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These data were collected by Christopher L. Sabine and Richard A. Feely of NOAA Pacific Marine Environmental Laboratory (PMEL), Andrew G. Dickson of Scripps Institution of Oceanography (SIO), and Dennis A. Hansell and Frank J. Millero of Rosenstiel School of Marine and Atmospheric Science (RSMAS) as part of the CLIVAR_S04P_2011 dataset.

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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
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                <gco:CharacterString>Global Change Master Directory (GCMD) Science Keywords</gco:CharacterString>
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                    <gco:Date>2026</gco:Date>
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                        <gmd:CI_OnlineResource>
                          <gmd:linkage>
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                <gco:CharacterString>OCADS Study Type</gco:CharacterString>
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            <gco:CharacterString>CLIVAR_S04P_2011</gco:CharacterString>
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          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Provider Keywords</gco:CharacterString>
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              <gmd:date gco:nilReason="inapplicable" />
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            <gco:CharacterString>ALKALI</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>CFC-11</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>CFC-12</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>CTDOXY</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>CTDSAL</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>CTDTMP</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>DIC</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>DOC</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>NITRAT</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>NITRIT</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>OXYGEN</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>PHSPHT</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>PH_TMP</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>PH_TOT</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>SALNTY</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>SF6</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>SILCAT</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>TA</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>TCARBN</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>TDN</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>TRITER</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>TRITUM</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>pH</gco:CharacterString>
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          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Provider Variable Abbreviations</gco:CharacterString>
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              <gmd:date gco:nilReason="inapplicable" />
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            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/55facbdc-d4ed-4ee2-a74d-911b084c8ff8" xlink:actuate="onRequest">OPTSPEC &gt; Optical Spectrometer</gmx:Anchor>
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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="instrument">instrument</gmd:MD_KeywordTypeCode>
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              <gmd:title>
                <gco:CharacterString>Global Change Master Directory (GCMD) Instrument Keywords</gco:CharacterString>
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                <gmd:CI_Date>
                  <gmd:date>
                    <gco:Date>2026</gco:Date>
                  </gmd:date>
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                    <gmd:CI_DateTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="revision">revision</gmd:CI_DateTypeCode>
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          <gmd:keyword>
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                <gmd:CI_Date>
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            <gco:CharacterString>Southern Ocean</gco:CharacterString>
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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="place">place</gmd:MD_KeywordTypeCode>
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            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Provider Geographic Names</gco:CharacterString>
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Abbreviation: DIC;
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Measured or calculated: Calculated;
Replicate information: The replicate samples (N=314) were interspersed throughout the station analysis for quality assurance and integrity of the coulometer cell solutions. No systematic differences between the replicates were observed;
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CRM batch number: Batch 106</gco:CharacterString>
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Abbreviation: TA;
Observation type: discrete;
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Measured;
Type of titration: potentiometric;
Cell type (open or closed): Open;
Curve fitting method: Total alkalinity measurements were made using an open-cell, two-stage, potentiometric titration procedure similar to that used to certify reference materials for total alkalinity (see Dickson et al., 2003), except that samples were not weighed into the titration vessel.;
Uncertainty: Precision ~ 1.5 μmol/kg, Accuracy ~ 2.0 μmol/kg;
Method reference: Dickson, A.G., Sabine, C.L. and Christian, J.R. (Eds.), (2007): Guide to Best Practices for Ocean C O2 Measurements. PICES Special Publication 3, 191 pp. Dickson, A. G., Afghan, J. D. &amp; Anderson, G. C., 2003. Reference materials for oceanic CO2 analysis: A method for the certification of total alkalinity. Marine Chemistry 80, 185-197.</gco:CharacterString>
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Temperature of pH measurement: 25;
Detailed sampling and analyzing information: pH (mmol/kg H2O) on the total scale was measured using an Agilent 8453 spectrophotometer according to the methods outlined by Clayton and Byrne (1993). A RTE17 water bath maintained spectrophotometric cell temperature at 25.0C.;
