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            <gco:CharacterString>NCEI Accession 0259391 was revised and a new version of the archival package was published. Updates to existing archival packages may provide additional files or replace obsolete files. The latest version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession. Please see journal.txt in the /about directory for additional details on changes made.</gco:CharacterString>
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            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/5" xlink:actuate="onRequest">total alkalinity</gmx:Anchor>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/7cf22186-281a-4665-b79b-5a6e5ea5b471" xlink:actuate="onRequest">MPI-M &gt; Max Planck Institute for Meteorology</gmx:Anchor>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/b092e798-3bcd-42a3-9ffb-0a28bd4ea35b" xlink:actuate="onRequest">U-SOTON/NOC &gt; National Oceanography Centre, University of Southampton</gmx:Anchor>
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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="dataCentre">dataCentre</gmd:MD_KeywordTypeCode>
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              <gmd:title>
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                    <gmd:CI_DateTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="revision">revision</gmd:CI_DateTypeCode>
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                      <gmd:onlineResource>
                        <gmd:CI_OnlineResource>
                          <gmd:linkage>
                            <gmd:URL>https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords</gmd:URL>
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                            <gco:CharacterString>HTTPS</gco:CharacterString>
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                <gco:CharacterString>Ocean Acidification Search Keywords</gco:CharacterString>
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      <gmd:descriptiveKeywords>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/26afa886-4866-4536-be3a-6f9db9aacd97" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; OCEAN CHEMISTRY &gt; CARBON DIOXIDE</gmx:Anchor>
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          <gmd:keyword>
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          <gmd:keyword>
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            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/bd24a9a9-7d52-4c29-b2a0-6cefd216ae78" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; OCEAN TEMPERATURE &gt; SEA SURFACE TEMPERATURE</gmx:Anchor>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/7e95b5fc-1d58-431a-af36-948b29fa870d" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; SALINITY/DENSITY &gt; SALINITY</gmx:Anchor>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Global Change Master Directory (GCMD) Science Keywords</gco:CharacterString>
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                <gmd:CI_Date>
                  <gmd:date>
                    <gco:Date>2026</gco:Date>
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                    <gmd:CI_DateTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="revision">revision</gmd:CI_DateTypeCode>
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                        <gmd:CI_OnlineResource>
                          <gmd:linkage>
                            <gmd:URL>https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords</gmd:URL>
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                            <gco:CharacterString>HTTPS</gco:CharacterString>
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                            <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
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          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>OCADS Study Type</gco:CharacterString>
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              <gmd:date gco:nilReason="inapplicable" />
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            <gco:CharacterString>Aragonite</gco:CharacterString>
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            <gco:CharacterString>Calcite</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>DIC</gco:CharacterString>
