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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/insttype/details/50" xlink:actuate="onRequest">pH sensor</gmx:Anchor>
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          <gmd:keyword>
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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="instrument">instrument</gmd:MD_KeywordTypeCode>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/obstype/details/52" xlink:actuate="onRequest">discrete sample</gmx:Anchor>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/obstype/details/14" xlink:actuate="onRequest">physical</gmx:Anchor>
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                            <gco:CharacterString>Global Change Master Directory (GCMD). 2025. GCMD Keywords, Version 21. Greenbelt, MD: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA). URL (GCMD Keyword Forum Page): https://forum.earthdata.nasa.gov/app.php/tag/GCMD+Keywords</gco:CharacterString>
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                            <gmd:URL>https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/coastal_carbon_data.html</gmd:URL>
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                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
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                    <gco:CharacterString>These data are available through the File Transfer Protocol (FTP). FTP is no longer supported by most internet browsers. You may copy and paste the FTP link to the data into an FTP client (e.g., FileZilla or WinSCP).</gco:CharacterString>
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              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Dissolved Inorganic Carbon;
Abbreviation: DIC;
Unit: µmol/kg;
Observation type: Laboratory experiment;
Measured or calculated: measured;
Calculation method and parameters: none;
Sampling instrument: 8.2 L Van Dorn bottle;
Analyzing instrument: Apollo AS-C3;
Standardization description: Certified Reference Materials;
Standardization frequency: Daily;
CRM manufacturer: Andrew Dickson's lab at Scripps Institute of Oceanography;
CRM batch number: Batch 133, 136, 140, 142, 147, 148, 156, 159, 170, 174;
Preservation method: Saturated HgCl2;
Preservative volume: 100 µL;
Preservative correction: Results are corrected for 0.04% due to the addition of HgCl2 solution;
Uncertainty: ±0.1%;
Quality flag convention: WOCE;
Method reference: Hu, X., M.F. Nuttall, H. Wang, H. Yao, C.J. Staryk, M.R. McCutcheon, R.J. Eckert, J.A. Embesi, M.A. Johnston, E.L. Hickerson, G.P. Schmahl, D. Manzello, I.C. Enochs, S. DiMarco, and L. Barbero. 2018. Seasonal variability of carbonate chemistry and decadal changes in waters of a marine sanctuary in the Northwestern Gulf of Mexico. Marine Chemistry 205: 16-28.;
Researcher name: Cory J. Staryk, Hongming Yao;
Researcher institution: Texas A&amp;M University-Corpus Christi</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Total alkalinity;
Abbreviation: TA;
Unit: µmol/kg;
Observation type: Laboratory experiment;
Measured or calculated: measured;
Calculation method and parameters: none;
Sampling instrument: 8.2 L Van Dorn bottle;
Analyzing instrument: Apollo AS-ALK2;
Type of titration: Potentiometric;
Cell type (open or closed): open;
Curve fitting method: Gran;
Standardization description: Certified Reference Materials;
Standardization frequency: Daily;
CRM manufacturer: Andrew Dickson's lab at Scripps Institute of Oceanography;
CRM batch number: Batch 14, 147, 148, 156;
Preservation method: Saturated HgCl2;
Preservative volume: 100 µL;
Preservative correction: Results are corrected for 0.04% due to the addition of HgCl2 solution;
TA blank correction: none;
Uncertainty: ±0.1%;
Quality flag convention: WOCE;
Method reference: Hu, X., M.F. Nuttall, H. Wang, H. Yao, C.J. Staryk, M.R. McCutcheon, R.J. Eckert, J.A. Embesi, M.A. Johnston, E.L. Hickerson, G.P. Schmahl, D. Manzello, I.C. Enochs, S. DiMarco, and L. Barbero. 2018. Seasonal variability of carbonate chemistry and decadal changes in waters of a marine sanctuary in the Northwestern Gulf of Mexico. Marine Chemistry 205: 16-28.;
Researcher name: Cory J. Staryk, Hongming Yao;
Researcher institution: Texas A&amp;M University-Corpus Christi</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: pH;
Abbreviation: pH;
pH scale: Total (NBS scale for salinity&lt;20);
Observation type: Laboratory experiment;
Measured or calculated: measured;
Calculation method and parameters: none;
Sampling instrument: 8.2 L Van Dorn bottle;
Analyzing instrument: Agilent 8453;
Temperature of pH measurement: 25°C;
Detailed sampling and analyzing information: Spectrophotometric (potentiometric for salinity&lt;20);
Replicate information: Random duplicate sample collection;
Standardization description: Purified mCP was used in the spectrophotometric analysis; Thermo Fisher 4.01, 7.00, 10.01 pH buffers were used for low salinity samples (salinity &lt; 20);
Standardization frequency: N/A;
pH standard values: N/A;
Temperature of standardization: N/A;
Temperature correction method: N/A;
At what temperature was pH reported: 25°C;
Uncertainty: ±0.0005 (±0.01 for salinity&lt;20);
Quality flag convention: WOCE;
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Abbreviation: Depth;
Unit: m;
Uncertainty: ±0.1</gco:CharacterString>
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Abbreviation: Temp;
Unit: °C;
Measured or calculated: Measured;
Uncertainty: ±0.1</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Salinity;
Abbreviation: Salinity;
Unit: N/A;
Measured or calculated: Measured;
Uncertainty: ±0.1</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Dissolved calcium concentration;
Abbreviation: Ca2+;
Unit: mmol/kg;
Measured or calculated: Measured;
Calculation method and parameters: none;
Sampling instrument: 8.2 L Van Dorn bottle;
Analyzing instrument: Titrando 888 Automatic titrator;
Detailed sampling and analyzing information: EGTA titration calribated with a Ca2+ standard in artificial sewater;
Uncertainty: ±0.2%;
Quality flag convention: WOCE;
Method reference: Kanamori, S., and Ikegami, H. (1980). Computer-processed potentiometric titration for the determination of calcium and magnesium in sea water. Journal of the Oceanographical Society of Japan, 36(4), 177-184.;
Researcher name: Hongming Yao and Cory Staryk;
Researcher institution: Texas A&amp;M University-Corpus Christi</gco:CharacterString>
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                <gco:CharacterString>carbon dioxide (CO2) gas analyzer</gco:CharacterString>
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            <gco:CharacterString>carbon dioxide (CO2) gas analyzer</gco:CharacterString>
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            <gco:CharacterString>measures gaseous carbon dioxide

Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption.

Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
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            <gco:CharacterString>generic meter used to measure pH

Any of a class of instruments used to quantify pH in a water or other type of sample.</gco:CharacterString>
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            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>salinometer</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>generic salinometer

use salinometer when the instrument type used is unclear but the data include salinity measurements</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be28">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>titrator</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>titrator</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>titrator</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
    </gmi:MI_AcquisitionInformation>
  </gmi:acquisitionInformation>
</gmi:MI_Metadata>