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          <gmd:keyword>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/309" xlink:actuate="onRequest">SALINITY - SURFACE WATER</gmx:Anchor>
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          <gmd:keyword>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/593" xlink:actuate="onRequest">xCO2 seawater</gmx:Anchor>
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          <gmd:keyword>
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          <gmd:keyword>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/obstype/details/27" xlink:actuate="onRequest">surface underway</gmx:Anchor>
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            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/1d8525f0-0cfc-4d59-8677-da5c8038deb7" xlink:actuate="onRequest">EARTH SCIENCE &gt; CLIMATE INDICATORS &gt; ATMOSPHERIC/OCEAN INDICATORS &gt; SURFACE SALINITY</gmx:Anchor>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/26afa886-4866-4536-be3a-6f9db9aacd97" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; OCEAN CHEMISTRY &gt; CARBON DIOXIDE</gmx:Anchor>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/bd24a9a9-7d52-4c29-b2a0-6cefd216ae78" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; OCEAN TEMPERATURE &gt; SEA SURFACE TEMPERATURE</gmx:Anchor>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/7e95b5fc-1d58-431a-af36-948b29fa870d" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; SALINITY/DENSITY &gt; SALINITY</gmx:Anchor>
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          <gmd:thesaurusName>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/d8efbcb9-9ab3-4016-b7ff-6426cd0bf545" xlink:actuate="onRequest">EQUILIBRATORS</gmx:Anchor>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/ed79ec7b-a2df-4948-9877-b75e1fcb8782" xlink:actuate="onRequest">SALINOMETERS</gmx:Anchor>
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          <gmd:keyword>
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      <gmd:resourceConstraints xlink:title="NCEI Data Citation Statement">
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      <gmd:resourceConstraints>
        <gmd:MD_LegalConstraints>
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                            <gmd:URL>https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/</gmd:URL>
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                <gco:CharacterString>[accessed 2024-02-08]</gco:CharacterString>
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        <gmd:MD_TopicCategoryCode>oceans</gmd:MD_TopicCategoryCode>
      </gmd:topicCategory>
      <gmd:topicCategory>
        <gmd:MD_TopicCategoryCode>climatologyMeteorologyAtmosphere</gmd:MD_TopicCategoryCode>
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          <gmd:temporalElement>
            <gmd:EX_TemporalExtent id="boundingTemporalExtent">
              <gmd:extent>
                <gml:TimePeriod gml:id="boundingTemporalExtentPeriod">
                  <gml:beginPosition>2018-08-14</gml:beginPosition>
                  <gml:endPosition>2018-11-28</gml:endPosition>
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              <gmd:organisationName>
                <gmx:Anchor xlink:href="https://ror.org/04r0wrp59" xlink:actuate="onRequest">NOAA National Centers for Environmental Information</gmx:Anchor>
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                  </gmd:phone>
                  <gmd:address>
                    <gmd:CI_Address>
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                        <gco:CharacterString>ncei.info@noaa.gov</gco:CharacterString>
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          <gmd:distributionOrderProcess>
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                <gco:CharacterString>In most cases, electronic downloads of the data are free. However, fees may apply for custom orders, data certifications, copies of analog materials, and data distribution on physical media.</gco:CharacterString>
              </gmd:fees>
              <gmd:orderingInstructions>
                <gco:CharacterString>Contact NCEI for other distribution options and instructions.</gco:CharacterString>
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                <gmd:CI_OnlineResource>
                  <gmd:linkage>
                    <gmd:URL>https://www.ncei.noaa.gov/data/oceans/ncei/ocads/metadata/0210600.html</gmd:URL>
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                    <gco:CharacterString>HTTPS</gco:CharacterString>
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                  <gmd:applicationProfile>
                    <gco:CharacterString>Web browser</gco:CharacterString>
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                  <gmd:description>
                    <gco:CharacterString>Navigate directly to the URL for a descriptive web page with download links.</gco:CharacterString>
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                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
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                    <gco:CharacterString>HTTPS</gco:CharacterString>
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                    <gco:CharacterString>NCEI Dataset Landing Page</gco:CharacterString>
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                  <gmd:description>
                    <gco:CharacterString>Navigate directly to the URL for a descriptive web page with download links.</gco:CharacterString>
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                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
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                    <gmd:URL>https://www.ncei.noaa.gov/archive/accession/oas/210600</gmd:URL>
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                  <gmd:protocol>
                    <gco:CharacterString>HTTPS</gco:CharacterString>
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                  <gmd:applicationProfile>
                    <gco:CharacterString>Web browser</gco:CharacterString>
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                  <gmd:name>
                    <gco:CharacterString>Descriptive Information</gco:CharacterString>
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                  <gmd:description>
                    <gco:CharacterString>Navigate directly to the URL for a descriptive web page with download links.</gco:CharacterString>
                  </gmd:description>
                  <gmd:function>
                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
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                <gmd:CI_OnlineResource>
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                    <gmd:URL>https://www.ncei.noaa.gov/archive/accession/download/210600</gmd:URL>
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                    <gco:CharacterString>HTTPS</gco:CharacterString>
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                  <gmd:applicationProfile>
                    <gco:CharacterString>Web browser</gco:CharacterString>
