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These data were collected by Rik Wanninkhof of NOAA Atlantic Oceanographic and Meteorological Laboratory (AOML) and Frank J. Millero, Frank J. Millero, and Ryan J. Woosley of Rosenstiel School of Marine and Atmospheric Science (RSMAS) as part of the Coastal_Walton_Smith_WS1402_33WA20140422, Coastal_Walton_Smith_WS1403_33WA20140423, Coastal_Walton_Smith_WS1404_33WA20140426, Coastal_Walton_Smith_WS1405_33WA20140428, Coastal_Walton_Smith_WS1406_33WA20140528, Coastal_Walton_Smith_WS1409_33WA20140722, Coastal_Walton_Smith_WS1413_33WA20140911, Coastal_Walton_Smith_WS1415_33WA20141019, Coastal_Walton_Smith_WS1416_33WA20141108 and Coastal_Walton_Smith_WS1418_33WA20141201 dataset. CDIAC associated the following cruise ID(s) with this dataset: 33WA20140422, 33WA20140423, 33WA20140426, 33WA20140428, 33WA20140528, 33WA20140722, 33WA20140911, 33WA20141019, 33WA20141108 and 33WA20141201</gco:CharacterString>
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          <gmd:keyword>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/bd24a9a9-7d52-4c29-b2a0-6cefd216ae78" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; OCEAN TEMPERATURE &gt; SEA SURFACE TEMPERATURE</gmx:Anchor>
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          <gmd:keyword>
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                      <gmd:onlineResource>
                        <gmd:CI_OnlineResource>
                          <gmd:linkage>
                            <gmd:URL>https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords</gmd:URL>
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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
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            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>OCADS Study Type</gco:CharacterString>
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              <gmd:date gco:nilReason="inapplicable" />
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          <gmd:keyword>
            <gco:CharacterString>PRES_EQU_hPa</gco:CharacterString>
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            <gco:CharacterString>QC_SUBFLAG</gco:CharacterString>
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            <gco:CharacterString>SAL_permil</gco:CharacterString>
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            <gco:CharacterString>WOCE_QC_FLAG</gco:CharacterString>
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                <gco:CharacterString>Provider Variable Abbreviations</gco:CharacterString>
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      <gmd:descriptiveKeywords>
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                            <gmd:URL>https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords</gmd:URL>
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                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
                  </gmd:function>
                </gmd:CI_OnlineResource>
              </gmd:onLine>
              <gmd:onLine>
                <gmd:CI_OnlineResource>
                  <gmd:linkage>
                    <gmd:URL>https://www.ncei.noaa.gov/archive/accession/download/157432</gmd:URL>
                  </gmd:linkage>
                  <gmd:protocol>
                    <gco:CharacterString>HTTPS</gco:CharacterString>
                  </gmd:protocol>
                  <gmd:applicationProfile>
                    <gco:CharacterString>Web browser</gco:CharacterString>
                  </gmd:applicationProfile>
                  <gmd:name>
                    <gco:CharacterString>HTTPS</gco:CharacterString>
                  </gmd:name>
                  <gmd:description>
                    <gco:CharacterString>Navigate directly to the URL for data access and direct download.</gco:CharacterString>
                  </gmd:description>
                  <gmd:function>
                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="download">download</gmd:CI_OnLineFunctionCode>
                  </gmd:function>
                </gmd:CI_OnlineResource>
              </gmd:onLine>
              <gmd:onLine>
                <gmd:CI_OnlineResource>
                  <gmd:linkage>
                    <gmd:URL>ftp://ftp-oceans.ncei.noaa.gov/nodc/archive/arc0101/0157432/</gmd:URL>
                  </gmd:linkage>
                  <gmd:protocol>
                    <gco:CharacterString>FTP</gco:CharacterString>
                  </gmd:protocol>
                  <gmd:applicationProfile>
                    <gco:CharacterString>Any FTP client</gco:CharacterString>
                  </gmd:applicationProfile>
                  <gmd:name>
                    <gco:CharacterString>FTP</gco:CharacterString>
                  </gmd:name>
                  <gmd:description>
                    <gco:CharacterString>These data are available through the File Transfer Protocol (FTP). FTP is no longer supported by most internet browsers. You may copy and paste the FTP link to the data into an FTP client (e.g., FileZilla or WinSCP).</gco:CharacterString>