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            <gco:CharacterString>H</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>Hfree</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>RF</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>Salinity</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>TA</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>Temperature</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>fCO2</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>pCO2a</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>pHT</gco:CharacterString>
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          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
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          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Provider Variable Abbreviations</gco:CharacterString>
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      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/7aecabfb-0047-484f-8396-efc0da16bc20" xlink:actuate="onRequest">CO2 ANALYZERS &gt; CO2 ANALYZERS</gmx:Anchor>
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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="instrument">instrument</gmd:MD_KeywordTypeCode>
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              <gmd:title>
                <gco:CharacterString>Global Change Master Directory (GCMD) Instrument Keywords</gco:CharacterString>
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                  <gmd:date>
                    <gco:Date>2026</gco:Date>
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                            <gco:CharacterString>MD</gco:CharacterString>
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                        <gmd:CI_OnlineResource>
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                            <gco:CharacterString>HTTPS</gco:CharacterString>
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                <gco:CharacterString>Provider Geographic Names</gco:CharacterString>
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            <gmd:MD_ScopeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_ScopeCode" codeListValue="dataset">dataset</gmd:MD_ScopeCode>
          </gmd:level>
        </gmd:DQ_Scope>
      </gmd:scope>
      <gmd:lineage>
        <gmd:LI_Lineage>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Dissolved Inorganic Carbon;
Abbreviation: DIC;
Unit: umol/kg;
Observation type: Model output;
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Calculated;
Detailed sampling and analyzing information: At each grid point, the DIC values are based on the median temporal changes out of fourteen Earth System Models of the sixth phase of the Coupled Model Intercomparison Project (CMIP6): (1) ACCESS-ESM1-5, Ziehn et al., 2020, https://doi.org/10.1071/es19035, (2) CanESM5, Swart et al., 2019, https://doi.org/10.5194/gmd-12-4823-2019, (3) CESM2, Danabasoglu et al., 2020, https://doi.org/10.1029/2019ms001916, (4) CMCC-ESM2, Lovato et al., 2022, https://doi.org/10.1029/2021ms002814, (5) CNRM-ESM-2, Séférian et al., 2019, https://doi.org/10.1029/2019ms001791, (6) EC-Earth3-CC, Döscher et al., 2021, https://doi.org/10.5194/gmd-2020-446, (7) GFDL-CM4, Held et al., 2019, https://doi.org/10.1029/2019MS001829, (8) GFDL-ESM4, Dunne et al., 2020, https://doi.org/10.1029/2019MS002015, (9) IPSL-CM6A-LR, Boucher et al., 2020, https://doi.org/10.1029/2019ms002010, (10) MIROC-ES2L, Hajima et al., 2020, https://doi.org/10.5194/gmd-13-2197-2020, (11) MPI-ESM1-2-LR, Mauritsen et al., 2019, https://doi.org/10.1029/2018ms001400, (12) MRI-ESM2-0, Yukimoto et al., 2019, https://doi.org/10.2151/jmsj.2019-051, (13) NorESM2-LM, Seland et al., 2020, https://doi.org/10.5194/gmd-13-6165-2020, (14) UKESM1-0-LL), Sellar et al., 2019, https://doi.org/10.1029/2019ms001739, with bias corrections based on three latest observational data products: (1) the Surface Ocean CO2 Atlas (SOCAT, version 2022, Bakker et al., 2016, https://doi.org/10.5194/essd-8-383-2016), (2) the Global Ocean Data Analysis Product Version 2 (GLODAPv2, version 2022, Lauvset et al., 2022, under review), and (3) the Coastal Ocean Data Analysis Product in North America (CODAP-NA, version 2021, Jiang et al., 2021, https://doi.org/10.5194/essd-13-2777-2021). All DIC values were corrected to the year of 2010 using the Empirical Seawater Property Estimation Routines (ESPER) from sea surface temperature and salinity (Carter et al., 2021).;
Researcher name: Li-Qing Jiang;
Researcher institution: Cooperative Institute for Satellite Earth System Studies, Earth System Science Interdisciplinary Center, University of Maryland, College Park, Maryland 20740, United States</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Total alkalinity;
