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          <gmd:keyword>
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          <gmd:keyword>
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          <gmd:keyword>
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          <gmd:keyword>
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          <gmd:keyword>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/obstype/details/27" xlink:actuate="onRequest">surface underway</gmx:Anchor>
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          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
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      <gmd:descriptiveKeywords>
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          <gmd:keyword>
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          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="platform">platform</gmd:MD_KeywordTypeCode>
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                <gco:CharacterString>NODC PLATFORM NAMES THESAURUS</gco:CharacterString>
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                <gml:TimePeriod gml:id="boundingTemporalExtentPeriod">
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              <gmd:orderingInstructions>
                <gco:CharacterString>Contact NCEI for other distribution options and instructions.</gco:CharacterString>
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                    <gco:CharacterString>Navigate directly to the URL for data access and direct download.</gco:CharacterString>
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                <gco:DateTime>2018-06-29T20:04:23Z</gco:DateTime>
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                <gco:CharacterString>Parameter or Variable: pCO2 (fCO2) autonomous;
Abbreviation: xCO2_sea;
Unit: uatm;
Observation type: Surface underway;
Measured or calculated: Measured;
Sampling instrument: Seawater pump;
Analyzing instrument: NDIR;
Detailed sampling and analyzing information: Non-dispersive infrared (NDIR) analysis on partially dried gas. NDIR calibration frequency: every 90 minutes using 0 ppm, 250 ppm, 350 ppm, or 450 ppm gas standards. Measurement frequency: every 1 minute except during NDIR calibration routines.;
Equilibrator type: Percolator;
Equilibrator volume: approx 1 L;
Is the equilibrator vented or not: Vented;
Water flow rate: 3.5 L/min;
Gas flow rate: 0.1 L/min;
Drying method for gas: Thermoelectric cooling units followed by permeable membrane dryer and magnessium perchlorate tube;
SEA CO2 gas detector manufacturer: Licor, Inc;
SEA CO2 gas detector model: LI7000;
SEA CO2 gas detector resolution: +/- 0.1 ppm;
SEA CO2 gas detector uncertainty: less than 2 ppm;
Standardization technique: Primary standards traceable to the WMO-X93 scale. Primary standards from NOAA calibrated in 2008;
Standard gas manufacturer: BOC, UK (www.boc.com);
Standard gas concentration: 0 ppm CO2 in dry air (UoE 000B052) with CO2 trap to remove any residual CO2 259.97 +/- 0.1 ppm CO2 in dry air (UoE 250B052) calibrated to NOAA/CMDL (http://www.cmdl.noaa.gov/ccgg/refgases/index.html) on 11 Feb 2017 361.00 +/- 0.1 ppm CO2 in dry air (UoE 350B052) calibrated to NOAA/CMDL (http://www.cmdl.noaa.gov/ccgg/refgases/index.html) on 11 Feb 2017 460.21 +/- 0.1 ppm CO2 in dry air (UoE 450B052) calibrated to NOAA/CMDL (http://www.cmdl.noaa.gov/ccgg/refgases/index.html) on 11 Feb 2017;
At what temperature was pCO2 reported: In situ sea surface temperature;
Method reference: Pierrot et al., Deep Sea Res. II, 56, 512-522 (2009);
Researcher name: Ute Schuster;
Researcher institution: University of Exeter, UK</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Sea Surface Temperature;
Abbreviation: SST_C;
Unit: degrees celcius;
Observation type: Surface Underway;
Analyzing instrument: T-4050; Aanderaa Instruments, Norway;
Uncertainty: 0.001;
Researcher name: Ute Schuster;
Researcher institution: University of Exeter, UK</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Sea Surface Salinity;
Abbreviation: SSS;
Observation type: Surface Underway;
Analyzing instrument: Seabird SBE 45 Micro Thermosalniograph; Sea-Bird Electronics, Inc., US;
Uncertainty: 0.0002;
Researcher name: Ute Schuster;
Researcher institution: University of Exeter, UK</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Barometreic pressure transducer;
Abbreviation: AtmPrs;
Unit: mBar;
Observation type: Surface Underway;
Analyzing instrument: Li7000; Li-Cor, ambient engine room pressure calibrated to sea level pressure;
Uncertainty: 0.1 hPa;
Researcher name: Ute Schuster;
Researcher institution: University of Exeter, UK</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Dissolved Oxygen;
Abbreviation: Oxygen;
Unit: UMOL/KG;
Observation type: Surface Underway;
Analyzing instrument: Optode 3835; Aanderaa Instruments, Norway;
Uncertainty: UMOL/KGhPa;
Researcher name: Ute Schuster;
Researcher institution: University of Exeter, UK</gco:CharacterString>
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        <gmd:MD_MaintenanceFrequencyCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_MaintenanceFrequencyCode" codeListValue="asNeeded">asNeeded</gmd:MD_MaintenanceFrequencyCode>
      </gmd:maintenanceAndUpdateFrequency>
      <gmd:maintenanceNote>
        <gco:CharacterString>Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.</gco:CharacterString>
      </gmd:maintenanceNote>
      <gmd:contact>
        <gmd:CI_ResponsibleParty>
          <gmd:organisationName>
            <gco:CharacterString>NOAA National Centers for Environmental Information</gco:CharacterString>
          </gmd:organisationName>
          <gmd:role>
            <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="custodian">custodian</gmd:CI_RoleCode>
          </gmd:role>
        </gmd:CI_ResponsibleParty>
      </gmd:contact>
    </gmd:MD_MaintenanceInformation>
  </gmd:metadataMaintenance>
  <gmi:acquisitionInformation>
    <gmi:MI_AcquisitionInformation id="AMS">
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be58">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>carbon dioxide (CO2) gas analyzer</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>carbon dioxide (CO2) gas analyzer</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>measures gaseous carbon dioxide

Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption.

Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be24">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>Non-dispersive infrared (NDIR) dissolved inorganic carbon (DIC) analyzer</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>Non-dispersive infrared (NDIR) dissolved inorganic carbon (DIC) analyzer</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>A known amount of seawater is dispensed into a stripping chamber where it is acidified and purged with an inert gas. The amount of CO2 in the resulting gas stream is determined with a non-dispersive infrared (NDIR) carbon dioxide analyzer.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be57">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>showerhead equilibrator</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>showerhead equilibrator</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>extracts dissolved CO2 from water

A carbon dioxide equilibrator is usually in the shape of a vertical tube, with a showerhead on the top, some headspace, a lot of beads to increase the surface exchange area between water and air, a water seal device at the bottom to allow water to overflow, but prevents air exchange between inside and outside.

Carbon dioxide (CO2) equilibrator works together with carbon dioxide (CO2) gas analyzer (insttypes_id 183) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:platform>
        <gmi:MI_Platform id="plat_95fd">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>Benguela Stream</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:description>
            <gco:CharacterString>Vessel of opportunity; built 1998; port of registry- Groningen, Netherlands;IMO9158594;</gco:CharacterString>
          </gmi:description>
          <gmi:instrument gco:nilReason="missing" />
        </gmi:MI_Platform>
      </gmi:platform>
    </gmi:MI_AcquisitionInformation>
  </gmi:acquisitionInformation>
</gmi:MI_Metadata>