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        <gco:CharacterString>This record describes water quality inorganic nutrient concentration metrics collected monthly between May 2023 to May 2024 to provide reference data of nearshore and watershed water quality on the island of Culebra, Puerto Rico. The water quality monitoring was conducted at 18 fixed stations. Five stations were selected to quantify Land Based Sources of Pollution (LBSP) stressor loads at key point and non-point sources in the Cabra, Coronel, and Aeropuerto watersheds. Levels of LBSP exposure were measured at 13 nearshore stations co-located with long-term seagrass monitoring sites. Nearshore monitoring sites were selected to identify watershed discharge points, coastal hydrodynamics, as well as the existing level of LBSP exposure and anticipated changes to LBSP exposure due to management actions. Nearshore monitoring stations were designated based on their land based sources of pollution management implementation status (LBSP Treatment Group), as follows: 1) LBSP Restoration stations: Located downstream where land-based pollutant management has or is being implemented. 2) LBSP Control stations: Represent a range of land-based pollutant impairments, including sites with no LBSP management, no known direct discharge of LBSP but are representative of the range of external factors that may be encountered at the LBSP Restoration stations. 3) Negative Reference stations of know significant -anecdotal and quantified- LBSP impairment. 4) Positive Reference stations of low LBSP impairment. Nearshore water quality samples were collected at two depths: surface (10-25 cm ) and bottom (2 m deep). Watershed water quality samples were collected only at surface.

Water quality inorganic nutrient concentration metrics include: Nitrite, nitrate, ammonium, total nitrogen, orthophosphate, total phosphorus, and silica. The research questions, survey design and monitoring localities were specific to this study and the associated water quality data is unsuitable in a regulatory framework.

The data presented herein was collected with financial support from NOAA Restoration Center and NOAA Coral Reef Conservation Program, and the National Fish and Wildlife Foundation (NFWF).</gco:CharacterString>
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      </gmd:descriptiveKeywords>
      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gco:CharacterString>Numeric Data Sets &gt; Chemistry</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>Numeric Data Sets &gt; Water Quality</gco:CharacterString>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>CoRIS Discovery Thesaurus</gco:CharacterString>
              </gmd:title>
              <gmd:date gco:nilReason="inapplicable" />
            </gmd:CI_Citation>
          </gmd:thesaurusName>
        </gmd:MD_Keywords>
      </gmd:descriptiveKeywords>
      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gco:CharacterString>EARTH SCIENCE &gt; Oceans &gt; Ocean Chemistry &gt; Nitrate</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>EARTH SCIENCE &gt; Oceans &gt; Ocean Chemistry &gt; Nitrite</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>EARTH SCIENCE &gt; Oceans &gt; Ocean Chemistry &gt; Nitrogen</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>EARTH SCIENCE &gt; Oceans &gt; Ocean Chemistry &gt; Nitrogen &gt; Total</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>EARTH SCIENCE &gt; Oceans &gt; Ocean Chemistry &gt; Phosphate</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>EARTH SCIENCE &gt; Oceans &gt; Ocean Chemistry &gt; Phosphate &gt; Total</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>EARTH SCIENCE &gt; Oceans &gt; Ocean Chemistry &gt; Phosphorus</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>EARTH SCIENCE &gt; Oceans &gt; Ocean Chemistry &gt; Silicate</gco:CharacterString>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>CoRIS Theme Thesaurus</gco:CharacterString>
              </gmd:title>
              <gmd:date gco:nilReason="inapplicable" />
            </gmd:CI_Citation>
          </gmd:thesaurusName>
        </gmd:MD_Keywords>
      </gmd:descriptiveKeywords>
      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/6eb3919b-85ce-4988-8b78-9d0018fd8089" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; OCEAN CHEMISTRY</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/64d17528-29b4-4e2e-843a-7f7035bb5717" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; OCEAN CHEMISTRY &gt; AMMONIA</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/4fde380a-38c5-4d46-bc80-4f2515a43983" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; OCEAN CHEMISTRY &gt; NITRATE</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/941410da-0b7f-4ec6-a718-212194ced13f" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; OCEAN CHEMISTRY &gt; NITRITE</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/db5357c9-cc9d-4693-86fe-6bb88555d434" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; OCEAN CHEMISTRY &gt; NITROGEN</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/0b513d8c-bfd3-44ee-976e-42757b8375a2" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; OCEAN CHEMISTRY &gt; PHOSPHATE</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/c91c8879-1b29-48e3-b4cd-a238af66cdaf" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; OCEAN CHEMISTRY &gt; SILICATE</gmx:Anchor>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Global Change Master Directory (GCMD) Science Keywords</gco:CharacterString>