Abbreviation: TA;
Unit: umol/kg;
Observation type: Model output;
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Calculated;
Detailed sampling and analyzing information: At each grid point, the TA values are based on the median temporal changes out of fourteen Earth System Models of the sixth phase of the Coupled Model Intercomparison Project (CMIP6): (1) ACCESS-ESM1-5, Ziehn et al., 2020, https://doi.org/10.1071/es19035, (2) CanESM5, Swart et al., 2019, https://doi.org/10.5194/gmd-12-4823-2019, (3) CESM2, Danabasoglu et al., 2020, https://doi.org/10.1029/2019ms001916, (4) CMCC-ESM2, Lovato et al., 2022, https://doi.org/10.1029/2021ms002814, (5) CNRM-ESM-2, Séférian et al., 2019, https://doi.org/10.1029/2019ms001791, (6) EC-Earth3-CC, Döscher et al., 2021, https://doi.org/10.5194/gmd-2020-446, (7) GFDL-CM4, Held et al., 2019, https://doi.org/10.1029/2019MS001829, (8) GFDL-ESM4, Dunne et al., 2020, https://doi.org/10.1029/2019MS002015, (9) IPSL-CM6A-LR, Boucher et al., 2020, https://doi.org/10.1029/2019ms002010, (10) MIROC-ES2L, Hajima et al., 2020, https://doi.org/10.5194/gmd-13-2197-2020, (11) MPI-ESM1-2-LR, Mauritsen et al., 2019, https://doi.org/10.1029/2018ms001400, (12) MRI-ESM2-0, Yukimoto et al., 2019, https://doi.org/10.2151/jmsj.2019-051, (13) NorESM2-LM, Seland et al., 2020, https://doi.org/10.5194/gmd-13-6165-2020, (14) UKESM1-0-LL), Sellar et al., 2019, https://doi.org/10.1029/2019ms001739, with bias corrections based on three latest observational data products: (1) the Surface Ocean CO2 Atlas (SOCAT, version 2022, Bakker et al., 2016, https://doi.org/10.5194/essd-8-383-2016), (2) the Global Ocean Data Analysis Product Version 2 (GLODAPv2, version 2021, Lauvset et al., 2022, under review), and (3) the Coastal Ocean Data Analysis Product in North America (CODAP-NA, version 2021, Jiang et al., 2021, https://doi.org/10.5194/essd-13-2777-2021).;
Researcher name: Li-Qing Jiang;
Researcher institution: Cooperative Institute for Satellite Earth System Studies, Earth System Science Interdisciplinary Center, University of Maryland, College Park, Maryland 20740, United States</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: pH;
Abbreviation: pHT;
pH scale: Total scale (T);
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Calculated;
Calculation method and parameters: The CO2 system calculation was conducted using a Julia version of the CO2System.jl (v2.0.5, https://github.com/mvdh7/CO2System.jl, Humphreys et al., 2022) with the dissociation constants and parameter as recommended by Jiang et al. (2022), i.e., dissociation constants for carbonic acid of Lueker et al. (2000), potassium bisulfate (KHSO4-) of Dickson (1990), hydrofluoric acid (HF) of Perez and Fraga (1987), and the total borate concentration equations of Lee et al. (2010).;
Method reference: Jiang, L.-Q., Pierrot, D., Wanninkhof, R., Feely, R. A., Tilbrook, B., Alin, S., et al. (2022), Best Practice Data Standards for Discrete Chemical Oceanographic Observations. Front. Mar. Sci. 8, 705638. https://doi.org/10.3389/fmars.2021.705638.</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: pCO2 (fCO2) autonomous;
Abbreviation: pCO2a;
Unit: uatm;
Observation type: Model output;
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Calculated;
Calculation method and parameters: The CO2 system calculation was conducted using a Julia version of the CO2System.jl (v2.0.5, https://github.com/mvdh7/CO2System.jl, Humphreys et al., 2022) with the dissociation constants and parameter as recommended by Jiang et al. (2022), i.e., dissociation constants for carbonic acid of Lueker et al. (2000), potassium bisulfate (KHSO4-) of Dickson (1990), hydrofluoric acid (HF) of Perez and Fraga (1987), and the total borate concentration equations of Lee et al. (2010).;
Method reference: Jiang, L.-Q., Pierrot, D., Wanninkhof, R., Feely, R. A., Tilbrook, B., Alin, S., et al. (2022), Best Practice Data Standards for Discrete Chemical Oceanographic Observations. Front. Mar. Sci. 8, 705638. https://doi.org/10.3389/fmars.2021.705638.;
Researcher name: Li-Qing Jiang;
Researcher institution: Cooperative Institute for Satellite Earth System Studies, Earth System Science Interdisciplinary Center, University of Maryland, College Park, Maryland 20740, United States</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Partial pressure (or fugacity) of carbon dioxide - Water;
Abbreviation: fCO2;
Unit: uatm;
Observation type: Model output;
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Calculated;