Uncertainty: The precision of the data can be accessed from measurements of duplicate samples, and certified reference material (CRM) Batch 106 (Dr. Andrew Dickson, UCSD). CRMs were measured approximately every other. The mean and standard deviation for the CRMs was 7.9168+/- 0.0031 (n=110).the accuracy of the pH measurements is underway, and large changes (~0.01) in the final reported values are likely. Confidence in the precision of the measurements remains high, and likely changes would be a simple offset or an offset that is a simple function of reported pH.</gco:CharacterString>
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Abbreviation: CTDTMP;
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In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: SALNTY;
Abbreviation: SALNTY;
Controlled vocabulary name: SALINITY;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: CTDOXY;
Abbreviation: CTDOXY;
Unit: UMOL/KG;
Controlled vocabulary name: DISSOLVED OXYGEN;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: OXYGEN;
Abbreviation: OXYGEN;
Unit: UMOL/KG;
Controlled vocabulary name: DISSOLVED OXYGEN;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: SILCAT;
Abbreviation: SILCAT;
Unit: UMOL/KG;
Controlled vocabulary name: silicate;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: NITRAT;
Abbreviation: NITRAT;
Unit: UMOL/KG;
Controlled vocabulary name: NITRATE;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: NITRIT;
Abbreviation: NITRIT;
Unit: UMOL/KG;
Controlled vocabulary name: NITRITE;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: PHSPHT;
Abbreviation: PHSPHT;
Unit: UMOL/KG;
Controlled vocabulary name: phosphate;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: CFC-11;
Abbreviation: CFC-11;
Unit: PMOL/KG;
Controlled vocabulary name: CHLOROFLUOROCARBON-11 (CFC-11);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: CFC-12;
Abbreviation: CFC-12;
Unit: PMOL/KG;
Controlled vocabulary name: CHLOROFLUOROCARBON-12 (CFC-12);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: SF6;
Abbreviation: SF6;
Unit: FMOL/KG;
Controlled vocabulary name: Sulfur Hexaflouride (SF6);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: TCARBN;
Abbreviation: TCARBN;
Unit: UMOL/KG;
Controlled vocabulary name: DISSOLVED INORGANIC CARBON (DIC);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: ALKALI;
Abbreviation: ALKALI;
Unit: UMOL/KG;
Controlled vocabulary name: total alkalinity;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: PH_TOT;
Abbreviation: PH_TOT;
Unit: @20C;
Controlled vocabulary name: pH;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: PH_TMP;
Abbreviation: PH_TMP;
Unit: DEG_C;
Controlled vocabulary name: pH;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: DOC;
Abbreviation: DOC;
Unit: UMOL/KG;
Controlled vocabulary name: DISSOLVED ORGANIC CARBON;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: TDN;
Abbreviation: TDN;
Unit: UMOL/KG;
Controlled vocabulary name: Total Dissolved Nitrogen (TDN);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: TRITUM;
Abbreviation: TRITUM;
Unit: TU;
Controlled vocabulary name: Tritium (Hydrogen isotope);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: TRITER;
Abbreviation: TRITER;
Unit: TU;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
        </gmd:LI_Lineage>
      </gmd:lineage>
    </gmd:DQ_DataQuality>
  </gmd:dataQualityInfo>
  <gmd:dataQualityInfo>
    <gmd:DQ_DataQuality>
      <gmd:scope>
        <gmd:DQ_Scope>
          <gmd:level>
            <gmd:MD_ScopeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_ScopeCode" codeListValue="repository">repository</gmd:MD_ScopeCode>
          </gmd:level>
          <gmd:levelDescription>
            <gmd:MD_ScopeDescription>
              <gmd:other>
                <gco:CharacterString>NOAA National Centers for Environmental Information</gco:CharacterString>
              </gmd:other>
            </gmd:MD_ScopeDescription>
          </gmd:levelDescription>
        </gmd:DQ_Scope>
      </gmd:scope>
      <gmd:lineage>
        <gmd:LI_Lineage>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>NOAA created the National Centers for Environmental Information (NCEI) by merging NOAA's National Climatic Data Center (NCDC), National Geophysical Data Center (NGDC), and National Oceanographic Data Center (NODC), including the National Coastal Data Development Center (NCDDC), per the Consolidated and Further Continuing Appropriations Act, 2015, Public Law 113-235. NCEI launched publicly on April 22, 2015.</gco:CharacterString>
              </gmd:description>
              <gmd:dateTime>
                <gco:DateTime>2015-04-22T00:00:00</gco:DateTime>
              </gmd:dateTime>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
        </gmd:LI_Lineage>
      </gmd:lineage>
    </gmd:DQ_DataQuality>
  </gmd:dataQualityInfo>
  <gmd:metadataMaintenance>
    <gmd:MD_MaintenanceInformation>
      <gmd:maintenanceAndUpdateFrequency>
        <gmd:MD_MaintenanceFrequencyCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_MaintenanceFrequencyCode" codeListValue="asNeeded">asNeeded</gmd:MD_MaintenanceFrequencyCode>
      </gmd:maintenanceAndUpdateFrequency>
      <gmd:maintenanceNote>
        <gco:CharacterString>Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.</gco:CharacterString>
      </gmd:maintenanceNote>
      <gmd:contact>
        <gmd:CI_ResponsibleParty>
          <gmd:organisationName>
            <gco:CharacterString>NOAA National Centers for Environmental Information</gco:CharacterString>
          </gmd:organisationName>
          <gmd:role>
            <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="custodian">custodian</gmd:CI_RoleCode>
          </gmd:role>
        </gmd:CI_ResponsibleParty>
      </gmd:contact>
    </gmd:MD_MaintenanceInformation>
  </gmd:metadataMaintenance>
  <gmi:acquisitionInformation>
    <gmi:MI_AcquisitionInformation id="AMS">
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be73">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>spectrophotometer</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>spectrophotometer</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>spectrophotometer, optical spectrometer, spectrograph or spectroscope

