A photoactive bimetallic framework for direct aminoformylation of nitroarenes
A bimetallic catalyst, AgPd@g-C3N4, synthesized by reducing silver and palladium salts over graphitic carbon nitride (g-C3N4), enables the concerted reductive formylation of aromatic nitro compounds under photo-chemical conditions using formic acid, which serves the dual role of a hydrogen source and a formylating agent.
This dataset is associated with the following publication:
Baig, R.B.N., S. Verma, M. Nadagouda , and R. Varma. A photoactive bimetallic framework for direct aminoformylation of nitroarenes. GREEN CHEMISTRY. Royal Society of Chemistry, Cambridge, UK, 18(4): 1019-1022, (2016).
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https://www.rsc.org/suppdata/c5/gc/c5gc02799c/c5gc02799c1.pdf
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Complete Metadata
| @type | dcat:Dataset |
|---|---|
| accessLevel | public |
| bureauCode |
[ "020:00" ] |
| contactPoint |
{ "fn": "Rajender Varma", "hasEmail": "mailto:varma.rajender@epa.gov" } |
| description | A bimetallic catalyst, AgPd@g-C3N4, synthesized by reducing silver and palladium salts over graphitic carbon nitride (g-C3N4), enables the concerted reductive formylation of aromatic nitro compounds under photo-chemical conditions using formic acid, which serves the dual role of a hydrogen source and a formylating agent. This dataset is associated with the following publication: Baig, R.B.N., S. Verma, M. Nadagouda , and R. Varma. A photoactive bimetallic framework for direct aminoformylation of nitroarenes. GREEN CHEMISTRY. Royal Society of Chemistry, Cambridge, UK, 18(4): 1019-1022, (2016). |
| distribution |
[ { "title": "https://www.rsc.org/suppdata/c5/gc/c5gc02799c/c5gc02799c1.pdf", "accessURL": "https://www.rsc.org/suppdata/c5/gc/c5gc02799c/c5gc02799c1.pdf" } ] |
| identifier | A-37q0-321 |
| keyword |
[ "Aminoformylation", "Bimetallic framework", "Earth-abundant materials", "Nitroarenes", "Sustainable materials management" ] |
| license | https://pasteur.epa.gov/license/sciencehub-license.html |
| modified | 2016-02-16 |
| programCode |
[ "020:000" ] |
| publisher |
{ "name": "U.S. EPA Office of Research and Development (ORD)", "subOrganizationOf": { "name": "U.S. Environmental Protection Agency", "subOrganizationOf": { "name": "U.S. Government" } } } |
| references |
[ "https://doi.org/10.1039/c5gc02799c" ] |
| rights |
null
|
| title | A photoactive bimetallic framework for direct aminoformylation of nitroarenes |
