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                                    <gmd:URL>https://www.ncei.noaa.gov/archive/accession/0112841/2.2</gmd:URL>
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                <gco:CharacterString>Parameter or Variable: Dissolved Inorganic Carbon;
Abbreviation: DIC;
Observation type: discrete;
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Calculated;
Detailed sampling and analyzing information: A VINDTA 3C system [Mintrop et al., 2000] (www.MARIANDA.com), with coulometer determination was used for the titration of the total dissolved inorganic carbon after phosphoric acid addition. The titration of CRMs (#85) was used to test the performance of the equipment after the preparation of each titration cell. Over 30 bottles were analysed on board with a system precision of ± 1.5 μmol kg-1.</gco:CharacterString>
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Abbreviation: TA;
Observation type: discrete;
In-situ / Manipulation / Response variable: in-situ observation;
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Type of titration: potentiometric titration;
Curve fitting method: Samples for AT were potentiometrically titrated with standardized 0.25 M HCl (0.45M in NaCl) to the carbonic acid end point using a systems described in detail by Mintrop et al. [2000]. The titration of certify reference Material for Oceanic CO2, CRMs (#85) was used to test the performance of the titration system given values that were within ± 1.0 μmol kg-1 of the certified value.;
Uncertainty: Each CRM sample was also analysed for total alkalinity determination, and the corresponding chart sheet is presented in Figure 42. The agreement between on board experimental data (NAT = 2293.7 ± 1.0) and certify value (NAT = 2293.7 ± 0.8) indicates accurate HCl concentration and pipette volume for the titration system.</gco:CharacterString>
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In-situ / Manipulation / Response variable: in-situ observation;
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Detailed sampling and analyzing information: The pH is measured in total scale ([H+]T = [H+]F + [HSO4-], where [H+]F is the free proton concentration), pHT at a constant temperature of 25oC. An automatized system based on the spectrophotometric technique of Clayton and Byrne [1993] with the m-cresol purple as indicator was used [González-Dávila et al., 2003].</gco:CharacterString>
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Abbreviation: CTDSAL;
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Abbreviation: CTDOXY;
Unit: UMOL/KG;
Controlled vocabulary name: DISSOLVED OXYGEN;
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Unit: UMOL/KG;
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Abbreviation: SILCAT;
Unit: UMOL/KG;
Controlled vocabulary name: silicate;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
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Abbreviation: NITRAT;
Unit: UMOL/KG;
Controlled vocabulary name: NITRATE;
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Abbreviation: PHSPHT;
Unit: UMOL/KG;
Controlled vocabulary name: phosphate;
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          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: NH4;
Abbreviation: NH4;
Unit: UMOL/KG;
Controlled vocabulary name: AMMONIUM (NH4);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: CFC-11;
Abbreviation: CFC-11;
Unit: PMOL/KG;
Controlled vocabulary name: CHLOROFLUOROCARBON-11 (CFC-11);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: CFC-12;
Abbreviation: CFC-12;
Unit: PMOL/KG;
Controlled vocabulary name: CHLOROFLUOROCARBON-12 (CFC-12);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: CFC-113;
Abbreviation: CFC-113;
Unit: PMOL/KG;
Controlled vocabulary name: CHLOROFLUOROCARBON-113 (CFC-113);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: CCL4;
Abbreviation: CCL4;
Unit: PMOL/KG;
Controlled vocabulary name: Carbon tetrachloride (CCL4);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: TCARBN;
Abbreviation: TCARBN;
Unit: UMOL/KG;
Controlled vocabulary name: DISSOLVED INORGANIC CARBON (DIC);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: ALKALI;
Abbreviation: ALKALI;
Unit: UMOL/KG;
Controlled vocabulary name: total alkalinity;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: PH_TOT;
Abbreviation: PH_TOT;
Controlled vocabulary name: pH;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: PH_TMP;
Abbreviation: PH_TMP;
Unit: DEG_C;
Controlled vocabulary name: pH;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: THETA;
Abbreviation: THETA;
Unit: DEG_C;
Controlled vocabulary name: Potential temperature (theta);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
        </gmd:LI_Lineage>
      </gmd:lineage>
    </gmd:DQ_DataQuality>
  </gmd:dataQualityInfo>
  <gmd:dataQualityInfo>
    <gmd:DQ_DataQuality>
      <gmd:scope>
        <gmd:DQ_Scope>
          <gmd:level>
            <gmd:MD_ScopeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_ScopeCode" codeListValue="repository">repository</gmd:MD_ScopeCode>
          </gmd:level>
          <gmd:levelDescription>
            <gmd:MD_ScopeDescription>
              <gmd:other>
                <gco:CharacterString>NOAA National Centers for Environmental Information</gco:CharacterString>
              </gmd:other>
            </gmd:MD_ScopeDescription>
          </gmd:levelDescription>
        </gmd:DQ_Scope>
      </gmd:scope>
      <gmd:lineage>
        <gmd:LI_Lineage>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>NOAA created the National Centers for Environmental Information (NCEI) by merging NOAA's National Climatic Data Center (NCDC), National Geophysical Data Center (NGDC), and National Oceanographic Data Center (NODC), including the National Coastal Data Development Center (NCDDC), per the Consolidated and Further Continuing Appropriations Act, 2015, Public Law 113-235. NCEI launched publicly on April 22, 2015.</gco:CharacterString>
              </gmd:description>
              <gmd:dateTime>
                <gco:DateTime>2015-04-22T00:00:00</gco:DateTime>
              </gmd:dateTime>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
        </gmd:LI_Lineage>
      </gmd:lineage>
    </gmd:DQ_DataQuality>
  </gmd:dataQualityInfo>
  <gmd:metadataMaintenance>
    <gmd:MD_MaintenanceInformation>
      <gmd:maintenanceAndUpdateFrequency>
        <gmd:MD_MaintenanceFrequencyCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_MaintenanceFrequencyCode" codeListValue="asNeeded">asNeeded</gmd:MD_MaintenanceFrequencyCode>
      </gmd:maintenanceAndUpdateFrequency>
      <gmd:maintenanceNote>
        <gco:CharacterString>Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.</gco:CharacterString>
      </gmd:maintenanceNote>
      <gmd:contact>
        <gmd:CI_ResponsibleParty>
          <gmd:organisationName>
            <gco:CharacterString>NOAA National Centers for Environmental Information</gco:CharacterString>
          </gmd:organisationName>
          <gmd:role>
            <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="custodian">custodian</gmd:CI_RoleCode>
          </gmd:role>
        </gmd:CI_ResponsibleParty>
      </gmd:contact>
    </gmd:MD_MaintenanceInformation>
  </gmd:metadataMaintenance>
  <gmi:acquisitionInformation>
    <gmi:MI_AcquisitionInformation id="AMS">
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_beec">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>bottle</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>bottle</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>any type of water bottle sampling device

