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            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleoceanography</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleocean &gt; biomarkers</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleocean &gt; other</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleocean &gt; nitrogen isotopes</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>earth science &gt; paleoclimate &gt; paleocean &gt; carbon isotopes</gco:CharacterString>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName xlink:title="GCMD Science Keywords">
            <gmd:CI_Citation uuid="227737d0-428b-11df-9879-0800200c9a66">
              <gmd:title>
                <gco:CharacterString>Global Change Master Directory (GCMD) Science Keywords</gco:CharacterString>
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              <gmd:date>
                <gmd:CI_Date>
                  <gmd:date>
                    <gco:Date>2025</gco:Date>
                  </gmd:date>
                  <gmd:dateType>
                    <gmd:CI_DateTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="revision">revision</gmd:CI_DateTypeCode>
                  </gmd:dateType>
                </gmd:CI_Date>
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              <gmd:edition>
                <gco:CharacterString>22</gco:CharacterString>
              </gmd:edition>
              <gmd:citedResponsibleParty xlink:title="GCMD Landing Page">
                <gmd:CI_ResponsibleParty uuid="1edb41d0-428a-11df-9879-0800200c9a66">
                  <gmd:organisationName>
                    <gco:CharacterString>Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA)</gco:CharacterString>
                  </gmd:organisationName>
                  <gmd:contactInfo>
                    <gmd:CI_Contact>
                      <gmd:onlineResource>
                        <gmd:CI_OnlineResource>
                          <gmd:linkage>
                            <gmd:URL>https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords</gmd:URL>
                          </gmd:linkage>
                          <gmd:name>
                            <gco:CharacterString>GCMD Keyword Forum Page</gco:CharacterString>
                          </gmd:name>
                          <gmd:description>
                            <gco:CharacterString>Global Change Master Directory (GCMD). 2025. GCMD Keywords, Version 22. Greenbelt, MD: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA). URL (GCMD Keyword Forum Page): https://forum.earthdata.nasa.gov/app.php/tag/GCMD+Keywords</gco:CharacterString>
                          </gmd:description>
                          <gmd:function>
                            <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
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                    </gmd:CI_Contact>
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                  <gmd:role>
                    <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="custodian">custodian</gmd:CI_RoleCode>
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      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gco:CharacterString>What: sample identification; Material: null</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>What: sample identification; Material: null</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: trophic position index; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: hydroxyproline; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: phenylalanine; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: sample identification; Material: null</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: amino acid; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: leucine; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: proline; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: serine; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 13C; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: age at sample start; Material: null</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: amino acid; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: methionine; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 13C; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 13C; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: age at sample end; Material: null</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: amino acid; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: amino acid; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: isoleucine; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: notes; Material: null</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: amino acid; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: sample identification; Material: null</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: lysine; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 13C; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 13C; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: age; Material: null</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: aspartic acid; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 13C; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: age; Material: null</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: glycine; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: threonine; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 13C; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: age; Material: null</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: amino acid; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: delta 15N; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: age; Material: null</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: glutamic acid; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: tyrosine; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>What: valine; Material: bivalve</gco:CharacterString>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
          </gmd:type>
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        <gco:CharacterString>STUDY NOTES: 2 sigma combined uncertainty (analytical uncertainty and average correction factor) for bulk d15N is +/- 0.36 per mil and for d13C is +/- 0.22 per mil. The long term, average 2 sigma analytical uncertainty for d15N of amino acids is +/- 1.9 per mil. The 2 sigma propagated analytical uncertainty for the trophic position calculation is +/- 0.5. Details of the construction of the chronology used for this study can be found in Wanamaker et al., 2019 (https://doi.org/10.1007/s00382-018-4513-8). Core water depths range from -38 to -80 m. Provided Keywords: geochemistry, Arctica islandica, nitrogen isotopes, compound specific isotopic analyses of amino acids, Gulf of Maine, ocean circulation 
ABSTRACT SUPPLIED BY ORIGINATOR: Developing high resolution, well-dated marine proxies of environmental, climatic, and oceanographic conditions is critical in order to advance our understanding of the ocean's role in the global climate system. While some work has investigated bulk and compound specific stable nitrogen isotopes (d15N) in bivalve shells as proxies for environmental variability, the small concentrations of nitrogen found in the organic matrix of the shell calcium carbonate (CaCO3) makes developing high resolution records challenging. This study investigates the potential of using the bulk and amino acid d15N of bivalve periostracum, the protein layer on the outside of the shell, as a proxy archive of nitrogen cycling processes and water source variability. Bulk d15N values were measured on the periostracum, aragonitic CaCO3, and adductor muscle of Arctica islandica shells collected in the Gulf of Maine. Increased variability of isotopic values across growth lines compared to along growth lines support mechanistic reasoning based on growth processes that periostracum is recording changes in d15N over the course of the clam's lifetime (up to 500 years). In addition, the statistically significant relationship between periostracum d15N and contemporaneous carbonate d15N of the same shell (r= 0.82, p&lt;.0001, n=40) suggests that periostracum preserves a similar d15N signal to that preserved in the carbonate. This finding, coupled with the fact that source amino acid d15N values of periostracum are similar to that of the adductor muscle and the particulate organic matter (POM) consumed by the clam, suggests that periostracum bulk d15N reflect the d15N of the clam's food source. The isotopic offsets between periostracum, carbonate, and adductor muscle d15N values are primarily caused by differences in amino acid composition of the different tissue types, as evidenced by isotope mass balance calculations, although may also be related to differences in d15N values of the individual amino acids of the different tissue types, especially the trophic amino acids. Compound specific d15N analyses of the periostracum of A. islandica shells were used to determine that the calculated trophic position of the clams in this study (1.4 +/- 0.4) did not change significantly between 1783 and 1997. Phenylalanine d15N values over the last 70 years show similar trends to that of the bulk record, suggesting that changes in bulk d15N of that time period are related to changes in baseline d15N. Periostracum d15N values from shells collected in the western Gulf of Maine have decreased by ~1‰ since the mid-1920s. This trend (-0.008‰/year) is not statistically different from the trend of previously published d15N values of deep-sea corals from the entrance to the Gulf of Maine over the same time period. This coral record has been shown to indicate a shift in water mass source to the region and therefore the similarity between the two records suggest that changes in periostracum d15N values are reflecting broader North Atlantic hydrographic changes. Our study introduces a new, high-resolution and absolutely dated paleoceanographic proxy of baseline d15N, presenting the opportunity for future reconstructions of aspects of nitrogen cycling and water source changes in the global oceans.</gco:CharacterString>
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