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                <gco:CharacterString>Parameter or Variable: Dissolved Inorganic Carbon;
Abbreviation: DIC;
Unit: micro-mol/kg;
Observation type: Surface discrete measurement (flow through);
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Measured;
Sampling instrument: flow through system;
Analyzing instrument: Coulometer used: AOML2 (SOMMA #2);
Detailed sampling and analyzing information: The discrete samples were collected by a French observer hired by Gilles Reverdin. Surface samples were collected from intake on the Reykjafoss that is tapped from the ship’s engine intake on board. Sampling collection followed SOP 1 in Dickson et al., (2007). Analysis date: 12/09/2010 Coulometer used: AOML2 (SOMMA #2) Blank: min=12 counts/min; max = 20 counts/min; average = 17 counts/min CRM # used and assigned value (include both DIC and salinity): Meas CRM cert CRM meas sal cert sal batch 1986.74 2000.44 32.984 33.326 85 Run time: min=9 min; max = 15 min; average = 10 min Reproducibility: (# samples and average difference): 10 sets of duplicate samples, average difference 1.7 umol/kg +- 1.3 umol/kg CRM, salinity and HgCl2 correction applied: Salinity correction was applied using TSG salinity Remarks- The volume correction was applied due to added HgCl2 (Measured DIC*1.00037). The first CRM of each cell was used for a CRM correction. match up with the underway DIC and TA samples;
CRM manufacturer: Dr. A. Dickson of UCSD;
CRM batch number: Batch 80;
Preservation method: saturated HgCl2;
Preservative volume: 0.2 ml;
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value, 5 = value not reported, 6 = mean of replicate measurements, 9 = sample not drawn.;
Researcher name: Rik Wanninkhof, Leticia Barbero;
Researcher institution: Atlantic Oceanographic and Meteorological Laboratory, National Oceanic and Atmospheric Administration (NOAA)</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Total alkalinity;
Abbreviation: TA;
Unit: micro-mol/kg;
Observation type: Surface discrete measurement (flow through);
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Measured;
Sampling instrument: flow through system;
Type of titration: Full Titration;
Cell type (open or closed): Open;
Curve fitting method: Least-Square Analysis;
Detailed sampling and analyzing information: The discrete samples were collected by a French observer hired by Gilles Reverdin. Surface samples were collected from intake on the Reykjafoss that is tapped from the ship’s engine intake on board. Sampling collection followed SOP 1 in Dickson et al., (2007). The results posted are duplicate analyses from the same sample bottles used for DIC. Analysis date: 12/17/2010 Titration system used: Open cell CRM # used and assigned value: Meas CRM cert CRM batch 2169.01 2214.49 80 Reproducibility: (# samples and average difference): 10 sets of duplicate samples, average difference 2.2 umol/kg ± 3.8 umol/kg CRM correction applied The first and last CRMs were used for a CRM correction.;
CRM manufacturer: Dr. A. Dickson of UCSD;
CRM batch number: CRM batch: 80;
Preservation method: saturated HgCl2;
Preservative volume: 0.2 ml;
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value, 5 = value not reported, 6 = mean of replicate measurements, 9 = sample not drawn.;
Method reference: Millero, F. J., Zhang, J. Z., Lee, K., and Campbell, D. M. (1993). Titration alkalinity of seawater. Marine Chemistry, 44(2), 153-165.;
Researcher name: Rik Wanninkhof, Leticia Barbero;
Researcher institution: Atlantic Oceanographic and Meteorological Laboratory, National Oceanic and Atmospheric Administration (NOAA)</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Water temperature;
Abbreviation: SST_C;
Unit: degrees celsius (ITS-90);
Observation type: Flow-through;
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Measured;
Sampling instrument: SBE 38;
Uncertainty: plus or minus 0.001 degrees celsius;
Quality flag convention: -999 indicates bad or missing data;
Researcher name: Rik Wanninkhof;
Researcher institution: Atlantic Oceanographic and Meteorological Laboratory, National Oceanic and Atmospheric Administration (NOAA)</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Salinity;
Abbreviation: SAL;
Unit: practical salinity scale of 1978;
Observation type: Flow-through;
In-situ / Manipulation / Response variable: in-situ observation;
Sampling instrument: SBE 45;
Uncertainty: plus or minus 0.005;
Quality flag convention: -999 indicates bad or missing data;
Researcher name: Rik Wanninkhof;
Researcher institution: Atlantic Oceanographic and Meteorological Laboratory, National Oceanic and Atmospheric Administration (NOAA)</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
        </gmd:LI_Lineage>
      </gmd:lineage>
    </gmd:DQ_DataQuality>
  </gmd:dataQualityInfo>
  <gmd:metadataMaintenance>
    <gmd:MD_MaintenanceInformation>
      <gmd:maintenanceAndUpdateFrequency>
        <gmd:MD_MaintenanceFrequencyCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_MaintenanceFrequencyCode" codeListValue="asNeeded">asNeeded</gmd:MD_MaintenanceFrequencyCode>
      </gmd:maintenanceAndUpdateFrequency>
      <gmd:maintenanceNote>
        <gco:CharacterString>Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.</gco:CharacterString>
      </gmd:maintenanceNote>
      <gmd:contact>
        <gmd:CI_ResponsibleParty>
          <gmd:organisationName>
            <gco:CharacterString>NOAA National Centers for Environmental Information</gco:CharacterString>
          </gmd:organisationName>
          <gmd:role>
            <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="custodian">custodian</gmd:CI_RoleCode>
          </gmd:role>
        </gmd:CI_ResponsibleParty>
      </gmd:contact>
    </gmd:MD_MaintenanceInformation>
  </gmd:metadataMaintenance>
  <gmi:acquisitionInformation>
    <gmi:MI_AcquisitionInformation id="AMS">
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be29">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>coulometer for DIC measurement</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>coulometer for DIC measurement</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>measures dissolved inorganic carbon (DIC)

A known amount of seawater is dispensed into a stripping chamber where it is acidified and purged with an inert gas. The amount of CO2 in the resulting gas stream is determined by absorbing the CO2 in an absorbent. The pH of the solution is monitored by measuring the transmittance .</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be2a">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>Flow-through pump</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>Flow-through pump</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>Flow-through pump refers to a pump system, often found onboard a research vessel. Such pump can feed seawater continuously into instrument that record certain properties of the seawater continuously.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_bea4">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>salinometer</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>salinometer</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>generic salinometer

use salinometer when the instrument type used is unclear but the data include salinity measurements</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be41">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>temperature sensor</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>temperature sensor</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>A sensor used to measure temperature.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be28">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>titrator</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>titrator</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>titrator</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:platform>
        <gmi:MI_Platform id="plat_9398">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>Reykjafoss</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:description>
            <gco:CharacterString>Flag: Netherlands
Vessel Type: General Cargo Ship
Built: 1999
IMO: 9202077
Former Name: Westersingel (2005)

Information Source:
Lloyd's Register 2010-11


Submitted to ICES on 2011-08-18.
Confirmed by NOAA on 2012-11-26.</gco:CharacterString>
          </gmi:description>
          <gmi:instrument gco:nilReason="missing" />
        </gmi:MI_Platform>
      </gmi:platform>
    </gmi:MI_AcquisitionInformation>
  </gmi:acquisitionInformation>
</gmi:MI_Metadata>