                  </gmd:description>
                  <gmd:function>
                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="download">download</gmd:CI_OnLineFunctionCode>
                  </gmd:function>
                </gmd:CI_OnlineResource>
              </gmd:onLine>
            </gmd:MD_DigitalTransferOptions>
          </gmd:distributorTransferOptions>
        </gmd:MD_Distributor>
      </gmd:distributor>
    </gmd:MD_Distribution>
  </gmd:distributionInfo>
  <gmd:dataQualityInfo>
    <gmd:DQ_DataQuality>
      <gmd:scope>
        <gmd:DQ_Scope>
          <gmd:level>
            <gmd:MD_ScopeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_ScopeCode" codeListValue="dataset">dataset</gmd:MD_ScopeCode>
          </gmd:level>
        </gmd:DQ_Scope>
      </gmd:scope>
      <gmd:lineage>
        <gmd:LI_Lineage>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>NCEI Accession 0157432 v1.1 was published.</gco:CharacterString>
              </gmd:description>
              <gmd:dateTime>
                <gco:DateTime>2016-12-10T19:29:40Z</gco:DateTime>
              </gmd:dateTime>
              <gmi:output>
                <gmi:LE_Source>
                  <gmd:sourceCitation>
                    <gmd:CI_Citation>
                      <gmd:title>
                        <gco:CharacterString>NCEI Accession 0157432 v1.1</gco:CharacterString>
                      </gmd:title>
                      <gmd:date>
                        <gmd:CI_Date>
                          <gmd:date gco:nilReason="inapplicable" />
                          <gmd:dateType>
                            <gmd:CI_DateTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="publication">publication</gmd:CI_DateTypeCode>
                          </gmd:dateType>
                        </gmd:CI_Date>
                      </gmd:date>
                      <gmd:citedResponsibleParty>
                        <gmd:CI_ResponsibleParty>
                          <gmd:individualName gco:nilReason="inapplicable" />
                          <gmd:contactInfo>
                            <gmd:CI_Contact>
                              <gmd:onlineResource>
                                <gmd:CI_OnlineResource>
                                  <gmd:linkage>
                                    <gmd:URL>https://www.ncei.noaa.gov/archive/accession/0157432/1.1</gmd:URL>
                                  </gmd:linkage>
                                  <gmd:protocol>
                                    <gco:CharacterString>HTTPS</gco:CharacterString>
                                  </gmd:protocol>
                                  <gmd:name>
                                    <gco:CharacterString>NCEI Accession 0157432 v1.1</gco:CharacterString>
                                  </gmd:name>
                                  <gmd:description>
                                    <gco:CharacterString>published 2016-12-10T19:29:40Z</gco:CharacterString>
                                  </gmd:description>
                                  <gmd:function>
                                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="download">download</gmd:CI_OnLineFunctionCode>
                                  </gmd:function>
                                </gmd:CI_OnlineResource>
                              </gmd:onlineResource>
                            </gmd:CI_Contact>
                          </gmd:contactInfo>
                          <gmd:role gco:nilReason="inapplicable" />
                        </gmd:CI_ResponsibleParty>
                      </gmd:citedResponsibleParty>
                    </gmd:CI_Citation>
                  </gmd:sourceCitation>
                </gmi:LE_Source>
              </gmi:output>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
        </gmd:LI_Lineage>
      </gmd:lineage>
    </gmd:DQ_DataQuality>
  </gmd:dataQualityInfo>
  <gmd:dataQualityInfo>
    <gmd:DQ_DataQuality>
      <gmd:scope>
        <gmd:DQ_Scope>
          <gmd:level>
            <gmd:MD_ScopeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_ScopeCode" codeListValue="dataset">dataset</gmd:MD_ScopeCode>
          </gmd:level>
        </gmd:DQ_Scope>
      </gmd:scope>
      <gmd:lineage>
        <gmd:LI_Lineage>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: xCO2_EQU_ppm;
Abbreviation: xCO2_EQU_ppm;
Unit: Mole fraction of CO2 in the equilibrator headspace (dry) at equilibrator temperature (ppm);
Controlled vocabulary name: partial pressure of carbon dioxide - water;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: xCO2_ATM_ppm;
Abbreviation: xCO2_ATM_ppm;
Unit: Mole fraction of CO2 measured in dry outside air (ppm);
Controlled vocabulary name: Partial pressure (or fugacity) of carbon dioxide - atmosphere;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: xCO2_ATM_interpolated_ppm;
Abbreviation: xCO2_ATM_interpolated_ppm;
Unit: Mole fraction of CO2 in outside air associated with each water analysis. These values are interpolated between the bracketing averaged good xCO2_ATM analyses (ppm);
