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                <gco:CharacterString>OCADS Study Type</gco:CharacterString>
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            <gco:CharacterString>ALKALI</gco:CharacterString>
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            <gco:CharacterString>CTDSAL</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>CTDTMP</gco:CharacterString>
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            <gco:CharacterString>OXYGEN</gco:CharacterString>
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            <gco:CharacterString>SILCAT, NITRAT, NITRIT, PHSPHT</gco:CharacterString>
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      <gmd:descriptiveKeywords>
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            <gco:CharacterString>Distribution liability: NOAA and NCEI make no warranty, expressed or implied, regarding these data, nor does the fact of distribution constitute such a warranty. NOAA and NCEI cannot assume liability for any damages caused by any errors or omissions in these data. If appropriate, NCEI can only certify that the data it distributes are an authentic copy of the records that were accepted for inclusion in the NCEI archives.</gco:CharacterString>
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            <gco:CharacterString>Use liability: NOAA and NCEI cannot provide any warranty as to the accuracy, reliability, or completeness of furnished data. Users assume responsibility to determine the usability of these data. The user is responsible for the results of any application of this data for other than its intended purpose.</gco:CharacterString>
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      <gmd:resourceConstraints xlink:title="Data License Statement">
        <gmd:MD_LegalConstraints>
          <gmd:useConstraints>
            <gmd:MD_RestrictionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_RestrictionCode" codeListValue="license">license</gmd:MD_RestrictionCode>
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            <gmx:Anchor xlink:href="https://creativecommons.org/publicdomain/zero/1.0/" xlink:actuate="onRequest" xlink:title="CC0-1.0">These data were produced by NOAA and are not subject to copyright protection in the United States. NOAA waives any potential copyright and related rights in these data worldwide through the Creative Commons Zero 1.0 Universal Public Domain Dedication (CC0-1.0).</gmx:Anchor>
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          <gmd:otherConstraints>
            <gmx:Anchor xlink:href="https://spdx.org/licenses/CC0-1.0" xlink:actuate="onRequest" xlink:title="CC0-1.0">SPDX License: Creative Commons Zero v1.0 Universal (CC0-1.0)</gmx:Anchor>
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                <gco:CharacterString>Parameter or Variable: Dissolved Inorganic Carbon;
Abbreviation: TCARBN;
Unit: UMOL/KG;
Observation type: Discrete, bottle;
Measured or calculated: Measured;
Sampling instrument: Niskin Bottles;
Analyzing instrument: coulometry with analytical system;
Detailed sampling and analyzing information: In coulometric analysis of DIC, all carbonate species are converted to CO2 by addition of excess hydrogen ion (acid) to the seawater sample, and the evolved CO2 is swept into the titration cell of the coulometer with CO2 free dry air or compressed nitrogen where it reacts quantitatively with a proprietary reagent based on ethanolamine to generate hydrogen ions. In this process, the solution changes from blue to colorless, triggering a current through the cell and causing coulometric generation of OH- ions at the anode. The OH- ions react with the H+ and the solution turns blue again. A beam of light is shone through the solution, and a photometric detector at the opposite side of the cell senses the change in transmission. Once the percent transmission reaches its original value, the coulometric titration is stopped, and the amount of CO2 that enters the cell is determined by integrating the total change during the titration.;
Standardization frequency: Daily;
CRM manufacturer: Andrew Dickson Laboratory at SIO;
CRM batch number: 206;
Preservation method: Mercuric chloride solution;
Preservative volume: 200 μL;
Uncertainty: The accuracy of the DICE measurement is determined with the use of CRMs consisting of filtered and UV irradiated seawater, supplied by Dr. A. Dickson of SIO. The CRM accuracy is determined manometrically on land at SIO, and the DIC data reported have been corrected to the certified values (DIC = 2021.55 μmol kg-1; salinity = 33.4230 PSU) for CRM batch 206. The summary table below1 lists information for the CRMs. The precision of the two DICE systems can be demonstrated via the replicate samples. Approximately 6% of the total niskins sampled during the cruise were duplicates taken as a check of our precision. These replicate samples were interspersed throughout the station analysis for quality assurance and integrity of the coulometer cell solutions. The average absolute difference from the mean of these replicates was 0.86 μmol kg-1; no systematic differences between the replicates were observed.;
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value;
Method reference: Guide to Best Practices for Ocean CO2 Measurements [Dickson2007]);
Researcher name: Rik Wanninkhoff, Richard Feely;
Researcher institution: NOAA/PMEL/AOML/</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Total alkalinity;
Abbreviation: ALKALI;
Unit: UMOL/KG;
Observation type: Discrete, bottle;
Measured or calculated: Measured;
Sampling instrument: Niskin Bottles;
Type of titration: Potentiometric;
Cell type (open or closed): Open;