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              <gmd:date>
                <gmd:CI_Date>
                  <gmd:date>
                    <gco:Date>2026</gco:Date>
                  </gmd:date>
                  <gmd:dateType>
                    <gmd:CI_DateTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="revision">revision</gmd:CI_DateTypeCode>
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                </gmd:CI_Date>
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              <gmd:edition>
                <gco:CharacterString>24</gco:CharacterString>
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              <gmd:citedResponsibleParty>
                <gmd:CI_ResponsibleParty>
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                      <gmd:address>
                        <gmd:CI_Address>
                          <gmd:city>
                            <gco:CharacterString>Greenbelt</gco:CharacterString>
                          </gmd:city>
                          <gmd:administrativeArea>
                            <gco:CharacterString>MD</gco:CharacterString>
                          </gmd:administrativeArea>
                        </gmd:CI_Address>
                      </gmd:address>
                      <gmd:onlineResource>
                        <gmd:CI_OnlineResource>
                          <gmd:linkage>
                            <gmd:URL>https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords</gmd:URL>
                          </gmd:linkage>
                          <gmd:protocol>
                            <gco:CharacterString>HTTPS</gco:CharacterString>
                          </gmd:protocol>
                          <gmd:name>
                            <gco:CharacterString>GCMD Keyword Forum Page</gco:CharacterString>
                          </gmd:name>
                          <gmd:description>
                            <gco:CharacterString>Global Change Master Directory (GCMD). 2025. GCMD Keywords, Version 21. Greenbelt, MD: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA). URL (GCMD Keyword Forum Page): https://forum.earthdata.nasa.gov/app.php/tag/GCMD+Keywords</gco:CharacterString>
                          </gmd:description>
                          <gmd:function>
                            <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
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                    <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="custodian">custodian</gmd:CI_RoleCode>
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      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gco:CharacterString>Dissolved inorganic nutrient concentrations</gco:CharacterString>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
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          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Provider Keywords</gco:CharacterString>
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              <gmd:date gco:nilReason="inapplicable" />
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          </gmd:thesaurusName>
        </gmd:MD_Keywords>
      </gmd:descriptiveKeywords>
      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/79f76e22-ae42-450d-8bed-d05a800f6ea0" xlink:actuate="onRequest">AUTOANALYZER &gt; AUTOANALYZER</gmx:Anchor>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/b79c7e06-cd07-442f-bf12-2019cd71c201" xlink:actuate="onRequest">NISKIN BOTTLES</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/55facbdc-d4ed-4ee2-a74d-911b084c8ff8" xlink:actuate="onRequest">OPTSPEC &gt; Optical Spectrometer</gmx:Anchor>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="instrument">instrument</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Global Change Master Directory (GCMD) Instrument Keywords</gco:CharacterString>
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              <gmd:date>
                <gmd:CI_Date>
                  <gmd:date>
                    <gco:Date>2026</gco:Date>
                  </gmd:date>
                  <gmd:dateType>
                    <gmd:CI_DateTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="revision">revision</gmd:CI_DateTypeCode>
                  </gmd:dateType>
                </gmd:CI_Date>
              </gmd:date>
              <gmd:edition>
                <gco:CharacterString>24</gco:CharacterString>
              </gmd:edition>
              <gmd:citedResponsibleParty>
                <gmd:CI_ResponsibleParty>
                  <gmd:organisationName>