Controlled vocabulary name: Partial pressure (or fugacity) of carbon dioxide - atmosphere;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: PRES_EQU_hPa;
Abbreviation: PRES_EQU_hPa;
Unit: Barometric pressure in the equilibrator headspace (hectopascals);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: PRES_ATM@SSP_hPa;
Abbreviation: PRES_ATM@SSP_hPa;
Unit: Barometric pressure measured outside, corrected to sea level (hectopascals);
Controlled vocabulary name: BAROMETRIC PRESSURE;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: TEMP_EQU_C;
Abbreviation: TEMP_EQU_C;
Unit: Water temperature in equilibrator (degrees Celsius);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: SST_C;
Abbreviation: SST_C;
Unit: Sea surface temperature (degrees Celsius);
Controlled vocabulary name: SEA SURFACE TEMPERATURE;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: SAL_permil;
Abbreviation: SAL_permil;
Unit: Sea surface salinity on Practical Salinity Scale (permil);
Controlled vocabulary name: SALINITY;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: fCO2_SW@SST_uatm;
Abbreviation: fCO2_SW@SST_uatm;
Unit: Fugacity of CO2 in sea water at SST and 100% humidity (microatmospheres);
Controlled vocabulary name: partial pressure of carbon dioxide - water;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: fCO2_ATM_interpolated_uatm;
Abbreviation: fCO2_ATM_interpolated_uatm;
Unit: Fugacity of CO2 in air corresponding to the interpolated xCO2 at SST and 100% humidity (microatmospheres);
Controlled vocabulary name: Partial pressure (or fugacity) of carbon dioxide - atmosphere;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: dfCO2_uatm;
Abbreviation: dfCO2_uatm;
Unit: Sea water fCO2 minus interpolated air fCO2 (microatmospheres);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: WOCE_QC_FLAG;
Abbreviation: WOCE_QC_FLAG;
Unit: Quality control flag for fCO2 values (2=good, 3=questionable);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: QC_SUBFLAG;
Abbreviation: QC_SUBFLAG;
Unit: Quality control subflag for fCO2 values, provides explanation when QC flag=3;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
        </gmd:LI_Lineage>
      </gmd:lineage>
    </gmd:DQ_DataQuality>
  </gmd:dataQualityInfo>
  <gmd:metadataMaintenance>
    <gmd:MD_MaintenanceInformation>
      <gmd:maintenanceAndUpdateFrequency>
        <gmd:MD_MaintenanceFrequencyCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_MaintenanceFrequencyCode" codeListValue="asNeeded">asNeeded</gmd:MD_MaintenanceFrequencyCode>
      </gmd:maintenanceAndUpdateFrequency>
      <gmd:maintenanceNote>
        <gco:CharacterString>Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.</gco:CharacterString>
      </gmd:maintenanceNote>
      <gmd:contact>
        <gmd:CI_ResponsibleParty>
          <gmd:organisationName>
            <gco:CharacterString>NOAA National Centers for Environmental Information</gco:CharacterString>
          </gmd:organisationName>
          <gmd:role>
            <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="custodian">custodian</gmd:CI_RoleCode>
          </gmd:role>
        </gmd:CI_ResponsibleParty>
      </gmd:contact>
    </gmd:MD_MaintenanceInformation>
  </gmd:metadataMaintenance>
  <gmi:acquisitionInformation>
    <gmi:MI_AcquisitionInformation id="AMS">
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be58">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>carbon dioxide (CO2) gas analyzer</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>carbon dioxide (CO2) gas analyzer</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>measures gaseous carbon dioxide

Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption.

Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be57">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>showerhead equilibrator</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>showerhead equilibrator</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>extracts dissolved CO2 from water

A carbon dioxide equilibrator is usually in the shape of a vertical tube, with a showerhead on the top, some headspace, a lot of beads to increase the surface exchange area between water and air, a water seal device at the bottom to allow water to overflow, but prevents air exchange between inside and outside.

Carbon dioxide (CO2) equilibrator works together with carbon dioxide (CO2) gas analyzer (insttypes_id 183) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:platform>
        <gmi:MI_Platform id="plat_9b7e">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>R/V F.G. Walton Smith</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:description>
            <gco:CharacterString>R/V; RSMAS Univ. of Miami; built 1999; active as July 2007

University of Miami assigned a new call sign to F.G. WALTON SMITH on January 13, 2021. The previous call sign was WCZ6292.</gco:CharacterString>
          </gmi:description>
          <gmi:instrument gco:nilReason="missing" />
        </gmi:MI_Platform>
      </gmi:platform>
    </gmi:MI_AcquisitionInformation>
  </gmi:acquisitionInformation>
</gmi:MI_Metadata>