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                <gco:CharacterString>Parameter or Variable: pCO2 (fCO2) autonomous;
Abbreviation: pCO2_SW@SST;
Unit: uatm;
Observation type: Surface underway;
Measured or calculated: Measured;
Calculation method and parameters: following Pierrot et al. (2009), Deep-Sea Res.;
Sampling instrument: Seawater pump described in Arevalo-Martinez et al. (2013), Ocean Sci., https://doi.org/10.5194/os-9-1071-2013;
Location of seawater intake: ships moonpool;
Analyzing instrument: Infrared Analyzer: LI-COR model 6252;
Detailed sampling and analyzing information: Arevalo-Martinez, D.L., M. Beyer, M. Krumbholz, I. Piller, A. Kock, T. Steinhoff, A. Körtzinger, and H. W. Bange (2013). A new method for continuous measurements of oceanic and atmospheric N2O, CO and CO2: performance of off-axis integrated cavity output spectroscopy (OA-ICOS) coupled to non-dispersive infrared detection (NDIR). Ocean Sci., 9, 1071-1087, https://doi.org/10.5194/os-9-1071-2013.;
Equilibrator type: Spray head above dynamic pool, with thermal jacket;
Equilibrator volume: 0.95 L (0.4 L water, 0.55 L headspace);
Is the equilibrator vented or not: Vented;
Water flow rate: 2-3 L min-1;
Gas flow rate: 100 mL min-1;
How was temperature inside the equilibrator measured: Due to a broken temperature probe, we used the temperature of an Aanderaa Optode that was placed in a continously flushed water bath next to the equilibrator. We still estimate the accuracy of the equilibrator to 0.05 deg C.;
How was pressure inside the equilibrator measured: The equilibrator is open to the atmosphere. Here we assume to have atmospheric pressure in the equilibration chamber.;
Drying method for gas: ice cooled column and subsequent Nafion dryer;
SEA CO2 gas detector manufacturer: Licor, Inc;
SEA CO2 gas detector model: Licor 6262;
SEA CO2 gas detector resolution: Accuracy: +/- 2 uatm in fCO2_SW;
SEA CO2 gas detector uncertainty: +/- 0.5 ppm;
Standardization technique: calibrated against NOAA/CMDL standard gases. Resulting uncertainty: +/- 0.5 ppm.;
Standardization frequency: every 4 hours;
Standard gas manufacturer: Deuste Steininger;
Standard gas concentration: 208.96 402 602.4;
Standard gas uncertainty: 0.5;
At what temperature was pCO2 reported: SST;
Uncertainty: 5 uatm;
Researcher name: Tobias Steinhoff;
Researcher institution: GEOMAR Helmholtz Centre for Ocean Research Kiel</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Sea Surface Temperature;
Abbreviation: SST;
Unit: Deg. C;
Observation type: Surface underway;
Sampling instrument: pump at approximately 6 m depth;
Analyzing instrument: Seabird (SBE37);
Uncertainty: +/- 0.05 deg C;
Researcher name: Tobias Steinhoff;
Researcher institution: GEOMAR Helmholtz Centre for Ocean Research Kiel</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Sea Surface Salinity;
Abbreviation: SSS;
Observation type: Surface underway;
Sampling instrument: pump at approximately 6 m depth;
Analyzing instrument: Seabird (SBE37);
Uncertainty: +/- 0.1;
Researcher name: Tobias Steinhoff;
Researcher institution: GEOMAR Helmholtz Centre for Ocean Research Kiel</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Equilibrator temperature;
Abbreviation: Equi Temp;
Unit: Deg. C;
Observation type: Surface underway;
Uncertainty: +/-0.05 deg C;
Researcher name: Tobias Steinhoff;
Researcher institution: GEOMAR Helmholtz Centre for Ocean Research Kiel</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Athmospheric Presuure;
Abbreviation: Atm. Pressure;
Unit: mbar;
Analyzing instrument: The atmospheric pressure was measured by the ships weather station;
Uncertainty: +/- 0.1 mbar;
Researcher name: Tobias Steinhoff;
Researcher institution: GEOMAR Helmholtz Centre for Ocean Research Kiel</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Equilibrator Pressure;
Abbreviation: Equi Press;
Unit: mbar;
Analyzing instrument: The equilibrator is open to the atmosphere. Here we assume to have atmospheric pressure in the equilibration chamber;
Uncertainty: +/- 0.1 mbar;
Researcher name: Tobias Steinhoff;
Researcher institution: GEOMAR Helmholtz Centre for Ocean Research Kiel</gco:CharacterString>
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        <gmd:MD_MaintenanceFrequencyCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_MaintenanceFrequencyCode" codeListValue="asNeeded">asNeeded</gmd:MD_MaintenanceFrequencyCode>
      </gmd:maintenanceAndUpdateFrequency>
      <gmd:maintenanceNote>
        <gco:CharacterString>Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.</gco:CharacterString>
      </gmd:maintenanceNote>
      <gmd:contact>
        <gmd:CI_ResponsibleParty>
          <gmd:organisationName>
            <gco:CharacterString>NOAA National Centers for Environmental Information</gco:CharacterString>
          </gmd:organisationName>
          <gmd:role>
            <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="custodian">custodian</gmd:CI_RoleCode>
          </gmd:role>
        </gmd:CI_ResponsibleParty>
      </gmd:contact>
    </gmd:MD_MaintenanceInformation>
  </gmd:metadataMaintenance>
  <gmi:acquisitionInformation>
    <gmi:MI_AcquisitionInformation id="AMS">
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be58">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>carbon dioxide (CO2) gas analyzer</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>carbon dioxide (CO2) gas analyzer</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>measures gaseous carbon dioxide

Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption.

Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be57">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>showerhead equilibrator</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>showerhead equilibrator</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>extracts dissolved CO2 from water

A carbon dioxide equilibrator is usually in the shape of a vertical tube, with a showerhead on the top, some headspace, a lot of beads to increase the surface exchange area between water and air, a water seal device at the bottom to allow water to overflow, but prevents air exchange between inside and outside.

Carbon dioxide (CO2) equilibrator works together with carbon dioxide (CO2) gas analyzer (insttypes_id 183) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:platform>
        <gmi:MI_Platform id="plat_be00">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>SONNE</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:description>
            <gco:CharacterString>SONNE</gco:CharacterString>
          </gmi:description>
          <gmi:instrument gco:nilReason="missing" />
        </gmi:MI_Platform>
      </gmi:platform>
    </gmi:MI_AcquisitionInformation>
  </gmi:acquisitionInformation>
</gmi:MI_Metadata>