                    <gco:CharacterString>Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA)</gco:CharacterString>
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                  <gmd:contactInfo>
                    <gmd:CI_Contact>
                      <gmd:address>
                        <gmd:CI_Address>
                          <gmd:city>
                            <gco:CharacterString>Greenbelt</gco:CharacterString>
                          </gmd:city>
                          <gmd:administrativeArea>
                            <gco:CharacterString>MD</gco:CharacterString>
                          </gmd:administrativeArea>
                        </gmd:CI_Address>
                      </gmd:address>
                      <gmd:onlineResource>
                        <gmd:CI_OnlineResource>
                          <gmd:linkage>
                            <gmd:URL>https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords</gmd:URL>
                          </gmd:linkage>
                          <gmd:protocol>
                            <gco:CharacterString>HTTPS</gco:CharacterString>
                          </gmd:protocol>
                          <gmd:name>
                            <gco:CharacterString>GCMD Keyword Forum Page</gco:CharacterString>
                          </gmd:name>
                          <gmd:description>
                            <gco:CharacterString>Global Change Master Directory (GCMD). 2025. GCMD Keywords, Version 21. Greenbelt, MD: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA). URL (GCMD Keyword Forum Page): https://forum.earthdata.nasa.gov/app.php/tag/GCMD+Keywords</gco:CharacterString>
                          </gmd:description>
                          <gmd:function>
                            <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
                          </gmd:function>
                        </gmd:CI_OnlineResource>
                      </gmd:onlineResource>
                    </gmd:CI_Contact>
                  </gmd:contactInfo>
                  <gmd:role>
                    <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="custodian">custodian</gmd:CI_RoleCode>
                  </gmd:role>
                </gmd:CI_ResponsibleParty>
              </gmd:citedResponsibleParty>
            </gmd:CI_Citation>
          </gmd:thesaurusName>
        </gmd:MD_Keywords>
      </gmd:descriptiveKeywords>
      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gco:CharacterString>COUNTRY/TERRITORY &gt; United States of America &gt; Puerto Rico &gt; Culebra Island (18N065W0011)</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>OCEAN BASIN &gt; Atlantic Ocean &gt; Caribbean Sea /North Atlantic Ocean &gt; Puerto Rico &gt; Culebra Island (18N065W0011)</gco:CharacterString>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="place">place</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>CoRIS Place Thesaurus</gco:CharacterString>
              </gmd:title>
              <gmd:date gco:nilReason="inapplicable" />
            </gmd:CI_Citation>
          </gmd:thesaurusName>
        </gmd:MD_Keywords>
      </gmd:descriptiveKeywords>
      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/eb176e48-13e2-413c-85d6-b37e16303573" xlink:actuate="onRequest">OCEAN &gt; ATLANTIC OCEAN &gt; NORTH ATLANTIC OCEAN &gt; CARIBBEAN SEA</gmx:Anchor>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="place">place</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Global Change Master Directory (GCMD) Location Keywords</gco:CharacterString>
              </gmd:title>
              <gmd:date>
                <gmd:CI_Date>
                  <gmd:date>
                    <gco:Date>2026</gco:Date>
                  </gmd:date>
                  <gmd:dateType>
                    <gmd:CI_DateTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="revision">revision</gmd:CI_DateTypeCode>
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                </gmd:CI_Date>
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              <gmd:edition>
                <gco:CharacterString>24</gco:CharacterString>
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              <gmd:citedResponsibleParty>
                <gmd:CI_ResponsibleParty>
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                    <gco:CharacterString>Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA)</gco:CharacterString>
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                  <gmd:contactInfo>
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                      <gmd:address>
                        <gmd:CI_Address>
                          <gmd:city>
                            <gco:CharacterString>Greenbelt</gco:CharacterString>
                          </gmd:city>
                          <gmd:administrativeArea>
                            <gco:CharacterString>MD</gco:CharacterString>
                          </gmd:administrativeArea>
                        </gmd:CI_Address>
                      </gmd:address>
                      <gmd:onlineResource>
