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                <gco:CharacterString>Parameter or Variable: Change in seawater content of anthropogenic CO2;
Abbreviation: dcant;
Observation type: Observation-based reconstruction with statistical method (eMLR(C*));
Calculation method and parameters: The observation-based estimates of the change in anthropogenic CO2 content (ΔCant) in the ocean between 1994, 2004 and 2014 were generated using the eMLR(C*) method introduced and described in detail by Clement and Gruber (2018). Briefly, this method relies on dissolved inorganic carbon (DIC) observations from GLODAPv2.2021 (Lauvset et al., 2021), which are processed in three steps. In the first step, the semi-conservative tracer C* = DIC – 117×[PO43-] – 0.5×(TA + 16×[PO43-]) is computed from the measured DIC, alkalinity [TA] and phosphate ([PO43-]) content assuming constant stoichiometric C:P (117:1) and N:P (16:1) ratios during photosynthesis and respiration. In the second step, all data are allocated to either the first (1989–1999), second (2000–2009), or third (2010–2020) sampling period and then adjusted to the reference year of the respective period (1994, 2004 or 2014) based on a transient steady state assumption. In the third step, the data from each sampling period are fitted using multiple linear regression (MLR) models with a combination of up to seven predictor variables. For the MLR fitting, the data are vertically binned into ranges of neutral density, i.e., isoneutral slabs, and horizontally into ocean basins. The best fitting MLR models for each spatial bin and each pair of two sampling periods are selected and then used together with climatological distributions of the predictor variables to map out C* for each reference year to the global ocean. Finally, ΔCant is determined as the difference between two C* distribution fields. A suite of 10 sensitivity cases were run in order to explore the robustness of the estimated ΔCant to a range of subjective choices in the estimation procedure. These subjective choices can be categorised into two main groups, namely the basin mask definition used for the horizontal binning of the data and the exact configuration of the eMLR(C*) method.</gco:CharacterString>
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Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
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