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ABSTRACT SUPPLIED BY ORIGINATOR: Currently, there is only one paleo-CO2 record from plant macrofossils that has sufficient stratigraphic resolution to potentially capture a transient spike related to rapid carbon release at the Cretaceous-Paleogene (K-Pg) boundary. Unfortunately, the associated measurements of stomatal index are off-calibration, leading to a qualitative interpretation of &gt;2,300-ppm CO2. Here we reevaluate this record with a paleo-CO2 proxy based on leaf gas exchange principles. We also test the proxy with three living species grown at 500- and 1,000-ppm CO2, including the nearest living relative of the K-Pg fern, and find a mean error rate of ~22%, which is comparable to other leading paleo-CO2 proxies. Our fossils record a ~250-ppm increase in CO2 across the K-Pg boundary from ~625 to ~875 ppm. A small CO2 spike associated with the end-Cretaceous mass extinction is consistent with many temperature records and with carbon cycle modeling of Deccan volcanism and the meteorite impact.</gco:CharacterString>
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                  <gmd:protocol>
                    <gco:CharacterString>HTTPS</gco:CharacterString>
                  </gmd:protocol>
                  <gmd:applicationProfile>
                    <gco:CharacterString>Landing Page</gco:CharacterString>
                  </gmd:applicationProfile>
                  <gmd:name>
                    <gco:CharacterString>Metadata Landing Page</gco:CharacterString>
                  </gmd:name>
                  <gmd:description>
                    <gco:CharacterString>NCEI landing page with general information and links to access the data.</gco:CharacterString>
                  </gmd:description>
                  <gmd:function>
                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
                  </gmd:function>
                </gmd:CI_OnlineResource>
              </gmd:onLine>
            </gmd:MD_DigitalTransferOptions>
          </gmd:distributorTransferOptions>
          <gmd:distributorTransferOptions>
            <gmd:MD_DigitalTransferOptions>
              <gmd:onLine>
                <gmd:CI_OnlineResource>
                  <gmd:linkage>
                    <gmd:URL>https://www.ncei.noaa.gov/access/paleo-search/study/26190</gmd:URL>
                  </gmd:linkage>
                  <gmd:protocol>
                    <gco:CharacterString>HTTPS</gco:CharacterString>
                  </gmd:protocol>
                  <gmd:applicationProfile>
                    <gco:CharacterString>Web Browser</gco:CharacterString>
                  </gmd:applicationProfile>
                  <gmd:name>
                    <gco:CharacterString>NOAA Study Page</gco:CharacterString>
                  </gmd:name>
                  <gmd:description>
                    <gco:CharacterString>Study page with data access information.</gco:CharacterString>
                  </gmd:description>
                  <gmd:function>
                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="search">search</gmd:CI_OnLineFunctionCode>
                  </gmd:function>
                </gmd:CI_OnlineResource>
              </gmd:onLine>
            </gmd:MD_DigitalTransferOptions>
          </gmd:distributorTransferOptions>
          <gmd:distributorTransferOptions>
            <gmd:MD_DigitalTransferOptions>
              <gmd:onLine>
                <gmd:CI_OnlineResource>
                  <gmd:linkage>
                    <gmd:URL>https://www.ncei.noaa.gov/products/paleoclimatology/climate-forcing</gmd:URL>
                  </gmd:linkage>
                  <gmd:protocol>
                    <gco:CharacterString>HTTPS</gco:CharacterString>
                  </gmd:protocol>
                  <gmd:applicationProfile>
                    <gco:CharacterString>Information</gco:CharacterString>
                  </gmd:applicationProfile>
                  <gmd:name>
                    <gco:CharacterString>NCEI Forcing Page</gco:CharacterString>
                  </gmd:name>
                  <gmd:description>
                    <gco:CharacterString>General information for this data type.</gco:CharacterString>
                  </gmd:description>
                  <gmd:function>
                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
                  </gmd:function>
                </gmd:CI_OnlineResource>
              </gmd:onLine>
            </gmd:MD_DigitalTransferOptions>
          </gmd:distributorTransferOptions>
          <gmd:distributorTransferOptions>
            <gmd:MD_DigitalTransferOptions>
              <gmd:onLine>
                <gmd:CI_OnlineResource>
                  <gmd:linkage>
                    <gmd:URL>https://www.ncei.noaa.gov/pub/data/paleo/climate_forcing/trace_gases/Paleo-pCO2/stomata-franks_milligan_2019.xlsx</gmd:URL>
                  </gmd:linkage>
                  <gmd:protocol>
                    <gco:CharacterString>HTTPS</gco:CharacterString>
                  </gmd:protocol>
                  <gmd:applicationProfile>
                    <gco:CharacterString>Download</gco:CharacterString>
                  </gmd:applicationProfile>
                  <gmd:name>
                    <gco:CharacterString>NCEI Direct Download</gco:CharacterString>
                  </gmd:name>
                  <gmd:description>
                    <gco:CharacterString>Direct download links for dataset files.</gco:CharacterString>
                  </gmd:description>
                  <gmd:function>
                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="download">download</gmd:CI_OnLineFunctionCode>
                  </gmd:function>
                </gmd:CI_OnlineResource>
              </gmd:onLine>
            </gmd:MD_DigitalTransferOptions>
          </gmd:distributorTransferOptions>
          <gmd:distributorTransferOptions>
            <gmd:MD_DigitalTransferOptions>
              <gmd:onLine>
                <gmd:CI_OnlineResource>
                  <gmd:linkage>
                    <gmd:URL>https://www.ncei.noaa.gov/pub/data/paleo/climate_forcing/trace_gases/Paleo-pCO2/stomata-franks_milligan_2019.txt</gmd:URL>
                  </gmd:linkage>
                  <gmd:protocol>
                    <gco:CharacterString>HTTPS</gco:CharacterString>
                  </gmd:protocol>
                  <gmd:applicationProfile>
                    <gco:CharacterString>Download</gco:CharacterString>
                  </gmd:applicationProfile>
                  <gmd:name>
                    <gco:CharacterString>NCEI Direct Download</gco:CharacterString>
                  </gmd:name>
                  <gmd:description>
                    <gco:CharacterString>Direct download links for dataset files.</gco:CharacterString>
                  </gmd:description>
                  <gmd:function>
                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="download">download</gmd:CI_OnLineFunctionCode>
                  </gmd:function>
                </gmd:CI_OnlineResource>
              </gmd:onLine>
            </gmd:MD_DigitalTransferOptions>
          </gmd:distributorTransferOptions>
        </gmd:MD_Distributor>
      </gmd:distributor>
    </gmd:MD_Distribution>
  </gmd:distributionInfo>
  <gmd:metadataMaintenance>
    <gmd:MD_MaintenanceInformation>
      <gmd:maintenanceAndUpdateFrequency>
        <gmd:MD_MaintenanceFrequencyCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_MaintenanceFrequencyCode" codeListValue="asNeeded">asNeeded</gmd:MD_MaintenanceFrequencyCode>
      </gmd:maintenanceAndUpdateFrequency>
      <gmd:maintenanceNote>
        <gco:CharacterString>This ISO metadata record was translated from DIF metadata using dif-9x-to-iso-19115-2.xsl Version: 2022-06-21</gco:CharacterString>
      </gmd:maintenanceNote>
    </gmd:MD_MaintenanceInformation>
  </gmd:metadataMaintenance>
</gmi:MI_Metadata>