                        <gmd:CI_OnlineResource>
                          <gmd:linkage>
                            <gmd:URL>https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords</gmd:URL>
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                          <gmd:protocol>
                            <gco:CharacterString>HTTPS</gco:CharacterString>
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                          <gmd:name>
                            <gco:CharacterString>GCMD Keyword Forum Page</gco:CharacterString>
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                          <gmd:description>
                            <gco:CharacterString>Global Change Master Directory (GCMD). 2025. GCMD Keywords, Version 21. Greenbelt, MD: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA). URL (GCMD Keyword Forum Page): https://forum.earthdata.nasa.gov/app.php/tag/GCMD+Keywords</gco:CharacterString>
                          </gmd:description>
                          <gmd:function>
                            <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
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                        </gmd:CI_OnlineResource>
                      </gmd:onlineResource>
                    </gmd:CI_Contact>
                  </gmd:contactInfo>
                  <gmd:role>
                    <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="custodian">custodian</gmd:CI_RoleCode>
                  </gmd:role>
                </gmd:CI_ResponsibleParty>
              </gmd:citedResponsibleParty>
            </gmd:CI_Citation>
          </gmd:thesaurusName>
        </gmd:MD_Keywords>
      </gmd:descriptiveKeywords>
      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
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            <gco:CharacterString>Culebra Island, Puerto Rico</gco:CharacterString>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="place">place</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Provider Place Names</gco:CharacterString>
              </gmd:title>
              <gmd:date gco:nilReason="inapplicable" />
            </gmd:CI_Citation>
          </gmd:thesaurusName>
        </gmd:MD_Keywords>
      </gmd:descriptiveKeywords>
      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gco:CharacterString>ERCP08</gco:CharacterString>
          </gmd:keyword>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Send2NCEI Submission Package ID</gco:CharacterString>
              </gmd:title>
              <gmd:date gco:nilReason="inapplicable" />
            </gmd:CI_Citation>
          </gmd:thesaurusName>
        </gmd:MD_Keywords>
      </gmd:descriptiveKeywords>
      <gmd:resourceConstraints>
        <gmd:MD_Constraints>
          <gmd:useLimitation>
            <gco:CharacterString>accessLevel: public</gco:CharacterString>
          </gmd:useLimitation>
        </gmd:MD_Constraints>
      </gmd:resourceConstraints>
      <gmd:resourceConstraints xlink:title="NCEI Data Citation Statement">
        <gmd:MD_LegalConstraints>
          <gmd:useConstraints>
            <gmd:MD_RestrictionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_RestrictionCode" codeListValue="otherRestrictions">otherRestrictions</gmd:MD_RestrictionCode>
          </gmd:useConstraints>
          <gmd:otherConstraints>
            <gco:CharacterString>Cite as: Viqueira-Rios, Jorge; Figueroa-Sanchez, Yasiel; Sanchez, Juan; Rivera-Rieira, Rebeca; Vargas-Ángel, Bernardo; Vandiver, Lisa (2025). Water quality surveys in Culebra: comprehensive assessment of inorganic nutrient concentrations 2023-05-03 to 2024-05-21 (NCEI Accession 0306499). [indicate subset used]. NOAA National Centers for Environmental Information. Dataset. https://doi.org/10.25921/1e3k-9922. Accessed [date].</gco:CharacterString>
          </gmd:otherConstraints>
        </gmd:MD_LegalConstraints>
      </gmd:resourceConstraints>
      <gmd:resourceConstraints>
        <gmd:MD_LegalConstraints>
          <gmd:useLimitation>
            <gco:CharacterString>Distribution liability: NOAA and NCEI make no warranty, expressed or implied, regarding these data, nor does the fact of distribution constitute such a warranty. NOAA and NCEI cannot assume liability for any damages caused by any errors or omissions in these data. If appropriate, NCEI can only certify that the data it distributes are an authentic copy of the records that were accepted for inclusion in the NCEI archives.</gco:CharacterString>
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        </gmd:MD_LegalConstraints>
      </gmd:resourceConstraints>
      <gmd:resourceConstraints>
        <gmd:MD_LegalConstraints>
          <gmd:accessConstraints>
            <gmd:MD_RestrictionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_RestrictionCode" codeListValue="otherRestrictions">otherRestrictions</gmd:MD_RestrictionCode>
          </gmd:accessConstraints>
          <gmd:otherConstraints>