Detailed sampling and analyzing information: Alkalinity samples are drawn using silicone tubing connected to the niskin bottle and collected into 250 mL Pyrex bottles. The sample bottles and Teflon-sleeved glass stoppers were rinsed at least twice before the final filling. A headspace of approximately 3 mL was removed and 0.1 mL of 50% saturated mercuric chloride solution was added to each sample for preservation. The samples were equilibrated prior to analysis at approximately 20°C using a Thermo Scientific Isotemp water bath. Samples for total alkalinity were taken at all stations where a core cast was completed. Alkalinity samples were collected from each niskin where DIC and pH were collected, to completely characterize the CO2 system. The typical sample scheme was as follows: A full collection every 5 stations (36 niskins), a half collection every 5 stations (16 niskins), and partial collections (27 niskins) on the stations in-between. To evaluate the reproducibility of the alkalinity system, 2 duplicate samples (two separate alkalinity bottles) were collected on each cast, except for casts with fewer than 18 bottles, in which 1 duplicate sample was collected.;
Standardization description: The samples were standardized using Certified Reference Materials (CRMs) provided by Dr. A. Dickson of Scripps Institution of Oceanography.;
Standardization frequency: Daily;
CRM manufacturer: Certified Reference Material (Dr. Andrew Dickson, Marine Physical Laboratory, La Jolla, California);
CRM batch number: Batch 206, 207;
Preservation method: Mercuric chloride;
Preservative volume: 200 μL;
Uncertainty: Duplicate precision: ± 1.02 μmol kg-1 (n = 318 pairs);
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value;
Method reference: Dickson 2007;
Researcher name: Andrew Dickson;
Researcher institution: SIO</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: pH on total scale;
Abbreviation: PH_TOT;
Observation type: discrete, bottle;
Sampling instrument: Niskin Bottles;
Analyzing instrument: Agilent 8453 spectrophotometer;
Detailed sampling and analyzing information: pHT was measured spectrophotometrically on the total hydrogen scale using an Agilent 8453 spectrophotometer and in accordance with the methods outlined by Carter et al, 2013. A Kloehn V6 syringe pump was used to autonomously fill, mix, and dispense sample through the custom 10cm flow-through jacketed cell. A Thermo Fisher Isotemp recirculating water bath was used to maintain the cell temperature at 25.0°C during analyses, and a YSI 4600 precision thermometer and probe were used to monitor and record the temperature of each sample during the spectrophotometric measurements. Purified meta-cresol purple (mCP) was the indicator used to measure the absorbance of light measured at two different wavelengths (434 nm, 578 nm) corresponding to the maximum absorbance peaks for the acidic and basic forms of the indicator dye. A baseline absorbance was also measured and subtracted from these wavelengths. The baseline absorbance was determined by averaging the absorbances from 725-735nm. The ratio of the absorbances was then used to calculate pH on the total scale using the equations outlined in Liu et al., 2011. The salinity data used was obtained from the salinity analysis conducted on board.;
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value;
Researcher name: Andrew Dickson;
Researcher institution: SIO</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Dissolved Organic Carbon;
Abbreviation: DOC;
Unit: UMOL/KG;
Observation type: CTD Niskin Bottles;
Sampling instrument: CTD Niskin Bottles;
Analyzing instrument: DOC samples will be analyzed via high temperature combustion using a Shimadzu TOC-V or Shimadzu TOC-L at an inshore based laboratory at UCSB.;
Detailed sampling and analyzing information: The goal of the DOM project is to provide high resolution, long term monitoring of DOC/TDN distribution throughout the water column, in order to help better understand biogeochemical cycling in global oceans. For 2023 the Carlson Lab at UCSB will evaluate dissolved organic carbon (DOC) and total dissolved nitrogen (TDN) concentrations along the US GO-SHIP I05 transect (114E to 30E along ~32S).;
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value;
Researcher name: Craig Carlson (UCSB);
Researcher institution: UCSB</gco:CharacterString>
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Abbreviation: CTDTMP;
Unit: degrees celcius;
Observation type: CTD sensor;
Sampling instrument: CTD;
Analyzing instrument: CTD;
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value;
Researcher name: Todd Martz;
Researcher institution: SIO</gco:CharacterString>
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Abbreviation: CTDSAL;
Observation type: CTD sensor;
Sampling instrument: CTD;
Analyzing instrument: CTD;
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value;
Researcher name: Todd Martz;
Researcher institution: SIO</gco:CharacterString>
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Abbreviation: SILCAT, NITRAT, NITRIT, PHSPHT;
Unit: UMOL/KG;
Observation type: Bottle, discrete;
Sampling instrument: CTD Niskin Bottles;
Analyzing instrument: Discrete samples were run on a continuous flow analyzer.;
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value;
Researcher name: Susan Becker;
Researcher institution: SIO</gco:CharacterString>
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Abbreviation: OXYGEN;
Unit: UMOL/KG;
Observation type: Bottle, discrete;
Sampling instrument: CTD Niskin Bottles;
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value;
Researcher name: Susan Becker, Jim Swift;
Researcher institution: SIO</gco:CharacterString>
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Abbreviation: CFC11, CFC12, CFC113;
Unit: PMOL/KG;
Observation type: Bottle, discrete;
Sampling instrument: CTD Niskin Bottles;
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value;
Researcher institution: UW</gco:CharacterString>
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          <gmi:description>
            <gco:CharacterString>measures gaseous carbon dioxide

Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption.

Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_bee7">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>CTD</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>CTD</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>Conductivity-Temperature-Depth probe</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be3d">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>Niskin bottle</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>Niskin bottle</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>Device for obtaining samples of seawater at a specific depth

Why special entry for Niskin bottle but no entry for Nansen bottle?</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be48">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>nutrient autoanalyzer</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>nutrient autoanalyzer</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>Laboratory Instrument

Nutrient Autoanalyzer is a generic term describing an automated flow-thru system used to conduct analyses of several different nutrients (nitrate, ammonium, orthophosphate, and silicate) simultaneously from a seawater sample.

For example:
SEAL AutoAnalyzer 3 HR Continuous Segmented Flow Analyzer</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_bef4">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>oxygen sensor</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>oxygen sensor</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>Any instrument that measures oxygen content in a compound.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_bedd">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>pH sensor</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>pH sensor</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>generic meter used to measure pH

Any of a class of instruments used to quantify pH in a water or other type of sample.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_bea4">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>salinometer</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>salinometer</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>generic salinometer

use salinometer when the instrument type used is unclear but the data include salinity measurements</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be41">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>temperature sensor</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>temperature sensor</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>A sensor used to measure temperature.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be28">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>titrator</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>titrator</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>titrator</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:platform>
        <gmi:MI_Platform id="plat_a534">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>R/V Roger Revelle</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:description>
            <gco:CharacterString>Flag: United States
Type: Research Vessel
IMO: 9075228
Company: Scripps Institution of Oceanography
DOB: 1996-06

https://scripps.ucsd.edu/ships/revelle</gco:CharacterString>
          </gmi:description>
          <gmi:instrument gco:nilReason="missing" />
        </gmi:MI_Platform>
      </gmi:platform>
    </gmi:MI_AcquisitionInformation>
  </gmi:acquisitionInformation>
</gmi:MI_Metadata>