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Nitrapyrin, 6-CPA, and Herbicide Concentrations in Streams in the Midwestern US (March 2016 to June 2017)

Metadata Updated: October 29, 2023

Nitrapyrin, a nitrification inhibitor, 6-CPA, a nitrapyrin degradate, and three co-applied herbicides (acetochlor, atrazine, and metolachlor) were measured in water samples from seven streams across Iowa and Illinois. Iowa water samples were collected from March 2016 to June 2017, and Illinois water samples were collected from September 2016 to June 2017. The compounds studied are applied to corn, and Iowa and Illinois are the two largest corn producing states in the U.S. The seven stream sites are all adjacent to agricultural fields in corn production. Water samples (1-L) were collected in amber glass bottles using a grab or depth weighted approach. With the exception of one site, Iowa River at Wapello (USGS Site ID 05465500), all water samples were collected using a hydrologic based sampling approach. This means that samples were collected near peak flow during storm events and periodically during base flow conditions. Water samples were filtered (0.7 micrometers), extracted via solid phase extraction (Oasis® MAX cartridge), and analyzed (nitrapyrin and herbicides by gas chromatography with mass-spectrometry; 6-CPA by liquid chromatography tandem mass-spectrometry).

Access & Use Information

Public: This dataset is intended for public access and use. License: No license information was provided. If this work was prepared by an officer or employee of the United States government as part of that person's official duties it is considered a U.S. Government Work.

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Dates

Metadata Created Date June 1, 2023
Metadata Updated Date October 29, 2023

Metadata Source

Harvested from DOI EDI

Additional Metadata

Resource Type Dataset
Metadata Created Date June 1, 2023
Metadata Updated Date October 29, 2023
Publisher U.S. Geological Survey
Maintainer
@Id http://datainventory.doi.gov/id/dataset/75509b5381391dfbf590e80458c16b11
Identifier USGS:5b04760de4b0d8682b96357c
Data Last Modified 20220331
Category geospatial
Public Access Level public
Bureau Code 010:12
Metadata Context https://project-open-data.cio.gov/v1.1/schema/catalog.jsonld
Metadata Catalog ID https://datainventory.doi.gov/data.json
Schema Version https://project-open-data.cio.gov/v1.1/schema
Catalog Describedby https://project-open-data.cio.gov/v1.1/schema/catalog.json
Harvest Object Id 9bc2cc3b-7ba2-498b-b05d-17460183bf61
Harvest Source Id 52bfcc16-6e15-478f-809a-b1bc76f1aeda
Harvest Source Title DOI EDI
Metadata Type geospatial
Old Spatial -96.817016601261,36.518114360445,-87.236938476645,43.508403682242
Publisher Hierarchy White House > U.S. Department of the Interior > U.S. Geological Survey
Source Datajson Identifier True
Source Hash acb4e8a2f373abc36ecd4a78428ef9e13f4c39e18f3b86477a16647a0e4acc5c
Source Schema Version 1.1
Spatial {"type": "Polygon", "coordinates": -96.817016601261, 36.518114360445, -96.817016601261, 43.508403682242, -87.236938476645, 43.508403682242, -87.236938476645, 36.518114360445, -96.817016601261, 36.518114360445}

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