            <gco:CharacterString>Use liability: NOAA and NCEI cannot provide any warranty as to the accuracy, reliability, or completeness of furnished data. Users assume responsibility to determine the usability of these data. The user is responsible for the results of any application of this data for other than its intended purpose.</gco:CharacterString>
          </gmd:otherConstraints>
        </gmd:MD_LegalConstraints>
      </gmd:resourceConstraints>
      <gmd:resourceConstraints xlink:title="Data License Statement">
        <gmd:MD_LegalConstraints>
          <gmd:useConstraints>
            <gmd:MD_RestrictionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_RestrictionCode" codeListValue="license">license</gmd:MD_RestrictionCode>
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          <gmd:otherConstraints>
            <gmx:Anchor xlink:href="https://creativecommons.org/publicdomain/zero/1.0/" xlink:actuate="onRequest" xlink:title="CC0-1.0">This dataset has been dedicated to the public domain under the Creative Commons CC0 1.0 Universal (CC0 1.0) Public Domain Dedication.</gmx:Anchor>
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                <gco:CharacterString>Parameter or Variable: Dissolved inorganic nutrient concentrations (measured);
Units: mg/L;
Observation Category: laboratory analysis;
Sampling Instrument: laboratory analysis;
Sampling and Analyzing Method: Discrete water samples (125 mL) were collected for the analysis of nutrients including nitrate, nitrite, orthophosphate, ammonium, total nitrogen, total phosphorus, and silica. Watershed samples were hand collected at surface (10-25 cm); nearshore samples were collected at the surface and bottom (~2 m deep; employing a Niskin bottle). Sterile nitrile gloves were worn at all times to avoid sample contamination. Samples were frozen and sent to the TDI-Brooks Laboratory for analyses. For further instrumentation and methodological details please review the Culebra Nearshore and Watershed Water Quality Monitoring Work Plans listed in the Summary Package under "References".
Nitrate and nitrite analyses are based on the methodology of Armstrong et al. (1967) and utilize a ground Cd column for reduction of NO3- to NO2-.  Orthophosphate is measured using chemistry based on the investigations of Bernhardt and Wilhelms (1967) with the modification of hydrazine as a reductant. Silicate determination is accomplished using the methods of Armstrong et al. (1967) using stannous chloride.  Ammonium analysis is based on the method of Harwood (Harwood and Kuhn, 1970) using dichloro-isocyanurate as an oxidizer. Laboratory intercomparisons have been conducted and results are available. In order to increase processing efficiency and speed, voltage streams from the colorimeters are logged via a National Instruments acquisition board and data is acquired and stored using Labview.  Peak processing is accomplished using software written in Matlab and software development continues.  Peak voltage values associated with standards and samples can be determined with the written software, but manual checks and adjustment are still required at the present.  The total concentrations of nitrogen and phosphorus are determined after an initial decomposition step.  This method involves persulfate oxidation while heating the sample in an autoclave (115°C, 20 minutes)(Hansen and Koroleff 1999).  After oxidation of the samples nutrient determination is conducted on the Technicon II analyzer.  Samples are processed in batches of 30 with a full range of standards and blanks.  All samples, standards, and blanks are run in a standard format as described above.  Sample weight is recorded before and after oxidation treatment (and cooling) to detect any loss in volume. In order to determine total nitrogen and phosphorus a separate sample in addition to the volume taken for determination of dissolved components above must be provided.  A 20 ml volume in the above-mentioned 30 ml Nalgene containers suffices.  Currently five standards are run in duplicate at the beginning of each day.  Line regression calculations are conducted to generate conversion equations.  Correlation coefficients of 0.99 or better are achieved prior to analysis.  At the end of each day's run all standards are analyzed again and regression analysis is conducted.  The results of these regression analyses are compared to the initial determinations and adjustments can be made for instrument drift.  Low-end standards are also analyzed along with an internal standard (Spex certified standard, Certiprep Inc.) between each batch of 10 samples with blank determination before and after each standard check.  Blanks are also analyzed after each calibration in order to bracket each batch of 10 samples.  These blanks are used to adjust the baseline and to monitor drift.  Duplicate samples are analyzed with each batch.  The %RPD must be less than 30% for each of the analytes measured if the detected analytes are detected at greater than 3x MDL.  These methods are based on the following literature:
Aminot, A. and R. Kerovel.  198.  Dosage automatique de l'urée dans l'eau de mer: une méthode très sensible à la diacétylmonoxime.  Can. J. Fish. Aquat. Sci. 39: 174–183.