An optical spectrometer (spectrophotometer, spectrograph or spectroscope) is an instrument used to measure properties of light over a specific portion of the electromagnetic spectrum, typically used in spectroscopic analysis to identify materials.

Butler, L. R. P.; Laqua, K. (1995). "Nomenclature, symbols, units and their usage in spectrochemical analysis-IX. Instrumentation for the spectral dispersion and isolation of optical radiation (IUPAC Recommendations 1995)". Pure Appl. Chem. IUPAC. 67 (10): 1725–1744. doi:10.1351/pac199567101725. A spectrometer is the general term for describing a combination of spectral apparatus with one or more detectors to measure the intensity of one or more spectral bands."</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:platform>
        <gmi:MI_Platform id="plat_b0c8">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>RV Nathaniel B. Palmer</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:description>
            <gco:CharacterString>Updated information from ICES for the vessel NATHANIEL B. PALMER from UNITED STATES.
Use 3206 for all data attributed to the vessel NATHANIEL B. PALMER from UNITED STATES.
This platform has a current Call Sign = WPB3210 and two previous call signs, related to owner/company name changes since 1992. Previous call signs for NATHANIEL B. PALMER are:
KUS1475 (1992 - ca. 1996)
WCE9345 (ca. 1996 - mid-2006)
WBP3210 (mid-2006 to present)

Name : NATHANIEL B. PALMER
Flag : UNITED STATES - US (ISO Country Code)
Call Sign : WBP3210
Title : RV
Platform Class : 31 Research vessel
IMO : 9007257
Commissioned Date : 1992
Current Length : 86
Built : 1992-03
Notes : Data also found under previous call sign KUS1475
Lloyds URL : http://www.seasearcher.com/lmiu/vessels/overview.htm?vesselID=241527

Confirmed by NOAA on 2013-11-19.</gco:CharacterString>
          </gmi:description>
          <gmi:instrument gco:nilReason="missing" />
        </gmi:MI_Platform>
      </gmi:platform>
    </gmi:MI_AcquisitionInformation>
  </gmi:acquisitionInformation>
</gmi:MI_Metadata>