Calculation method and parameters: The CO2 system calculation was conducted using a Julia version of the CO2System.jl (v2.0.5, https://github.com/mvdh7/CO2System.jl, Humphreys et al., 2022) with the dissociation constants and parameter as recommended by Jiang et al. (2022), i.e., dissociation constants for carbonic acid of Lueker et al. (2000), potassium bisulfate (KHSO4-) of Dickson (1990), hydrofluoric acid (HF) of Perez and Fraga (1987), and the total borate concentration equations of Lee et al. (2010).;
Method reference: Jiang, L.-Q., Pierrot, D., Wanninkhof, R., Feely, R. A., Tilbrook, B., Alin, S., et al. (2022), Best Practice Data Standards for Discrete Chemical Oceanographic Observations. Front. Mar. Sci. 8, 705638. https://doi.org/10.3389/fmars.2021.705638.;
Researcher name: Li-Qing Jiang;
Researcher institution: Cooperative Institute for Satellite Earth System Studies, Earth System Science Interdisciplinary Center, University of Maryland, College Park, Maryland 20740, United States</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Aragonite saturation state;
Abbreviation: Aragonite;
Observation type: Model output;
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Calculated;
Method reference: Jiang, L.-Q., Pierrot, D., Wanninkhof, R., Feely, R. A., Tilbrook, B., Alin, S., et al. (2022), Best Practice Data Standards for Discrete Chemical Oceanographic Observations. Front. Mar. Sci. 8, 705638. https://doi.org/10.3389/fmars.2021.705638.;
Researcher name: Li-Qing Jiang;
Researcher institution: Cooperative Institute for Satellite Earth System Studies, Earth System Science Interdisciplinary Center, University of Maryland, College Park, Maryland 20740, United States</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Calcite saturation state;
Abbreviation: Calcite;
Observation type: Model output;
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Calculated;
Calculation method and parameters: The CO2 system calculation was conducted using a Julia version of the CO2System.jl (v2.0.5, https://github.com/mvdh7/CO2System.jl, Humphreys et al., 2022) with the dissociation constants and parameter as recommended by Jiang et al. (2022), i.e., dissociation constants for carbonic acid of Lueker et al. (2000), potassium bisulfate (KHSO4-) of Dickson (1990), hydrofluoric acid (HF) of Perez and Fraga (1987), and the total borate concentration equations of Lee et al. (2010).;
Method reference: Jiang, L.-Q., Pierrot, D., Wanninkhof, R., Feely, R. A., Tilbrook, B., Alin, S., et al. (2022), Best Practice Data Standards for Discrete Chemical Oceanographic Observations. Front. Mar. Sci. 8, 705638. https://doi.org/10.3389/fmars.2021.705638.;
Researcher name: Li-Qing Jiang;
Researcher institution: Cooperative Institute for Satellite Earth System Studies, Earth System Science Interdisciplinary Center, University of Maryland, College Park, Maryland 20740, United States</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Carbonate;
Abbreviation: CO3;
Unit: umol/kg;
Observation type: Model output;
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Calculated;
Calculation method and parameters: The CO2 system calculation was conducted using a Julia version of the CO2System.jl (v2.0.5, https://github.com/mvdh7/CO2System.jl, Humphreys et al., 2022) with the dissociation constants and parameter as recommended by Jiang et al. (2022), i.e., dissociation constants for carbonic acid of Lueker et al. (2000), potassium bisulfate (KHSO4-) of Dickson (1990), hydrofluoric acid (HF) of Perez and Fraga (1987), and the total borate concentration equations of Lee et al. (2010).;
Method reference: Jiang, L.-Q., Pierrot, D., Wanninkhof, R., Feely, R. A., Tilbrook, B., Alin, S., et al. (2022), Best Practice Data Standards for Discrete Chemical Oceanographic Observations. Front. Mar. Sci. 8, 705638. https://doi.org/10.3389/fmars.2021.705638.;
Researcher name: Li-Qing Jiang;
Researcher institution: Cooperative Institute for Satellite Earth System Studies, Earth System Science Interdisciplinary Center, University of Maryland, College Park, Maryland 20740, United States</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Total hydrogen ion content;
Abbreviation: H;
Unit: x 10^-9 mol/kg;
Observation type: Model output;
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Calculated;
Calculation method and parameters: The CO2 system calculation was conducted using a Julia version of the CO2System.jl (v2.0.5, https://github.com/mvdh7/CO2System.jl, Humphreys et al., 2022) with the dissociation constants and parameter as recommended by Jiang et al. (2022), i.e., dissociation constants for carbonic acid of Lueker et al. (2000), potassium bisulfate (KHSO4-) of Dickson (1990), hydrofluoric acid (HF) of Perez and Fraga (1987), and the total borate concentration equations of Lee et al. (2010).;
