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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/4eab7956-e59e-4615-8d5c-39a16faa1f27" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; OCEAN CHEMISTRY &gt; ALKALINITY</gmx:Anchor>
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            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/26afa886-4866-4536-be3a-6f9db9aacd97" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; OCEAN CHEMISTRY &gt; CARBON DIOXIDE</gmx:Anchor>
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                            <gmd:URL>https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords</gmd:URL>
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                <gco:CharacterString>Provider Variable Abbreviations</gco:CharacterString>
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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="instrument">instrument</gmd:MD_KeywordTypeCode>
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            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/5488b1cc-08b2-41cf-9bd2-4a2cdd0990de" xlink:actuate="onRequest">OCEAN &gt; PACIFIC OCEAN &gt; NORTH PACIFIC OCEAN</gmx:Anchor>
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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="place">place</gmd:MD_KeywordTypeCode>
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                <gco:CharacterString>Provider Geographic Names</gco:CharacterString>
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                    <gco:CharacterString>These data are available through the File Transfer Protocol (FTP). FTP is no longer supported by most internet browsers. You may copy and paste the FTP link to the data into an FTP client (e.g., FileZilla or WinSCP).</gco:CharacterString>
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                <gco:CharacterString>NCEI Accession 0247208 v1.1 was published.</gco:CharacterString>
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              <gmd:description>
                <gco:CharacterString>Parameter or Variable: pCO2 (fCO2) autonomous;
Abbreviation: SWpCO2@SST;
Unit: µatm;
Observation type: Measurements from continuously flowing seawater stream;
Measured or calculated: Calculated from measured CO2 mole fractions (xCO2) and ambient atmospheric pressure.;
Calculation method and parameters: Calculated from measured CO2 mole fractions (xCO2) and ambient atmospheric pressure;
Sampling instrument: Dakunalytics, LLC Burke-o-Lator pCO2/TCO2 Analyzer (with bubble-type equilibrator);
Location of seawater intake: Seawater drawn from 1-m depth approximately 50 m from shore in Sitka Harbor; southeast Alaska; 57.0526°N, 135.3456°W;
Depth of seawater intake: 1-m;
Analyzing instrument: Dakunalytics, LLC Burke-o-Lator (BoL) pCO2/TCO2 Analyzer use LI-COR LI-840A non-dispersive infrared detectors;
Detailed sampling and analyzing information: Seawater pCO2 data were calculated from corrected measurements of CO2 mixing ratio (xCO2) made using a Dakunalytics, LLC Burke-o-Lator (BoL) pCO2/TCO2 Analyzer following many recommended protocols by Pierrot et al. (2009) with the system theory and calculations described in detail elsewhere (Hales et al., 2004; Evans et al., 2015; Evans et al., 2019). Seawater continuously flowed at ~1 GPM first through a Sea-Bird Electronics SBE 45 MicroTSG Thermosalinograph and then to the equilibrator (bubble-type). Carrier gas (marine air) is pumped into the equilibrator from the electronics box at ~100 ml min-1. Full equilibration was verified by injecting high and low CO2 gas standard into the equilibration chamber and verifying carrier gas concentrations returned to the same pre-disturbance xCO2. These tests also revealed the response time of the equilibrator to be ~5 mins. Equilibrated carrier gas is then supplied to a non-dispersive infrared gas analyzer (LI-COR LI840A CO2/H2O) housed within the electronics box. Carrier gas is then recirculated through the system, minimizing the need for make-up by the equilibrator. Pressure and temperature were continuously measured in the equilibrators using a Honeywell ASCX Microstructure Pressure Sensor and an Omega Fast Response RTD, respectively. Equilibrated carrier gas, four standard gases of known mixing ratio (nominally 150, 450, 750, and 1500 ppm), and unaltered marine air were all plumbed to provide gas flow to the electronics box. The system is controlled using National Instruments LabVIEW software. The software controls data acquisition from the thermosalinograph, the pressure and temperature sensors, and the LI-COR; while also controlling Valco Instruments Co. Inc. (VICI) multi-port actuators that cycle between the gas streams plumbed to the electronics box. None of the gas streams were dried prior to analysis, and all measurements were made at 1 Hz. The prescribed measurement scheme controlled by the software was to supply equilibrated carrier gas from the equilibrator to the LI-COR continuously for 720 minutes, then cycle the actuators to consecutively allow for the standard gas streams and unaltered marine air to be measured for 90 s each at 100 ml min-1 before returning to sample the carrier gas equilibrated with seawater xCO2. From each sequence of standard gas measurements, the final 20 s of data in the 80 s interval