Here we provide information for the PlanetScope and d Deutsches Zentrum fur Luft- und Raumfahrt (DLR) Earth Sensing Imaging Spectrometer (DESIS) Derived Spectral Library of Agricultural Crops in California which was developed using PlanetScope Dove-R high spatial resolution data and DESIS hyperspectral data acquired for 2020. PlanetScope images are available through Planet Labs (2022). The DESIS images used for this dataset are available through the German Aerospace Center and Teledyne Brown (2022). The crop type data and confidence layer for 2020 can be accessed through the United States Department of Agriculture National Agricultural Statistics Service (2022). The PlanetScope and DESIS Derived Spectral Library of Agricultural Crops dataset characteristics are described below, with PlanetScope and DESIS data provided in two separate CSV files. Related Primary Publication: Aneece, I., Foley, D., Thenkabail, P.S., Oliphant, A., and Teluguntla, P. 2022. New generation hyperspectral data from DESIS compared and contrasted with hyperspatial resolution PlanetScope data for crop type classification. DOI: https://doi.org/10.5066/xxxxxxxx.