Method reference: Jiang, L.-Q., Pierrot, D., Wanninkhof, R., Feely, R. A., Tilbrook, B., Alin, S., et al. (2022), Best Practice Data Standards for Discrete Chemical Oceanographic Observations. Front. Mar. Sci. 8, 705638. https://doi.org/10.3389/fmars.2021.705638.;
Researcher name: Li-Qing Jiang;
Researcher institution: Cooperative Institute for Satellite Earth System Studies, Earth System Science Interdisciplinary Center, University of Maryland, College Park, Maryland 20740, United States</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Free hydrogen ion content;
Abbreviation: Hfree;
Unit: x 10^-9 mol/kg;
Observation type: Model output;
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Calculated;
Calculation method and parameters: The CO2 system calculation was conducted using a Julia version of the CO2System.jl (v2.0.5, https://github.com/mvdh7/CO2System.jl, Humphreys et al., 2022) with the dissociation constants and parameter as recommended by Jiang et al. (2022), i.e., dissociation constants for carbonic acid of Lueker et al. (2000), potassium bisulfate (KHSO4-) of Dickson (1990), hydrofluoric acid (HF) of Perez and Fraga (1987), and the total borate concentration equations of Lee et al. (2010).;
Method reference: Jiang, L.-Q., Pierrot, D., Wanninkhof, R., Feely, R. A., Tilbrook, B., Alin, S., et al. (2022), Best Practice Data Standards for Discrete Chemical Oceanographic Observations. Front. Mar. Sci. 8, 705638. https://doi.org/10.3389/fmars.2021.705638.;
Researcher name: Li-Qing Jiang;
Researcher institution: Cooperative Institute for Satellite Earth System Studies, Earth System Science Interdisciplinary Center, University of Maryland, College Park, Maryland 20740, United States</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Revelle Factor;
Abbreviation: RF;
Observation type: Model output;
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Calculated;
Calculation method and parameters: The CO2 system calculation was conducted using a Julia version of the CO2System.jl (v2.0.5, https://github.com/mvdh7/CO2System.jl, Humphreys et al., 2022) with the dissociation constants and parameter as recommended by Jiang et al. (2022), i.e., dissociation constants for carbonic acid of Lueker et al. (2000), potassium bisulfate (KHSO4-) of Dickson (1990), hydrofluoric acid (HF) of Perez and Fraga (1987), and the total borate concentration equations of Lee et al. (2010).;
Method reference: Jiang, L.-Q., Pierrot, D., Wanninkhof, R., Feely, R. A., Tilbrook, B., Alin, S., et al. (2022), Best Practice Data Standards for Discrete Chemical Oceanographic Observations. Front. Mar. Sci. 8, 705638. https://doi.org/10.3389/fmars.2021.705638.;
Researcher name: Li-Qing Jiang;
Researcher institution: Cooperative Institute for Satellite Earth System Studies, Earth System Science Interdisciplinary Center, University of Maryland, College Park, Maryland 20740, United States</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Sea surface temperature;
Abbreviation: Temperature;
Unit: degrees Celsius;
Observation type: Model output;
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Calculated;
Detailed sampling and analyzing information: Sea surface temperature is reported at the International Temperature Scale of 1990 (ITS-90). At each grid point, the temperature values are based on the median temporal changes out of fourteen Earth System Models of the sixth phase of the Coupled Model Intercomparison Project (CMIP6): (1) ACCESS-ESM1-5, Ziehn et al., 2020, https://doi.org/10.1071/es19035, (2) CanESM5, Swart et al., 2019, https://doi.org/10.5194/gmd-12-4823-2019, (3) CESM2, Danabasoglu et al., 2020, https://doi.org/10.1029/2019ms001916, (4) CMCC-ESM2, Lovato et al., 2022, https://doi.org/10.1029/2021ms002814, (5) CNRM-ESM-2, Séférian et al., 2019, https://doi.org/10.1029/2019ms001791, (6) EC-Earth3-CC, Döscher et al., 2021, https://doi.org/10.5194/gmd-2020-446, (7) GFDL-CM4, Held et al., 2019, https://doi.org/10.1029/2019MS001829, (8) GFDL-ESM4, Dunne et al., 2020, https://doi.org/10.1029/2019MS002015, (9) IPSL-CM6A-LR, Boucher et al., 2020, https://doi.org/10.1029/2019ms002010, (10) MIROC-ES2L, Hajima et al., 2020, https://doi.org/10.5194/gmd-13-2197-2020, (11) MPI-ESM1-2-LR, Mauritsen et al., 2019, https://doi.org/10.1029/2018ms001400, (12) MRI-ESM2-0, Yukimoto et al., 2019, https://doi.org/10.2151/jmsj.2019-051, (13) NorESM2-LM, Seland et al., 2020, https://doi.org/10.5194/gmd-13-6165-2020, (14) UKESM1-0-LL), Sellar et al., 2019, https://doi.org/10.1029/2019ms001739, with bias corrections based on three latest observational data products: (1) the Surface Ocean CO2 Atlas (SOCAT, version 2021, Bakker et al., 2016, https://doi.org/10.5194/essd-8-383-2016), (2) the Global Ocean Data Analysis Product Version 2 (GLODAPv2, version 2021, Lauvset et al., 2021, https://doi.org/10.5194/essd-13-5565-2021), and (3) the Coastal Ocean Data Analysis Product in North America (CODAP-NA, version 2021, Jiang et al., 2021, https://doi.org/10.5194/essd-13-2777-2021).;