Generic name for water collection device; usually used to determine temperature, salinity and provide water aliquots for measurement of a wide range of parameters; often referred to by a specific type of water sampling bottle, such as a Nansen or Niskin bottle.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be29">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>coulometer for DIC measurement</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>coulometer for DIC measurement</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>measures dissolved inorganic carbon (DIC)

A known amount of seawater is dispensed into a stripping chamber where it is acidified and purged with an inert gas. The amount of CO2 in the resulting gas stream is determined by absorbing the CO2 in an absorbent. The pH of the solution is monitored by measuring the transmittance .</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_bee7">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>CTD</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>CTD</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>Conductivity-Temperature-Depth probe</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be73">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>spectrophotometer</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>spectrophotometer</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>spectrophotometer, optical spectrometer, spectrograph or spectroscope

An optical spectrometer (spectrophotometer, spectrograph or spectroscope) is an instrument used to measure properties of light over a specific portion of the electromagnetic spectrum, typically used in spectroscopic analysis to identify materials.

Butler, L. R. P.; Laqua, K. (1995). "Nomenclature, symbols, units and their usage in spectrochemical analysis-IX. Instrumentation for the spectral dispersion and isolation of optical radiation (IUPAC Recommendations 1995)". Pure Appl. Chem. IUPAC. 67 (10): 1725–1744. doi:10.1351/pac199567101725. A spectrometer is the general term for describing a combination of spectral apparatus with one or more detectors to measure the intensity of one or more spectral bands."</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be28">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>titrator</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>titrator</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>titrator</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:platform>
        <gmi:MI_Platform id="plat_ae40">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>MARION DUFRESNE</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:description>
            <gco:CharacterString>Use 35M1 for any data from vessel name MARION DUFRESNE, call sign = FNGB acquired at NODC after December 2009. NODC code 35MF may refer to two different vessels with the same name.

35M1 was assigned by ICES to disambiguate data from two vessels with the name MARION DUFRESNE. USE NODC CODE 35MV for vessel MARION DUFRESNE, call sign = FNIN.

Built 1973
owned by IFREMER;
IMO7208388;
Commissioned Date  1973
Decommissioned Date 1995
Current Length(m) 112
Built Date 1972
Notes Sold in 1995 to Alexander Nav. Vo and renamed FRES under Malta flag. Decomissioned in 2002 and destroyed in 2004.</gco:CharacterString>
          </gmi:description>
          <gmi:instrument gco:nilReason="missing" />
        </gmi:MI_Platform>
      </gmi:platform>
    </gmi:MI_AcquisitionInformation>
  </gmi:acquisitionInformation>
</gmi:MI_Metadata>