Armstrong, F. A. J., C. R. Stearns, et al. 1967. "The measurement of upwelling and subsequent biological processes by means of the Technicon Autoanalyzer and associated equipment." Deep-Sea Research 14(3):381–389.
Bernhardt, H. and A. Wilhelms (1967). The continuous determination of low level iron, soluble phosphate and total phosphate with the AutoAnalyzer. Technicon Symposium.
Hansen, H. P. and F. Koroleff (1999). Determination of Nutrients. Methods of Seawater Analysis. In: K. Grasshoff, K. Kremling and M. Ernhardt. New York, Wiley-VCH:159–251.
Harwood, J. E. and A. L. Kuhn (1970). "A colorimetric method for ammonia in natural waters." Water Research 4:805–811.;
Data Quality Method: The quality control occurred at several stages major stages: 1) instrument calibration; 2) sample collection; 3) data entry, and 4) data management. Data entry quality control included both review and manual error correction steps including purging data outside the instruments' parameter detection ranges.
Water quality measurements were made implementing state-of-the-art instrumentation.
Handheld GPS units were used to locate sites and mark site locations.
Survey methods were consistent across dates and sites.
Data gaps may originate from, but not limited to, instrument malfunction, weather conditions, and the data quality control process.</gco:CharacterString>
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        <gco:CharacterString>Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.</gco:CharacterString>
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    <gmi:MI_AcquisitionInformation id="AMS">
      <gmi:instrument>
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                <gco:CharacterString>laboratory analysis</gco:CharacterString>
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            <gco:CharacterString>Niskin bottle</gco:CharacterString>
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          <gmi:description>
            <gco:CharacterString>Device for obtaining samples of seawater at a specific depth

Why special entry for Niskin bottle but no entry for Nansen bottle?</gco:CharacterString>
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            <gco:CharacterString>Laboratory Instrument

Nutrient Autoanalyzer is a generic term describing an automated flow-thru system used to conduct analyses of several different nutrients (nitrate, ammonium, orthophosphate, and silicate) simultaneously from a seawater sample.

For example:
SEAL AutoAnalyzer 3 HR Continuous Segmented Flow Analyzer</gco:CharacterString>
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An optical spectrometer (spectrophotometer, spectrograph or spectroscope) is an instrument used to measure properties of light over a specific portion of the electromagnetic spectrum, typically used in spectroscopic analysis to identify materials.

Butler, L. R. P.; Laqua, K. (1995). "Nomenclature, symbols, units and their usage in spectrochemical analysis-IX. Instrumentation for the spectral dispersion and isolation of optical radiation (IUPAC Recommendations 1995)". Pure Appl. Chem. IUPAC. 67 (10): 1725–1744. doi:10.1351/pac199567101725. A spectrometer is the general term for describing a combination of spectral apparatus with one or more detectors to measure the intensity of one or more spectral bands."</gco:CharacterString>
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