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                  <gmd:name>
                    <gco:CharacterString>HTTPS</gco:CharacterString>
                  </gmd:name>
                  <gmd:description>
                    <gco:CharacterString>Navigate directly to the URL for data access and direct download.</gco:CharacterString>
                  </gmd:description>
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                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="download">download</gmd:CI_OnLineFunctionCode>
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              </gmd:onLine>
              <gmd:onLine>
                <gmd:CI_OnlineResource>
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                  <gmd:protocol>
                    <gco:CharacterString>FTP</gco:CharacterString>
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                  <gmd:name>
                    <gco:CharacterString>FTP</gco:CharacterString>
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                  <gmd:description>
                    <gco:CharacterString>These data are available through the File Transfer Protocol (FTP). FTP is no longer supported by most internet browsers. You may copy and paste the FTP link to the data into an FTP client (e.g., FileZilla or WinSCP).</gco:CharacterString>
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                                    <gmd:URL>https://www.ncei.noaa.gov/archive/accession/0210600/1.1</gmd:URL>
                                  </gmd:linkage>
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        <gmd:LI_Lineage>
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            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: pCO2 (fCO2) autonomous;
Abbreviation: xCO2;
Unit: ppm;
Observation type: Surface underway;
Measured or calculated: Measured;
Sampling instrument: Seawater pump;
Location of seawater intake: water enters through keel - max 2m below sea surface. System intake in main bode. Distance to membrane around 0.5 meter.;
Analyzing instrument: Li-804A;
Detailed sampling and analyzing information: Autocalibration with Zero (Soda lime) and non-zero standard; once per day. After autocalibration first 30 minutes of seawater measurements are not considered to allow full equilibrium;
Equilibrator type: Flat membrane (PDMS);
Equilibrator volume: 1885 mm2;
Is the equilibrator vented or not: closed loop;
Water flow rate: 7 L/min;
Gas flow rate: 0.5 L/min;
Drying method for gas: measuring in wet atmosphere;
SEA CO2 gas detector manufacturer: Licor, Inc;
SEA CO2 gas detector model: LI-840A;
SEA CO2 gas detector uncertainty: better than 1% of reading, zero drift less than 0.15 ppm/°C, span drift less than 0.03 %/°C;
Standardization technique: Calibration with artificial air with 600.9ppmv xCO2 content;
Standard gas manufacturer: Idronaut (TSG); TriOS (Fluorimeter);
Method reference: pCO2 calculation following T correction of Takahashi et al 1993 (where T_membrane is considered T_in-situ since distance membrane to inlet is about 0.5m). pCO2 and fCO2 are calculated following the DOE handbook</gco:CharacterString>
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            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Sea Surface Temperature;
Abbreviation: SST_C;
Unit: degrees celcius;
Observation type: Surface Underway;
Analyzing instrument: Sea and Sun customized CTD48;
Detailed sampling and analyzing information: Temperature and salinity last calibrated on 20180713 by Sea and Sun Technology, Arndtstrasse 9, D-24610 Trappenkamp. T Kalibration range: 0-30°C. Conductivity calibration range: 0-65mS/cm;
Uncertainty: Resolution: +/-0.005 °C; +/- 0.010 mS/cm</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Sea Surface Salinity;
Abbreviation: SSS;
Observation type: Surface Underway;
Detailed sampling and analyzing information: Temperature and salinity last calibrated on 20180713 by Sea and Sun Technology, Arndtstrasse 9, D-24610 Trappenkamp. T Kalibration range: 0-30°C. Conductivity calibration range: 0-65mS/cm</gco:CharacterString>
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          <gmd:processStep>
            <gmi:LE_ProcessStep>
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                <gco:CharacterString>Parameter or Variable: Barometric pressure;
Abbreviation: Pressure_hPa;
Unit: hPa;
Observation type: Underway</gco:CharacterString>
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            <gco:CharacterString>NOAA National Centers for Environmental Information</gco:CharacterString>
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      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be21">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>barometric pressure sensor</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>barometric pressure sensor</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>instrument used to measure the atmospheric pressure.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be58">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>carbon dioxide (CO2) gas analyzer</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>carbon dioxide (CO2) gas analyzer</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>measures gaseous carbon dioxide

Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption.

Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_bea4">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>salinometer</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>salinometer</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>generic salinometer

use salinometer when the instrument type used is unclear but the data include salinity measurements</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be57">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>showerhead equilibrator</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>showerhead equilibrator</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>extracts dissolved CO2 from water

A carbon dioxide equilibrator is usually in the shape of a vertical tube, with a showerhead on the top, some headspace, a lot of beads to increase the surface exchange area between water and air, a water seal device at the bottom to allow water to overflow, but prevents air exchange between inside and outside.

Carbon dioxide (CO2) equilibrator works together with carbon dioxide (CO2) gas analyzer (insttypes_id 183) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be41">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>temperature sensor</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>temperature sensor</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>A sensor used to measure temperature.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:platform>
        <gmi:MI_Platform id="plat_bf07">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>UNKNOWN PLATFORMS OF GERMANY</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:description>
            <gco:CharacterString>UNKNOWN PLATFORMS OF GERMANY</gco:CharacterString>
          </gmi:description>
          <gmi:instrument gco:nilReason="missing" />
        </gmi:MI_Platform>
      </gmi:platform>
    </gmi:MI_AcquisitionInformation>
  </gmi:acquisitionInformation>
</gmi:MI_Metadata>