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        <gco:CharacterString>This record provides physical, chemical, and pathogenic bacteria water quality metrics collected between February 2023 to January 2025 to provide reference data of nearshore and watershed water quality on the island of Culebra, Puerto Rico. The water quality monitoring was conducted at 18 fixed stations. Five stations were selected to quantify LBSP stressor loads at key points in the Cabra, Coronel, and Aeropuerto watersheds. Levels of land-based pollutant exposure in the nearshore were measured at 13 nearshore stations co-located with long-term seagrass monitoring sites. Nearshore monitoring sites were selected based on subject expert evaluation of watershed discharge points, coastal hydrodynamics,  as well as the existing level of LBSP exposure and anticipated changes to LBSP exposure due to management actions. Nearshore monitoring stations were designated based on their land based sources of pollution LBSP management implementation status (i.e., LBSP Treatment Group) as follows: 1) Restoration stations: Located downstream where land-based pollutant management has or is being implemented. 2) LBSP Control stations: Represent a range of land-based pollutant impairments, including sites with no LBSP management, no known direct discharge of LBSP but are representative of the range of external factors that may be encountered at the Restoration sites. 3) LBSP Negative Reference stations of know significant -anecdotal and quantified- LBSP impairment. 4) Positive Reference sites of low LBSP impairment. Nearshore water quality parameters were collected at two depths: surface (10-25 cm ) and bottom (2 m deep). Watershed water quality was sampled at surface only.
Metrics include:
1. Water physical properties: Temperature, Salinity, Dissolved Oxygen, and pH.
2. Indicators of water clarity threats: CDOM Colored Dissolved Organic Matter that absorbs light in the blue and UV part of the electromagnetic spectrum, giving water a yellow-brown color; Turbidity; Chlorophyll-a, used to gain insight of phytoplankton primary productivity, measured as fluorescence at two wave lengths, blue and red; and Kd-PAR Attenuation coefficient of Photosynthetic Active Radiation.
3. Indicators of wastewater threats: Optical brighteners which are whitening agents added to laundry soaps, detergents, toilet paper, and cleaning products to brighten fabrics and/or surfaces, are used to detect the presence of household effluent; and Monochloramines, long-lasting disinfectant used to treat drinking water protecting its quality as it moves through distribution pipes, primarily serving as a marker for the effectiveness of water treatment.
4) Indicators of fecal contamination: Fecal coliforms, the group of bacteria found in fecal matter from warm-blooded animals, including humans; Enterococcus, the group of fecal coliforms specifically used to assess water quality in marine and estuarine environments; and E. coli, a specific type of fecal coliform often considered (but not exclusive) a more reliable indicator due to its specific association with human waste.</gco:CharacterString>
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        <gco:CharacterString>This work is an integral component of the Culebra Ridge-to-Reef Monitoring Program; a spatiotemporally coordinated effort designed to evaluate the effectiveness of NOAA management strategies and actions in priority watersheds to reduce land-based sources of pollution (LBSP) impacts to the nearshore marine ecosystems of the island. This ridge-to-reef monitoring framework implements a Multiple Lines of Evidence approach consisting of: 1) Monitoring of LBSP stressors that are being managed through NOAA funding including sediment accumulation at unpaved road stabilization projects, water quality monitoring at key points throughout the watershed, and watershed modeling to estimate pollutant loads into the nearshore coastal environment. 2) Monitoring of LBSP exposure through nearshore water quality and sediment trap monitoring at nearshore fixed stations. 3) Monitoring of nearshore habitat responses that is co-located with the aforementioned nearshore water quality fixed stations and includes data collection via seagrass monitoring transects. Within this context, water quality is characterized and tracked to quantify the land-based pollutant loads and exposure levels in the receiving coastal environment and the associated seagrass and coral reef communities, which are ultimately the focal point of NOAA's LBSP management efforts on Culebra.</gco:CharacterString>
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        <gco:CharacterString>This data was collected with financial support from the NOAA Restoration Center, the NOAA Coral Reef Conservation Program, and the National Fish and Wildlife Foundation.</gco:CharacterString>
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                                    <gco:CharacterString>NCEI Accession 0305617 v1.1</gco:CharacterString>
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                                    <gco:CharacterString>published 2025-07-01T13:24:36Z</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Water quality metrics (measured);
Units: degrees C, ppb, PSU, %Saturation, mg/L, ug/L, rfu, NTU;
Observation Category: in situ;
Sampling Instrument: multi-parameter water quality sensor;
Sampling and Analyzing Method: In the field general water physicochemical characteristics, and clarity were measured implementing the Eureka Manta 35 Water Quality Sonde; surface salinity was measured using the HANNA HI98319U portable marine salinometer, Monochloramine with the HACH SL100 Portable Analyzer, and optical brighteners with the Turner AquaFluor handheld fluorometer. PAR was assessed using the Apogee buoy-suspended light sensing system and estimates of KdPAR were computed as the normalized average of surface and bottom measurements. The Quanti-Tray system was implemented to detect the presence of fecal coliforms using the Most Probable Number (MPN) model.;
Data Quality Method: The quality control occurred at three major stages: 1) instrument calibration; 2) data entry; and 3) data management. Data entry quality control included both review and manual error correction steps including purging data outside the instruments' parameter detection ranges.
Water quality measurements were made implementing state-of-the-art instrumentation.
Handheld GPS units were used to locate sites and mark site locations.
Survey methods were consistent across dates and sites.
Data gaps may originate from, but not limited to, instrument malfunction, weather conditions, and the data quality control process.</gco:CharacterString>
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            <gco:CharacterString>used to measure temperature, salinity, dissolved oxygen, and other parameters

Instrument used to measure temperature, salinity, dissolved oxygen, and other parameters, often used to measure water quality parameters. Can be a hand-held instrument or a sonde for unattended monitoring. Often used in coastal water monitoring stations. YSI is the preeminent brand (as of 2024).</gco:CharacterString>
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