before the actuator changed position were used to construct calibration functions that were then interpolated in time between standard gas sequences. These functions were then used to calibrate the xCO2 measurements of seawater equilibrated carrier gas. Corrected seawater xCO2 was subsequently adjusted for under- or over-pressurization in the equilibrator using the ratio of equilibrator to vented LI-COR cell pressure, and then converted to pCO2 using atmospheric pressure measured by the LI-COR. The 1 Hz seawater pCO2, temperature and salinity data were quality controlled by removing questionable measurements, and then averaged in 5-min interval bins. Finally, pCO2 at the equilibrator temperature was adjusted to sea surface temperature using the average temperature difference measured between the seawater intake and the equilibrator (see Change Log note). Uncertainty in SWpCO2@SST was computed by adding the component uncertainties in quadrature: LI840A calibration uncertainty (0.5 ppm, by comparison with WMO traceable standard from ESRL), equilibrator temperature uncertainty (0.164 degrees C, by comparison between RTD probe and the TSG temperature), equilibrator pressure uncertainty (2 hPa), and uncertainty in the warming correction (0.15 degrees C, 1 standard deviation of the average difference between intake and TSG temperatures). Computed at a pCO2 of 400 uatm, this equates to sqrt(0.5^2 + 2.76^2 + 0.79^2 + 2.513^2) = 3.98 µatm.;
Equilibrator type: non-dispersive infrared gas analyzer;
Standardization technique: xCO2 calibration functions developed during periodic sequential analysis of gas standards of known concentration (nominally 150, 450, 750, and 1500);
Standardization frequency: Every 720 minutes;
Standard gas manufacturer: Praxair, Inc.;
Standard gas uncertainty: 2 ppm for calibrated xCO2; ~2 µatm for pCO2;
Uncertainty: 2 µatm;
Quality flag convention: no quality flag applied;
Method reference: Hales, B., D. Chipman, and T. Takahashi (2004), High-frequency measurements of partial pressure and total concentration of carbon dioxide in seawater using microporous hydrophobic membrane contactors, Limnology and Oceanography: Methods, 2, 356-364; Pierrot, D., C. Neill, K. Sullivan, R. Castle, R. Wanninkhof, H. Lüger, T. Johannessen, A. Olsen, R. A. Feely, and C. E. Cosca (2009), Recommendations for autonomous underway pCO2 measuring systems and data-reduction routines, Deep Sea Research Part II: Topical Studies in Oceanography, 56(8-10), 512-522, https://doi.org/10.1016/j.dsr2.2008.12.005; Evans, W., Mathis, J.T., Ramsay, J., and Hetrick, J. (2015). On the Frontline: Tracking Ocean Acidification in an Alaskan Shellfish Hatchery. PLoS One 10, e0130384; Evans, W., Pocock, K., Hare, A., Weekes, C., Hales, B., Jackson, J., Gurney-Smith, H., Mathis, J.T., Alin, S.R., and Feely, R.A. (2019). Marine CO2 Patterns in the Northern Salish Sea. Frontiers in Marine Science 5, https://doi.org/10.3389/fmars.2018.00536;
Researcher name: Wiley Evans;
Researcher institution: Hakai Institute</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Sea surface temperature;
Abbreviation: SST;
Unit: °C, ITS-90 scale;
Observation type: Measurements from continuously flowing seawater stream;
Measured or calculated: calculated as the measured seawater temperature within the laboratory as determined by the TSG adjusted to sea surface temperature using the average difference in temperature between the TSG and the intake temperature records;
Analyzing instrument: Sea-Bird SBE 45 MicroTSG Thermosalinograph;
Detailed sampling and analyzing information: 1 Hz data captured using National Instruments LabVIEW software on an iMac computer;
Uncertainty: 0.002°C;
Researcher name: Wiley Evans;
Researcher institution: Hakai Institute</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Sea surface salinity;
Abbreviation: Salinity;
Unit: 1978 Practical Salinity Scale;
Observation type: measurements from continuously flowing seawater stream;
Calculation method and parameters: calculated from conductivity and temperature measurements;
Analyzing instrument: SBE 45 MicroTSG Thermosalinograph;
Detailed sampling and analyzing information: 1 Hz data captured using National Instruments LabVIEW software on an iMac computer;
Uncertainty: 0.003 S/m;
Researcher name: Wiley Evans;
Researcher institution: Hakai Institute</gco:CharacterString>
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            <gco:CharacterString>measures gaseous carbon dioxide

Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption.

Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
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            <gco:CharacterString>Non-dispersive infrared (NDIR) dissolved inorganic carbon (DIC) analyzer</gco:CharacterString>
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            <gco:CharacterString>A known amount of seawater is dispensed into a stripping chamber where it is acidified and purged with an inert gas. The amount of CO2 in the resulting gas stream is determined with a non-dispersive infrared (NDIR) carbon dioxide analyzer.</gco:CharacterString>
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use salinometer when the instrument type used is unclear but the data include salinity measurements</gco:CharacterString>
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