values were used to determine pH according to the citation given below;
Replicate information: no field replicates;
Standardization description: A tris buffer obtained from the Dickson lab at UCSD was analyzed to check the functioning of the instrument and quality of the dye solution;
Standardization frequency: start of experiment;
Temperature of standardization: 25 C;
Temperature correction method: NA;
At what temperature was pH reported: provided in data file;
Method reference: SOP 6b in Dickson, A.G., Sabine, C.L. and Christian, J.R. (Eds.) 2007. Guide to best practices for ocean CO2 measurements. PICES Special Publication 3, 191 pp.;
Researcher name: Matthew Poach;
Researcher institution: NOAA-James J. Howard Lab</gco:CharacterString>
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              <gmd:description>
                <gco:CharacterString>Parameter or Variable: pCO2 (fCO2) autonomous;
Abbreviation: pCO2;
Unit: uatm;
Observation type: Laboratory experiment;
In-situ / Manipulation / Response variable: manipulation condition;
Measured or calculated: Calculated</gco:CharacterString>
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            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Durfet pH;
Abbreviation: Durfet pH;
Observation type: Laboratory experiment;
In-situ / Manipulation / Response variable: manipulation condition;
Measured or calculated: Measured;
Sampling instrument: Durfet iii;
Analyzing instrument: Honeywell UDA Analyzer;
Duration: 53.3 days;
Detailed sampling and analyzing information: Durfet installed on each treatment column;
Species ID: Paralichthys dentatus;
Researcher name: Daniel Wieczorek;
Researcher institution: National Marine Fisheries Service</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Electrode pH;
Abbreviation: Electrode pH;
Observation type: Laboratory experiment;
In-situ / Manipulation / Response variable: manipulation condition;
Measured or calculated: Measured;
Sampling instrument: Orion pH electrode;
Analyzing instrument: Hanna;
Duration: 53.3 days;
Detailed sampling and analyzing information: Water samples taken from treatment columns.;
Species ID: Paralichthys dentatus;
Researcher name: Daniel Wieczorek;
Researcher institution: National Marine Fisheries Service</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Salinity;
Abbreviation: Salinity;
Observation type: Laboratory experiment;
In-situ / Manipulation / Response variable: manipulation condition;
Measured or calculated: Measured;
Analyzing instrument: traceable conductivity meter from Control Company;
Duration: 53.3 days;
Detailed sampling and analyzing information: Measurements taken prior to analysis on spec.;
Species ID: Paralichthys dentatus;
Researcher name: Daniel Wieczorek;
Researcher institution: National Marine Fisheries Service</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Spectrophotometer Temp;
Abbreviation: Spectrophotometer Temp;
Observation type: Laboratory experiment;
In-situ / Manipulation / Response variable: manipulation condition;
Measured or calculated: Measured;
Analyzing instrument: traceable digital thermometer from Fisher Scientific;
Duration: 53.3 days;
Detailed sampling and analyzing information: Measurements taken prior to analysis on spec.;
Species ID: Paralichthys dentatus;
Researcher name: Daniel Wieczorek;
Researcher institution: National Marine Fisheries Service</gco:CharacterString>
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          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Sample Temp;
Abbreviation: Sample Temp;
Observation type: Laboratory experiment;
In-situ / Manipulation / Response variable: manipulation condition;
Measured or calculated: Measured;
Sampling instrument: Durfet iii;
Analyzing instrument: Honeywell UDA Analyzer;
Duration: 53.3 days;
Detailed sampling and analyzing information: Durfet installed on each treatment column;
Species ID: Paralichthys dentatus;
Researcher name: Daniel Wieczorek;
Researcher institution: National Marine Fisheries Service</gco:CharacterString>
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                <gco:CharacterString>NOAA National Centers for Environmental Information</gco:CharacterString>
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                <gco:CharacterString>NOAA created the National Centers for Environmental Information (NCEI) by merging NOAA's National Climatic Data Center (NCDC), National Geophysical Data Center (NGDC), and National Oceanographic Data Center (NODC), including the National Coastal Data Development Center (NCDDC), per the Consolidated and Further Continuing Appropriations Act, 2015, Public Law 113-235. NCEI launched publicly on April 22, 2015.</gco:CharacterString>
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                <gco:DateTime>2015-04-22T00:00:00</gco:DateTime>
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      <gmd:maintenanceNote>
        <gco:CharacterString>Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.</gco:CharacterString>
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      <gmd:contact>
        <gmd:CI_ResponsibleParty>
          <gmd:organisationName>
            <gco:CharacterString>NOAA National Centers for Environmental Information</gco:CharacterString>
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          <gmd:role>
            <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="custodian">custodian</gmd:CI_RoleCode>
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    <gmi:MI_AcquisitionInformation id="AMS">
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be73">
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            <gco:CharacterString>spectrophotometer, optical spectrometer, spectrograph or spectroscope

An optical spectrometer (spectrophotometer, spectrograph or spectroscope) is an instrument used to measure properties of light over a specific portion of the electromagnetic spectrum, typically used in spectroscopic analysis to identify materials.

Butler, L. R. P.; Laqua, K. (1995). "Nomenclature, symbols, units and their usage in spectrochemical analysis-IX. Instrumentation for the spectral dispersion and isolation of optical radiation (IUPAC Recommendations 1995)". Pure Appl. Chem. IUPAC. 67 (10): 1725–1744. doi:10.1351/pac199567101725. A spectrometer is the general term for describing a combination of spectral apparatus with one or more detectors to measure the intensity of one or more spectral bands."</gco:CharacterString>
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