Researcher name: Li-Qing Jiang;
Researcher institution: Cooperative Institute for Satellite Earth System Studies, Earth System Science Interdisciplinary Center, University of Maryland, College Park, Maryland 20740, United States</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Water salinity;
Abbreviation: Salinity;
Observation type: Model output;
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Calculated;
Detailed sampling and analyzing information: The scale of salinity is PSS78. At each grid point, the salinity values are based on the median temporal changes out of fourteen Earth System Models of the sixth phase of the Coupled Model Intercomparison Project (CMIP6): (1) ACCESS-ESM1-5, Ziehn et al., 2020, https://doi.org/10.1071/es19035, (2) CanESM5, Swart et al., 2019, https://doi.org/10.5194/gmd-12-4823-2019, (3) CESM2, Danabasoglu et al., 2020, https://doi.org/10.1029/2019ms001916, (4) CMCC-ESM2, Lovato et al., 2022, https://doi.org/10.1029/2021ms002814, (5) CNRM-ESM-2, Séférian et al., 2019, https://doi.org/10.1029/2019ms001791, (6) EC-Earth3-CC, Döscher et al., 2021, https://doi.org/10.5194/gmd-2020-446, (7) GFDL-CM4, Held et al., 2019, https://doi.org/10.1029/2019MS001829, (8) GFDL-ESM4, Dunne et al., 2020, https://doi.org/10.1029/2019MS002015, (9) IPSL-CM6A-LR, Boucher et al., 2020, https://doi.org/10.1029/2019ms002010, (10) MIROC-ES2L, Hajima et al., 2020, https://doi.org/10.5194/gmd-13-2197-2020, (11) MPI-ESM1-2-LR, Mauritsen et al., 2019, https://doi.org/10.1029/2018ms001400, (12) MRI-ESM2-0, Yukimoto et al., 2019, https://doi.org/10.2151/jmsj.2019-051, (13) NorESM2-LM, Seland et al., 2020, https://doi.org/10.5194/gmd-13-6165-2020, (14) UKESM1-0-LL), Sellar et al., 2019, https://doi.org/10.1029/2019ms001739, with bias corrections based on three latest observational data products: (1) the Surface Ocean CO2 Atlas (SOCAT, version 2021, Bakker et al., 2016, https://doi.org/10.5194/essd-8-383-2016), (2) the Global Ocean Data Analysis Product Version 2 (GLODAPv2, version 2021, Lauvset et al., 2021, https://doi.org/10.5194/essd-13-5565-2021), and (3) the Coastal Ocean Data Analysis Product in North America (CODAP-NA, version 2021, Jiang et al., 2021, https://doi.org/10.5194/essd-13-2777-2021).;
Researcher name: Li-Qing Jiang;
Researcher institution: Cooperative Institute for Satellite Earth System Studies, Earth System Science Interdisciplinary Center, University of Maryland, College Park, Maryland 20740, United States</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
        </gmd:LI_Lineage>
      </gmd:lineage>
    </gmd:DQ_DataQuality>
  </gmd:dataQualityInfo>
  <gmd:metadataMaintenance>
    <gmd:MD_MaintenanceInformation>
      <gmd:maintenanceAndUpdateFrequency>
        <gmd:MD_MaintenanceFrequencyCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_MaintenanceFrequencyCode" codeListValue="asNeeded">asNeeded</gmd:MD_MaintenanceFrequencyCode>
      </gmd:maintenanceAndUpdateFrequency>
      <gmd:maintenanceNote>
        <gco:CharacterString>Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.</gco:CharacterString>
      </gmd:maintenanceNote>
      <gmd:contact>
        <gmd:CI_ResponsibleParty>
          <gmd:organisationName>
            <gco:CharacterString>NOAA National Centers for Environmental Information</gco:CharacterString>
          </gmd:organisationName>
          <gmd:role>
            <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="custodian">custodian</gmd:CI_RoleCode>
          </gmd:role>
        </gmd:CI_ResponsibleParty>
      </gmd:contact>
    </gmd:MD_MaintenanceInformation>
  </gmd:metadataMaintenance>
  <gmi:acquisitionInformation>
    <gmi:MI_AcquisitionInformation id="AMS">
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be58">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>carbon dioxide (CO2) gas analyzer</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>carbon dioxide (CO2) gas analyzer</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>measures gaseous carbon dioxide

Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption.

Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
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